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2009 Fiscal Year Final Research Report

Synthesis of Hetero and Chiral Buckybowls

Research Project

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Project/Area Number 20750039
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Organic chemistry
Research InstitutionInstitute for Molecular Science

Principal Investigator

HIGASHIBAYASHI Shuhei  Institute for Molecular Science, 分子スケールナノサイエンスセンター, 助教 (30338264)

Project Period (FY) 2008 – 2009
Keywords有機合成化学 / 構造有機化学
Research Abstract

Buckybowls are bowl-shaped hydrocarbons possessing interesting physical properties and possible candidates for new materials such as related fullerenes. New synthetic methodologies to prepare chiral buckybowls with right-or left-handed structure, heterobuckybowls having non-carbon elements, and substituted buckybowls have been developed. The physical properties have been elucidated as well.

  • Research Products

    (20 results)

All 2010 2009 2008 Other

All Journal Article (5 results) (of which Peer Reviewed: 4 results) Presentation (13 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Optical Resolution of Chiral Buckybowls by Chiral HPLC2010

    • Author(s)
      Ryoji Tsuruoka、Shuhei Higashibayashi、Takeharu Ishikawa、Shinji Toyota、Hidehiro Sakurai
    • Journal Title

      Chem. Let 39

      Pages: 646-647

    • Peer Reviewed
  • [Journal Article] Prepartion of C3-Symmetric Homochiral syn-Trisnorbornabenzenes through Regioselective Cyclotrimerization of Enantiopure Iodonorbornenes2009

    • Author(s)
      A.F.G. Masud Reza、Shuhei Higashibayashi、Hidehiro Sakurai
    • Journal Title

      Chem. Asian J. 4

      Pages: 1329-1337

    • Peer Reviewed
  • [Journal Article] おわん型共役炭素化合物バッキーボウルの合成2009

    • Author(s)
      東林修平
    • Journal Title

      有機合成化学協会誌 67

      Pages: 38-50

  • [Journal Article] Asymmetric Synthesis of a Chiral Buckybowl, Trimethylsumanene2008

    • Author(s)
      Shuhei Higashibayashi、Hidehiro Sakurai
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 8592-8593

    • Peer Reviewed
  • [Journal Article] Stereoselective Cyclotrimerization of Enantiopure Iodonorbornenes Catalyzed by Pd Nanoclusters for C3 or C3v Symmetric syn-Tris(norborneno)benzenes

    • Author(s)
      Shuhei Higashibayashi、A.F.G. Masud Reza、Hidehiro Sakurai
    • Journal Title

      J. Org. Chem (in press)

    • Peer Reviewed
  • [Presentation] パラジウム触媒を用いた環化三量化反応によるC3対称syn-トリス(ノルボルネノ)ベンゼンの合成2010

    • Author(s)
      東林修平、櫻井英博
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪)
    • Year and Date
      20100326-20100329
  • [Presentation] 光学活性7-アザノルボルナン-2-オン誘導体の合成2010

    • Author(s)
      小野木覚、東林修平、櫻井英博
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪)
    • Year and Date
      20100326-20100329
  • [Presentation] C3対称バッキーボウルの液相合成法の開発2010

    • Author(s)
      東林修平
    • Organizer
      日本化学会第90春季年会「若い世代の特別講演会」
    • Place of Presentation
      近畿大学(大阪)
    • Year and Date
      20100326-20100329
  • [Presentation] 光学活性バッキーボウルのキラルHPLCによる光学分割およびCDスペクトルを用いたボウル反転エネルギーの測定2010

    • Author(s)
      寉岡亮治、東林修平、石川丈晴、豊田真司、櫻井英博
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪)
    • Year and Date
      20100326-20100329
  • [Presentation] Synthesis of C3 Symmetric Buckybowls2010

    • Author(s)
      東林修平、櫻井英博
    • Organizer
      第6回平田記念レクチャー(名古屋大学G-COE・RCMS有機化学国際シンポジウム)
    • Place of Presentation
      名古屋大学(名古屋)
    • Year and Date
      2010-01-12
  • [Presentation] Asymmetric Synthesis of Chiral Buckybowls2009

    • Author(s)
      東林修平
    • Organizer
      IMS-RIKEN International Symposium on Chemistry and Material Science
    • Place of Presentation
      分子科学研究所(愛知)
    • Year and Date
      20091101-20091103
  • [Presentation] パラジウム触媒を用いた環化三量化反応によるC3対称syn-トリス(ノルボルネノ)ベンゼンの合成2009

    • Author(s)
      東林修平、櫻井英博
    • Organizer
      第20回基礎有機化学討論会
    • Place of Presentation
      群馬大学(群馬)
    • Year and Date
      20090928-20090930
  • [Presentation] Preparation of C3 Symmetricπ-Conjugated homochiral Molecules2009

    • Author(s)
      A.F.G. Masud Reza、東林修平、櫻井英博
    • Organizer
      The 13th Asian Chemical Congress
    • Place of Presentation
      上海(中国)
    • Year and Date
      20090914-20090916
  • [Presentation] Asymmetric Synthesis of Chiral Buckybowls2009

    • Author(s)
      東林修平、A.F.G. Masud Reza、石川丈晴、豊田真司、櫻井英博
    • Organizer
      13th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      ルクセンブルク
    • Year and Date
      20090719-20090724
  • [Presentation] C3対称π共役化合物の不斉合成2009

    • Author(s)
      A.F.G. Masud Reza、東林修平、櫻井英博
    • Organizer
      日本化学会第89春期年会
    • Place of Presentation
      日本大学(船橋)
    • Year and Date
      20090327-20090330
  • [Presentation] Synthesis of C3 Symmetricπ-Conjugated Molecules2008

    • Author(s)
      A.F.G. Masud Reza、東林修平、櫻井英博
    • Organizer
      第39回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      名古屋大学(名古屋)
    • Year and Date
      20081108-20091109
  • [Presentation] Asymmetric Synthesis of C3 Symmetric Chiral Buckybowls、Chirality 20082008

    • Author(s)
      東林修平、A.F.G. Masud Reza、櫻井英博
    • Organizer
      20th International Symposium on Chirality
    • Place of Presentation
      ジュネーブ(スイス)
    • Year and Date
      20080706-20080709
  • [Presentation] Synthesis of C3v Symmetric Chiral Buckybowls2008

    • Author(s)
      東林修平、A.F.G. Masud Reza、櫻井英博
    • Organizer
      17th International Conference on Organic Synthesis
    • Place of Presentation
      デジョン(韓国)
    • Year and Date
      20080622-20080627
  • [Book] 使える!有機合成反応241実践ガイド2010

    • Author(s)
      東林修平, 他
    • Total Pages
      86-87
  • [Remarks] 日刊工業新聞、『「バッキーボウル」の端部、選択的に官能基合成』、2007年4月20日、33面

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Published: 2011-06-18   Modified: 2016-04-21  

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