2010 Fiscal Year Final Research Report
Stimuli-response microsphere possessing information exchange and functional control
| Project/Area Number |
20560706
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Properties in chemical engineering process/Transfer operation/Unit operation
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| Research Institution | Kagoshima University |
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Principal Investigator |
YOSHIDA Masahiro Kagoshima University, 理工学研究科(工学系), 教授 (50315397)
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| Co-Investigator(Kenkyū-buntansha) |
AIKO Ryoko 鹿児島大学, 理工学研究科, 教務職員 (50244265)
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| Project Period (FY) |
2008 – 2010
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| Keywords | 液晶 / ミクロスフェア / 電場刺激 / 分子インプリント / In situ重合 |
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| Research Abstract |
An enantio-selective microsphere was prepared by the molecular imprinting technique for the separation of optically active Fmoc-PheOH. A synthetic ferroelectric liquid crystal monomer (functional monomer) responds to external electrical field possessing mesogenic group, spontaneous polarization property and chiral moiety was found to be effective for recognizing the chirality of amino acid derivative. The Fmoc-D-PheOH-imprinted microsphere containing the functional monomer reveals high enantio-selectivity toward the corresponding imprinted isomer compared to selectivity of another one in the electrical field.
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