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2010 Fiscal Year Annual Research Report

Fe系物質の超高圧下での挙動と最下部マントル~内核の物質科学

Research Project

Project/Area Number 20001005
Research InstitutionEhime University

Principal Investigator

入舩 徹男  愛媛大学, 地球深部ダイナミクス研究センター, 教授 (80193704)

Co-Investigator(Kenkyū-buntansha) 土屋 卓久  愛媛大学, 地球深部ダイナミクス研究センター, 教授 (70403863)
西山 宣正  愛媛大学, 地球深部ダイナミクス研究センター, 准教授 (10452682)
大藤 弘明  愛媛大学, 地球深部ダイナミクス研究センター, 助教 (80403864)
丹下 慶範  愛媛大学, 地球深部ダイナミクス研究センター, 助教 (70543164)
桑山 靖弘  愛媛大学, 地球深部ダイナミクス研究センター, 助教 (00554015)
Keywords固体地球物理学 / 超高圧実験 / 地球・惑星内部 / 第一原理計算 / マントル・核
Research Abstract

代表者らが開発した超高硬度ナノ多結晶ダイヤモンド(NPD)の大型化に関しては、目標どおり地直径・長さともに1cmの試料の合成に成功した。一方で、ルーチン的な合成が可能な6.5mmサイズのNPDの合成を数十個単位でおこない、ダイヤモンドアンビル装置(DAC)への応用をおこなうとともに、マルチアンビル装置(甑)への応用を目指した装置開発をおこなった。DACへの応用に関しては、400GPaを狙うのは現状のNPDは困難であることが明らかになった。一方でMAなどの大容量装置への応用に関しては、非常に有用であることがわかり、今後大容量装置におけるより高い圧力発生と精密測定を目指したNPDの応用に焦点を当てる予定である。一方、焼結ダイヤモンド(SD)を用いた下部マントル物質の研究では、50GPa領域で様々なFe含有量のかんらん石を出発物質として用い、高圧相間のFe分配の精密決定がなされた。この結果、2つの高圧相の1つであるフェロペリクレスにおける、2価Feのスピン転移に関連した新たな結果が得られた。また、DACを用いた中心核領域の圧力温度発生とFeの結晶構造に関しては、最初の報告は東工大のグループに一歩先んじられたが、より詳細な実験とともに、第一原理計算を併用した安定性の検討も含め、より確固とした新たな成果をあげた。更に、第一原理計算とDAC実験の組み合わせにより、新高圧相の探査においても重要な成果を得た。下部マントル領域における弾性波速度測定に関しても、測定技術は確立され、SiO_2の高圧型であるスティショバイト焼結体を試料とした高温高圧条件下での測定がなされた。尚、このスティショバイト焼結体は、非常に硬度が高いとともに靭性も大きいことがわかり,、新たな超硬材料として興味深い物質であることが分かった。

  • Research Products

    (76 results)

All 2011 2010 Other

All Journal Article (37 results) (of which Peer Reviewed: 37 results) Presentation (36 results) Book (2 results) Remarks (1 results)

  • [Journal Article] P-V-T equation of state of Ca3Al2Si3O12 grossular garnet.2011

    • Author(s)
      S.Greaux
    • Journal Title

      Phys.Chem.Min.

      Volume: 38 Pages: 85-94

    • Peer Reviewed
  • [Journal Article] Noncollinear Spin Structure in Fe-Ni Invar Alloy Probed by Magnetic EXAFS at High Pressure.2011

    • Author(s)
      K.Matsumoto
    • Journal Title

      J.Phys.Soc.Jpn.

      Volume: 80 Pages: 023709

    • Peer Reviewed
  • [Journal Article] High pressure and temperature fabric transitions in olivine and variations in upper mantle seismic anisotropy.2011

    • Author(s)
      T.Ohuchi
    • Journal Title

      Earth Planet.Sci.Lett.

      Volume: 304 Pages: 55-63

    • Peer Reviewed
  • [Journal Article] Phase transformations of Ca3Al2Si3O12 grossular garnet to the depths of the Earth's mantle transition zone.2011

    • Author(s)
      S.Greaux
    • Journal Title

      Phys.Earth Planet.Inter.

