2009 Fiscal Year Final Research Report
Synthesis of novel fullerene liquid crystals and their charge-transfer delivertives
| Project/Area Number |
20850025
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| Research Category |
Grant-in-Aid for Young Scientists (Start-up)
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| Allocation Type | Single-year Grants |
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| Research Field |
Functional materials/Devices
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| Research Institution | Osaka University |
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Principal Investigator |
IKUMA Naohiko Osaka University, 工学研究科, 助教 (70505990)
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| Research Collaborator |
OSHIMA Takumi 大阪大学, 工学研究科, 教授 (40107082)
KOKUBO Ken 大阪大学, 工学研究科, 講師 (20304008)
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| Project Period (FY) |
2008 – 2009
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| Keywords | 自己組織化 / 電気・電子デバイス / フラーレン / 液晶 |
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| Research Abstract |
To obtain novel fullerene liquid crystals, several fullerene delivertives has been synthesized via four reaction pathways ; (i) Rh-catalytic hydroarylation, (ii) 1,3-dipolar cycloaddition, (iii) Diels-Alder reaction of fulleroid, and (iv) Fridel-Crafts arylation of fullerene oxide. The tharmal analysis of the product from the (iv) pathway indicated some mesomorphic phase transition.
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