2010 Fiscal Year Final Research Report
Development of Novel Synthetic Method using C-H and C-Heteroatom bond Functionalization
| Project/Area Number |
20350019
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
KURAHASHI Takuya 京都大学, 大学院・工学研究科, 助教 (50432365)
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| Project Period (FY) |
2008 – 2010
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| Keywords | 複素環 / ニッケル / 環化付加 |
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| Research Abstract |
A nickelacycle, which was formed from easily available carbonyl compounds and nickel(0) via oxidative insertion and decarbonylation, added to an alkyne to produce the corresponding heterocyclic compound. It was found that phthalic imide gives tha isoquinolone ; phthalic anhydride gives the isochromenone.
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