      Volume: 185 Pages: 89-99

    • Peer Reviewed
  • [Journal Article] Tuning of structure, morphology and magnetism in postperovskite oxide solid solutions.2011

    • Author(s)
      S.Hirai
    • Journal Title

      Chem.Mater.

      Volume: 23 Pages: 114-121

    • Peer Reviewed
  • [Journal Article] Effect of hydrogen on the melting temperature of FeS at high pressure : Implications for the core of Ganymede.2011

    • Author(s)
      Y.Shibazaki
    • Journal Title

      Earth Planet.Sci.Lett.

      Volume: 301 Pages: 153-158

    • Peer Reviewed
  • [Journal Article] First principles prediction of post-pyrite phase transitions in germanium dioxide.2011

    • Author(s)
      H.Dekura
    • Journal Title

      Phys.Rev.B

      Volume: 83 Pages: 134114

    • Peer Reviewed
  • [Journal Article] First principles prediction of a high-pressure hydrous phase of AlOOH.2011

    • Author(s)
      J.Tsuchiya
    • Journal Title

      Phys.Rev.B.

      Volume: 83 Pages: 054115

    • Peer Reviewed
  • [Journal Article] Prediction of a hexagonal SiO2 phase affecting stabilities of MgSiO3 and CaSiO3 at multimegabar pressures.2011

    • Author(s)
      T.Tsuchiya
    • Journal Title

      Proc.Ntnl.Acad.Sci.

      Volume: 108 Pages: 1252-1255

    • Peer Reviewed
  • [Journal Article] 鉄系物質の第一原理研究2011

    • Author(s)
      石河孝洋
    • Journal Title

      高圧力の科学と技術

      Volume: (In press)

    • Peer Reviewed
  • [Journal Article] Thermal equation of state of CaIrO3 post-perovskite2011

    • Author(s)
      W.Liu
    • Journal Title

      Phys.Chem.Mineral.

      Volume: (In press)

    • Peer Reviewed
  • [Journal Article] Volume and structural study of Fe64Mn36 anti-ferromagnetic Invar alloy under high pressure.2011

    • Author(s)
      M.Matsushita
    • Journal Title

      Journal of Magnetism and Magnetic Materials

      Volume: 323 Pages: 838-841

    • Peer Reviewed
  • [Journal Article] フランボイダルパイライトー天然における鉱物の不思議な自己組織化作用2011

    • Author(s)
      大藤弘明
    • Journal Title

      日本結晶学会誌

      Volume: 53 Pages: 46-51

    • Peer Reviewed
  • [Journal Article] Phase boundary between perovskite and post-perovskite structures in MnGeO3 determined by in situ X-ray diffraction measurements using sintered diamond anvils.2011

    • Author(s)
      D.Yamazaki
    • Journal Title

      Am.Mineral.

      Volume: 96 Pages: 89-92

    • Peer Reviewed
  • [Journal Article] Effect of iron content on electrical conductivity of ferro-periclase with implications for the spin transition pressure.2011

    • Author(s)
      H.Terasaki
    • Journal Title

      J.Geophys.Res.

      Volume: 116 Pages: B04202

    • Peer Reviewed
  • [Journal Article] Micro-/nanostructural investigation of laser-cut surfaces of single- and polycrystalline diamonds.2010

    • Author(s)
      H.Ohfuji
    • Journal Title

      Diamond Rel.Mat.

      Volume: 19 Pages: 1040-1051

    • Peer Reviewed
  • [Journal Article] P-V-T relation of MgO derived by simultaneous elastic wave velocity and in situ X-ray measurements : A new pressure scale for the mantle transition region.2010

    • Author(s)
      Y.Kono
    • Journal Title

      Phys.Earth Planet.Inter.

      Volume: 183 Pages: 196-211

    • Peer Reviewed
  • [Journal Article] Pressure and temperature Dependences of Elastic Properties of Grossular Garnet up to 17 GPa and 1650 K.2010

    • Author(s)
      Y.Kono
    • Journal Title

      J.Earth Sci.

