2009 Fiscal Year Final Research Report
Development of nitrogen-containing graphene sheets
| Project/Area Number |
20850030
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| Research Category |
Grant-in-Aid for Young Scientists (Start-up)
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Tokyo Metropolitan University |
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Principal Investigator |
TAKASE Masayoshi Tokyo Metropolitan University, 大学院・理工学研究科, 助教 (90516121)
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| Project Period (FY) |
2008 – 2009
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| Keywords | グラフェン / 含窒素グラフェン / π電子共役系 / テトラチアフルバレン / 超分子集合体 |
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| Research Abstract |
We have newly designed and synthesized tri-, tetra-, and hexa-substituted pyrrole-fused TTF derivatives. Self-assembly of these molecules gave fiber and particle structures from proper solutions and their electric conductivities under iodine vapor indicated higher than that of the film state by an order of magnitude. Similar reaction with ditopic TTF derivatives gave insoluble materials probably due to the formation of three-dimensional porous networks.
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