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2013 Fiscal Year Final Research Report

Defect Engineering in SiC and Application to Robust Devices with Ultrahigh Blocking Voltage

Research Project

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Project/Area Number 21226008
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Electronic materials/Electric materials
Research InstitutionKyoto University

Principal Investigator

KIMOTO Tsunenobu  京都大学, 工学(系)研究科(研究院), 教授 (80225078)

Co-Investigator(Kenkyū-buntansha) SUDA Jun  京都大学, 大学院工学研究科, 准教授 (00293887)
NISHI Yusuke  京都大学, 大学院工学研究科, 助教 (10512759)
Project Period (FY) 2009-05-11 – 2014-03-31
Keywords半導体 / パワーデバイス / 結晶欠陥 / キャリア寿命 / 絶縁破壊
Research Abstract

Defect electronics in SiC and ultrahigh-voltage SiC power devices have been studied toward efficient electric power conversion employed for future smart grids. Fast epitaxy of high-purity SiC was developed, and extended defects in SiC epitaxial layers were systematically characterized. Physical properties of the major deep levels were elucidated. The carrier-lifetime killer defects could be eliminated, leading to remarkably enhanced carrier lifetimes. Control of carrier lifetimes was also achieved. Original junction-termination structures were proposed to achieve ultrahigh blocking voltage with SiC, and breakdown mechanism of SiC devices was discussed. By utilizing thick, lightly-doped SiC epitaxial layers and the original device structures, ultrahigh-voltage (> 20 kV) PiN diodes and npn bipolar transistors were realized. The performance was significantly improved by enhancement of carrier lifetimes, and high-temperature operation of SiC devices was demonstrated.

  • Research Products

    (19 results)

All 2013 2012 2011 2010 2009 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (5 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Investigation on origin of Z_<1/2> center in SiC by deep level transient spectroscopy and electron paramagnetic resonance2013

    • Author(s)
      K. Kawahara, X. T. Trinh, N. T. Son, J. Suda, and T. Kimoto
    • Journal Title

      Appl. Phys. Lett

      Volume: 102 Pages: 112106/1-4

    • DOI

      10.1063/1.4796141

    • Peer Reviewed
  • [Journal Article] Ultrahigh-voltage SiC PiN diodes with an improved junction termination extension structure and enhanced carrier lifetime2013

    • Author(s)
      N. Kaji, H. Niwa, J. Suda, and T. Kimoto
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 52 Pages: 070204/1-4

    • DOI

      10.7567/JJAP.52.070204

    • Peer Reviewed
  • [Journal Article] Improvement of carrier lifetimes in highly Al-doped p-type 4H-SiC epitaxial layers by hydrogen passivation2013

    • Author(s)
      T. Okuda, T. Kimoto, and J. Suda
    • Journal Title

      Appl. Phys. Express

      Volume: 6 Pages: 121301/1-3

    • DOI

      10.7567/APEX6.121301

    • Peer Reviewed
  • [Journal Article] 21.7 kV 4H-SiC diode with a space-modulated junction termination extension2012

    • Author(s)
      H. Niwa, J. Suda, and T. Kimoto
    • Journal Title

      Appl. Phys. Exp

      Volume: 5 Pages: 064001/1-3

    • DOI

      10.1143/APEX.5.064001

    • Peer Reviewed
  • [Journal Article] Carrier recombination in n-type 4H-SiC epilayers with long carrier lifetimes2012

    • Author(s)
      S. Ichikawa, K. Kawahara, J. Suda, and T. Kimoto
    • Journal Title

      Appl. Phys. Exp

      Volume: 5 Pages: 101301/1-3

    • DOI

      10.1143/APEX5.101301

    • Peer Reviewed
  • [Journal Article] 21-kV SiC BJTs with space-modulated junction termination extension2012

    • Author(s)
      H. Miyake, T. Okuda, H. Niwa, T. Kimoto, and J. Suda
    • Journal Title

      IEEE Electron Device Lett

      Volume: 33 Pages: 1598-1600

    • DOI

      10.1109/EDL.2012.2215004

    • Peer Reviewed
  • [Journal Article] Analytical model for reduction of deep levels in SiC by thermal oxidation2012