      Volume: 21 Pages: 782-791

    • Peer Reviewed
  • [Journal Article] Elastic wave velocities of silica glass at high temperatures and high pressures.2010

    • Author(s)
      A.Yokoyama
    • Journal Title

      J.Appl.Phys.

      Volume: 107 Pages: 123530

    • Peer Reviewed
  • [Journal Article] Technical Development of Simple Shear Deformation Experiments Using a Deformation-DIA Apparatus.2010

    • Author(s)
      T.Ohuchi
    • Journal Title

      J.Earth Sci.

      Volume: 21 Pages: 523-531

    • Peer Reviewed
  • [Journal Article] Preliminary deformation experiment of ringwoodite at 20 GPa and 1700 K using a D-DIA apparatus.2010

    • Author(s)
      T.Kawazoe
    • Journal Title

      J.Earth Sci.

      Volume: 21 Pages: 517-522

    • Peer Reviewed
  • [Journal Article] CaCu3Pt4O12 : The First Perovskite with the B Site Fully Occupied by Pt4+.2010

    • Author(s)
      I.Yamada
    • Journal Title

      Inorg.Chem.

      Volume: 49 Pages: 6778-6780

    • Peer Reviewed
  • [Journal Article] Cation order-disorder phase transitions in LiGaO2 : Observation of the pathways of ternary wurtzite under high pressure.2010

    • Author(s)
      L.Lei
    • Journal Title

      J.Appl.Phys.

      Volume: 108 Pages: 083531

    • Peer Reviewed
  • [Journal Article] Deformation experiment at P-T conditions of the mantle transition zone using D-DIA apparatus.2010

    • Author(s)
      T.Kawazoe
    • Journal Title

      Phys.Earth Planet.Inter.

      Volume: 183 Pages: 190-195

    • Peer Reviewed
  • [Journal Article] 新型大容量D-DIA装置とKMA装置による高圧地球物質科学の新しい展開2010

    • Author(s)
      入舩徹男
    • Journal Title

      高圧力の科学と技術

      Volume: 20 Pages: 158-165

    • Peer Reviewed
  • [Journal Article] 大型ナノ多結晶ダイヤモンド対向アンビルを用いた高圧下パルス中性子粉末回折実験2010

    • Author(s)
      奥地拓生
    • Journal Title

      高圧力の科学と技術

      Volume: 20 Pages: 175-178

    • Peer Reviewed
  • [Journal Article] A dense yttria phase eclipsing the A-type sesquioxide structure : high-pressure experiments and ab initio calculations.2010

    • Author(s)
      H.Yusa
    • Journal Title

      Inorg.Chem.

      Volume: 49 Pages: 4478-4485

    • Peer Reviewed
  • [Journal Article] Ab Initio Two Phase Molecular Dynamics on the Melting Curve of SiO2.2010

    • Author(s)
      Y.Usui
    • Journal Title

      J.Earth Sci.

      Volume: 21 Pages: 801-810

    • Peer Reviewed
  • [Journal Article] Ab initio investigation of high-pressure phase relation and elasticity in the NaAlSi2O6 system.2010

    • Author(s)
      K.Kawai
    • Journal Title

      Geophys.Res.Lett.

      Volume: 37 Pages: L17302

    • Peer Reviewed
  • [Journal Article] 第2大陸2010

    • Author(s)
      河合研志
    • Journal Title

      地学雑誌

      Volume: 119 Pages: 1197-1214

    • Peer Reviewed
  • [Journal Article] スケールフリー統合解析のすすめ2010

    • Author(s)
      丹下慶範
    • Journal Title

      高圧力の科学と技術

      Volume: 20 Pages: 210-220

    • Peer Reviewed
  • [Journal Article] Stress relaxation experiments of olivine under Earth's deep upper mantle conditions2010

    • Author(s)
      Y.Nishihara
    • Journal Title

      Physi.Earth Planet.Inter.

