2009 Fiscal Year Final Research Report
Synthesis of Strained Macrocyclic Compounds and Their Application to Functionalized Materials
| Project/Area Number |
20750079
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
MIKI Koji Kyoto University, 大学院・工学研究科, 講師 (60422979)
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| Project Period (FY) |
2008 – 2009
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| Keywords | 選択的合成・反応 / 大環状分子合成 / パイ共役系 |
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| Research Abstract |
In this study, tin-mediated reductive aromatization afforded strained π-conjugated cyclynes such as pyridine-containing strained cyclynes and p-phenyleneacetylene derivatives. The former compound emits fluorescence around 500-600 nm with a good quantum yield. The latter compounds can form 1:1 complexes with fullerene derivatives.
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