    • Author(s)
      K. Kawahara, J. Suda, and T. Kimoto
    • Journal Title

      J. Appl. Phys

      Volume: 111 Pages: 053710/1-9

    • DOI

      10.1063/1.3692766

    • Peer Reviewed
  • [Journal Article] Space-modulated junction termination extension for ultrahigh-voltage p-i-n diodes in 4H-SiC2012

    • Author(s)
      G. Feng, J. Suda, and T. Kimoto
    • Journal Title

      IEEE Trans. Electron Devices

      Volume: 59 Pages: 414-418

    • DOI

      10.1109/TED.2011.2175486

    • Peer Reviewed
  • [Journal Article] Nonradiative recombination at threading dislocations in 4H-SiC epilayers studied by micro-photoluminescence mapping2011

    • Author(s)
      G. Feng, J. Suda, and T. Kimoto
    • Journal Title

      J. Appl. Phys

      Volume: 110 Pages: 033525/1-5

    • DOI

      10.1063/1.3622336

    • Peer Reviewed
  • [Journal Article] Reduction of deep levels and improvement of carrier lifetime in n-type 4H-SiC by thermal oxidation2009

    • Author(s)
      T. Hiyoshi, and T. Kimoto
    • Journal Title

      Appl. Phys. Exp

      Volume: 2 Pages: 041101/1-3

    • DOI

      10.1143/APEX.2.041101

    • Peer Reviewed
  • [Presentation] Ultrahigh-voltage SiC devices for future power infrastructure2013

    • Author(s)
      T. Kimoto
    • Organizer
      Proc. of 43th Europ. Solid-State Device Research Conf
    • Place of Presentation
      Bucharest
    • Year and Date
      20130916-20
  • [Presentation] Junction technology in SiC for high-voltage power devices2013

    • Author(s)
      T. Kimoto, K. Kawahara, H. Niwa, T. Okuda, and J. Suda
    • Organizer
      Ext. Abstr. of IEEE 13th Int. Workshop on Junction Technology
    • Place of Presentation
      Kyoto
    • Year and Date
      20130606-07
  • [Presentation] "Defect electronics in SiC and fabrication of ultrahigh-voltage bipolar devices2012

    • Author(s)
      T. Kimoto, J. Suda, G. Feng, H. Miyake, K. Kawahara, H. Niwa, S. Ichikawa, and Y. Nishi
    • Organizer
      Electrochemical. Soc. Fall Meeting 2012
    • Place of Presentation
      Honolulu
    • Year and Date
      20121007-10
  • [Presentation] SiC technologies for future energy electronics2010

    • Author(s)
      T. Kimoto
    • Organizer
      Tech. Digests of 2010 VLSI Technology Symp
    • Place of Presentation
      Honolulu
    • Year and Date
      20100614-16
  • [Presentation] Defect control in growth and processing of 4H-SiC for power device applications2009

    • Author(s)
      T. Kimoto, G. Feng, T. Hiyoshi, K. Kawahara, M. Noborio, and J. Suda
    • Organizer
      Int. Conf. on Silicon Carbide and Related Materials 2009
    • Place of Presentation
      Nurnberg
    • Year and Date
      20091011-15
  • [Book] "4H-SiC epitaxial growth and defect characterization", Silicon Carbide Epitaxy 42012

    • Author(s)
      T. Kimoto, G. Feng, K. Danno, T. Hiyoshi and J. Suda
    • Total Pages
      121-144
    • Publisher
      Publisher Research Signpost
  • [Remarks]

    • URL

      http://semicon.kuee.kyoto-u.ac.jp/

  • [Patent(Industrial Property Rights)] 半導体装置の製造方法および熱処理装置2013

    • Inventor(s)
      須田淳、奥田貴史、木本恒暢
    • Industrial Property Rights Holder
      京都大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      特願2013-143504
    • Filing Date
      2013-07-09
  • [Patent(Industrial Property Rights)] 半導体素子及び半導体素子の製造2011

    • Inventor(s)
      木本恒暢、須田淳
    • Industrial Property Rights Holder
      京都大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      特願2011-059992
    • Filing Date
      2011-03-18

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Published: 2015-06-25  

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