      Volume: 183 Pages: 164-174

    • Peer Reviewed
  • [Journal Article] Analysis of the recrystallization of cold-rolled copper after isothermal annealing using electron backscattered diffraction patterns.2010

    • Author(s)
      M.Matsushita
    • Journal Title

      Defect and Diffusion Forum

      Volume: 359 Pages: 359-364

    • Peer Reviewed
  • [Journal Article] 冷間圧延された銅版の等温再結晶課程のEBSDによる観察2010

    • Author(s)
      松下正史
    • Journal Title

      銅と銅合金

      Volume: 49 Pages: 56-60

    • Peer Reviewed
  • [Journal Article] Pressure generation and investigation of the post-perovskite transformation in MgGeO3 by squeezing the Kawai-cell equipped with sintered diamond anvils.2010

    • Author(s)
      E.Ito
    • Journal Title

      Earth Planet.Sci.Lett.

      Volume: 293 Pages: 84-89

    • Peer Reviewed
  • [Journal Article] Mineralogy of the lower mantle investigated using sintered diamond multianvil apparatus.2010

    • Author(s)
      Y.Tange
    • Journal Title

      SPring-8 Research Frontiers 2009

      Pages: 114-115

    • Peer Reviewed
  • [Journal Article] Survival of majoritic garnet in diamond by direct kimberlite ascent from deep mantle.2010

    • Author(s)
      M.Nishi
    • Journal Title

      Geophys.Res.Lett.

      Volume: 37 Pages: L09305

    • Peer Reviewed
  • [Presentation] Synthesis, properties, and applications of ultrahard nano-polycrystalline diamond at high pressure.2011

    • Author(s)
      T.Irifune
    • Organizer
      Seminar, Inst.Earth Sci., National Chen-Kung Univ
    • Place of Presentation
      Taiwan, China
    • Year and Date
      2011-03-24
  • [Presentation] HIME-DIA : potential 3rd generation anvil material for deep Earth mineralogy.2011

    • Author(s)
      T.Irifune
    • Organizer
      Dynamics of the Earth's Interior Symposium
    • Place of Presentation
      Sendai, Miyagi
    • Year and Date
      2011-02-15
  • [Presentation] Multimegabar phase relations of earth and planetary materials.2011

    • Author(s)
      T.Tsuchiya
    • Organizer
      3rd Japan-France Workshop and School on High Energy Density Science
    • Place of Presentation
      Les Houches, France
    • Year and Date
      2011-01-10
  • [Presentation] Nano-polycrystalline diamond : a potential third-generation ultrahard material for LVP experiments2010

    • Author(s)
      T.Irifune
    • Organizer
      Workshop for Extreme Conditions Research in a Large Volume Press at PETRA II
    • Place of Presentation
      Luneburg, Germany
    • Year and Date
      20101014-20101015
  • [Presentation] P-V-T equation of state of MgSiO3 perovskite up to 110 GPa and 2500 K : Primary reference for the mineralogy of the lower mantle.2010

    • Author(s)
      Y.Tange
    • Organizer
      American Geophysical Union Fall Meeting 2010
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2010-12-16
  • [Presentation] Fe distribution between (post-)perovskite and ferropericlase.2010

    • Author(s)
      T.Tsuchiya
    • Organizer
      American Geophysical Union Fall Meeting 2010
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2010-12-16
  • [Presentation] Crystal structure of iron-rich iron-alloys under the Earth's core conditions.2010

    • Author(s)
      Y.Kuwayama
    • Organizer
      American Geophysical Union Fall Meeting 2010
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2010-12-16
  • [Presentation] A Novel Dense Phase of Silica Initiating Silicates Breakdown in Giant Terrestrial Planets.2010

    • Author(s)
      T.Tsuchiya
    • Organizer
      American Geophysical Union Fall Meeting 2010
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2010-12-15
  • [Presentation] Ab initio study for Earth and planetary materials.2010

    • Author(s)
      T.Tsuchiya
    • Organizer
      Seminar, Dept.Geol., Peking University
    • Place of Presentation
      Peking, China
    • Year and Date
      2010-11-09
  • [Presentation] Phase relations in harzburgite : stagnation of harzburgite and interpretation of multiple seismic discontinuities in mantle transition zone.2010

    • Author(s)
      N.Nishiyama
    • Organizer
      The 2010 TANDEM Symposium on deep Earth mineralogy
    • Place of Presentation
      Wuhan, China
    • Year and Date
      2010-11-06
  • [Presentation] Influence of graphite crystallinity on the microtexture of nanopolycrystalline diamond obtained by direct conversion.2010

