2012 Fiscal Year Final Research Report
Synthesis of Conjugated Polymers with Higher-Ordered Helical Structures in Helicity-Controllable Liquid Crystal Field and Their Functional Properties
Project/Area Number |
20225007
|
Research Category |
Grant-in-Aid for Scientific Research (S)
|
Allocation Type | Single-year Grants |
Research Field |
Polymer chemistry
|
Research Institution | Kyoto University |
Principal Investigator |
AKAGI Kazuo 京都大学, 工学研究科, 教授 (20150964)
|
Co-Investigator(Kenkyū-buntansha) |
GOH Munju 京都大学, 工学研究科, 助教 (80553966)
|
Co-Investigator(Renkei-kenkyūsha) |
KYOTANI Mutsumasa 筑波大学, 学際物質科学研究センター, 客員研究員 (30570080)
|
Project Period (FY) |
2008 – 2012
|
Keywords | 機能性高分子 / らせん制御 / 液晶場 / ヘリカル構造 / 共役ポリマー / 機能発現 |
Research Abstract |
We created chiral LC fields with thermally or optically controlled helicity. We dynamically controlled helical sense of helical polyacetylene and helical polyethylenedioxythiophene (PEDOT) that were synthesized through chemical and electrochemical polymerizations in the chiral LC fields, respectively. We achieved the control of helicity and circularly polarized luminescence of helical conjugated polymers using external forces.
|
Research Products
(60 results)