2009 Fiscal Year Final Research Report
Development of Catalytic Cyclization Reaction for the Construction of Oxindole Ring System
| Project/Area Number |
20750078
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
TOMOYA Miura Kyoto University, 大学院・工学研究科, 講師 (10378804)
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| Project Period (FY) |
2008 – 2009
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| Keywords | 合成化学 / 有機化学 / 有機工業化学 |
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| Research Abstract |
A new cyclization reaction occurred on treatment of 2-(alkynyl)aryl isocyanates with various nucleophiles such as organoboronic acids, amides, alcohols, and thiols in the presence of a palladium catalyst, leading to the stereoselective formation of 3-alkylideneoxindoles.
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