    • Author(s)
      H.Ohfuji
    • Organizer
      The 2010 TANDEM Symposium on deep Earth mineralogy
    • Place of Presentation
      Wuhan, China
    • Year and Date
      2010-11-06
  • [Presentation] P-V-T equation of state of MgSiO3 perovskite up to 110 GPa and 2500 K : Primary reference for the mineralogy of the lower Mantle.2010

    • Author(s)
      Y.Tange
    • Organizer
      The 2010 TANDEM Symposium on deep Earth mineralogy
    • Place of Presentation
      Wuhan, China
    • Year and Date
      2010-11-06
  • [Presentation] SOSEKI laboratory and new developments in multianvil technology2010

    • Author(s)
      T.Irifune
    • Organizer
      The 2010 TANDEM Symposium on deep Earth mineralogy
    • Place of Presentation
      Wuhan, China
    • Year and Date
      2010-11-05
  • [Presentation] Ab initio modeling of the deep mantle heterogeneity2010

    • Author(s)
      T.Tsuchiya
    • Organizer
      The 2010 TANDEM Symposium on deep Earth mineralogy
    • Place of Presentation
      Wuhan, China
    • Year and Date
      2010-11-05
  • [Presentation] マルチアンビル実験技術の高度化と下部マントル条件下でのレオロジー・弾性波速度・相関係の精密決定2010

    • Author(s)
      入舩徹男
    • Organizer
      第14回SPring-8シンポジウム
    • Place of Presentation
      千代田区,東京
    • Year and Date
      2010-11-04
  • [Presentation] MgSiO3ペロブスカイトのP-V-T状態方程式2010

    • Author(s)
      丹下慶範
    • Organizer
      第51回高圧討論会
    • Place of Presentation
      仙台,宮城
    • Year and Date
      2010-10-22
  • [Presentation] 大容量KMA合成装置"BOTCHAN-6000"の概要2010

    • Author(s)
      入舩徹男
    • Organizer
      第51回高圧討論会
    • Place of Presentation
      仙台,宮城
    • Year and Date
      2010-10-22
  • [Presentation] 大容量DDIA装置"MADONNA"の概要2010

    • Author(s)
      西山宣正
    • Organizer
      第51回高圧討論会
    • Place of Presentation
      仙台,宮城
    • Year and Date
      2010-10-22
  • [Presentation] 下部マントル条件に至る弾性波速度測定技術の開発2010

    • Author(s)
      肥後祐司
    • Organizer
      第51回高圧討論会
    • Place of Presentation
      仙台,宮城
    • Year and Date
      2010-10-21
  • [Presentation] 大容量超高圧鉱物合成装置BOTCHAN-6000の概要と応用2010

    • Author(s)
      入舩徹男
    • Organizer
      日本鉱物科学会2010年年会
    • Place of Presentation
      松江,島根
    • Year and Date
      2010-09-25
  • [Presentation] グラファイト-ダイヤモンド直接変換焼結におけるグラファイトの結晶度の影響2010

    • Author(s)
      大藤弘明
    • Organizer
      東京工業大学応用セラミクス研究所共同利用研究ワークショップ
    • Place of Presentation
      目黒区,東京
    • Year and Date
      2010-09-10
  • [Presentation] Phase transitiona and sound velocities of mantle and slab slab materials : implicatio the composition of the ransition region2010

    • Author(s)
      T.Irifune
    • Organizer
      Seminar, Bayerisches Geoinstitut
    • Place of Presentation
      Bayreuth, Germany
    • Year and Date
      2010-09-01
  • [Presentation] Recent progress in nano-polycristalline diamond project : syntjesis, physical, propertoes, and applicatopns2010

    • Author(s)
      T.Irifune
    • Organizer
      Seminar, Bayerisches Geoinstitut
    • Place of Presentation
      Bayreuth, Germany
    • Year and Date
      2010-09-01
  • [Presentation] Prediction of turbostratic iron from first-principles2010

    • Author(s)
      T.Ishikawa
    • Organizer
      IMA2010
    • Place of Presentation
      Budapest, Hungary
    • Year and Date
      2010-08-26
  • [Presentation] Phase transitions, densities, and sound velocities of mantle and slab materials down to the upper part of the lower mantle.2010

    • Author(s)
      T.Irifune
    • Organizer
      IMA 2010
    • Place of Presentation
      Budapest, Hungary
    • Year and Date
      2010-08-25
  • [Presentation] A new dense phase of silica initiating silicates breakdown in giant terrestrial planets.2010

    • Author(s)
      T.Tsuchiya
    • Organizer
      IMA2010
    • Place of Presentation
      Budapest, Hungary
    • Year and Date
      2010-08-25
  • [Presentation] Synthesis of ultrahard nano-polycrystalline diamond at high pressure and temperature using a large-volume multianvil apparatus.2010

    • Author(s)
      T.Irifune
    • Organizer
      IMA 2010
    • Place of Presentation
      Budapest, Hungary
    • Year and Date
      2010-08-23
  • [Presentation] 地球深部の構造・物質・ダイナミクス2010

    • Author(s)
      入舩徹男
    • Organizer
      第45回地盤工学研究発表会特別講演会
    • Place of Presentation
      松山,愛媛
    • Year and Date
      2010-08-19
  • [Presentation] Ab initio modeling of thermal chemical properties of the core-mantle boundary region.2010

    • Author(s)
      T.Tsuchiya
    • Organizer
      The 12th Symposium of SEDI
    • Place of Presentation
      Santa Barbara, California, USA
    • Year and Date
      2010-07-21
  • [Presentation] Constitutions and compositions of the mantle transition region and the upper part of the lower mantle.2010

    • Author(s)
      T.Irifune
    • Organizer
      010 Western Pacific Geophysics Meeting
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2010-06-22
  • [Presentation] A new dense phase of silica initiating silicates breakdown in giant terrestrial planets.2010

    • Author(s)
      T.Tsuchiya
    • Organizer
      2010 Western Pacific Geophysics Meeting
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2010-06-21
  • [Presentation] A new dence phase of silica initiating silicates breakdown in super-Earths.2010

    • Author(s)
      T.Tsuchiya
    • Organizer
      Japan Geoscience Union Meeting 2010
    • Place of Presentation
      Chiba, Japan
    • Year and Date
      2010-05-28
  • [Presentation] Nature and application of nano-polycrystalline diamond synthesized by direct conversion in large-volume multianvil apparatus.2010

    • Author(s)
      T.Irifune
    • Organizer
      4th International Conference on New Diamond and Nano Carbons (NDNC2010)
    • Place of Presentation
      Suzhou, China
    • Year and Date
      2010-05-27
  • [Presentation] Phase relaions, Fe partitioning, and density changes in pyrolite under the lower mantle P-T conditions.2010

    • Author(s)
      T.Irifune
    • Organizer
      Japan Geoscience Union Meeting 2010, Chiba
    • Place of Presentation
      Chiba, Japan
    • Year and Date
      2010-05-25
  • [Presentation] Synthesis of "amorphous" diamond from graphite under static high pressure and high temperature.2010

    • Author(s)
      H.Ohfuji
    • Organizer
      Japan Geoscience Union Meeting 2010
    • Place of Presentation
      Chiba, Japan
    • Year and Date
      2010-05-23
  • [Presentation] High pressure and high temperature synthesis of nano-polycryst aline diamond from various types of polycrystalline graph2010

    • Author(s)
      H.Ohfuji
    • Organizer
      Japan Geoscience Union Meeting 2010
    • Place of Presentation
      Chiba, Japan
    • Year and Date
      2010-05-23
  • [Book] 現代地球科学2011

    • Author(s)
      川上紳一
    • Total Pages
      22-59
    • Publisher
      NHK出版
  • [Book] J.Earth Sci.Special Issue2010

    • Author(s)
      L.F.Dobrzhinetskaya
    • Total Pages
      175-178
    • Publisher
      Springer
  • [Remarks]

    • URL

      http://www.ehime-u.ac.jp/~grc/

URL: 

Published: 2012-07-19  

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