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2013 Fiscal Year Final Research Report

Preparation of Completely Individualized Nanofibrils from Biomass, and Their Conversions to Environmentally Compatible Materials

Research Project

  • PDF
Project/Area Number 21228007
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Boundary agriculture
Research InstitutionThe University of Tokyo

Principal Investigator

ISOGAI Akira  東京大学, 農学生命科学研究科, 教授 (40191879)

Co-Investigator(Kenkyū-buntansha) KIMURA Satoshi  東京大学, 大学院・農学生命科学研究科, 助教 (00420224)
IWATA Tadahisa  東京大学, 大学院・農学生命科学研究科, 教授 (30281661)
WADA Masahisa  東京大学, 大学院・農学生命科学研究科, 准教授 (40270897)
IGARASHI Kiyohiko  東京大学, 大学院・農学生命科学研究科, 准教授 (80345181)
SAITO Tsuguyuki  東京大学, 大学院・農学生命科学研究科, 准教授 (90533993)
Project Period (FY) 2009-05-11 – 2014-03-31
Keywordsセルロース / ナノフィブリル / TEMPO / 触媒酸化 / バイオマス / キチン / ナノ材料 / ミクロフィブリル
Research Abstract

The conventional/new TEMPO-mediated oxidations were applied to cellulose and chitin consisting of crystalline microfibrils and curdlan. Chemical structures, nanostructures and molecular weights of the obtained oxidized polysaccharides were elucidated. During these studies, new TEMPO-mediated oxidation mechanisms were made clear. Position-selective and efficient surface medication methods of TEMPO-oxidized nanofibrils via ion-exchange treatment were studied, and switching technologies of the nanofibrils from biodegradable to stable and from hydrophilic to hydrophobic nature were established. New composite materials consisting of the surface-modified nanofibrils were prepared under various conditions, and some of them had quite high mechanical strengths, gas-barrier/gas-selective separation functions, heavy-metal adsorption behavior, and transparent/flexible/conductive properties. Thus, TEMPO-oxidized nanofibrils have versatile potential applications as new bio-based nanomaterials.

  • Research Products

    (19 results)

All 2013 2012 2011 2010 2009 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (5 results) Book (2 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Surface engineering of ultrafine cellulose nanofibrils towards polymer nanocomposite materials2013

    • Author(s)
      Fujisawa, S.; Saito, T.; Kimra, S.; Iwata, T.; Isogai, A.
    • Journal Title

      Biomacromolecules

      Volume: Vol.14 Pages: 1541-1546

    • DOI

      10.1021/bm400178m

    • Peer Reviewed
  • [Journal Article] Transparent, conductive and printable composites consisting of nanocellulose and carbon nanotube2013

    • Author(s)
      Koga, H.; Saito, T.; Kitaoka, T.; Nogi, M.; Suganuma, K.; Isogai, A.
    • Journal Title

      Biomacromolecuoles

      Volume: Vol.14 Pages: 1160-1165

    • DOI

      10.1021/bm400075f

    • Peer Reviewed
  • [Journal Article] An ultrastrong nanofibrillar biomaterial : Strength of single cellulose nanofibrils revealed from sonication- induced fragmentation2013

    • Author(s)
      Saito, T.; Kuramae, R.; Wohlert, J.; Berglund, L. A.; Isogai, A.
    • Journal Title

      Biomacromolecules

      Volume: Vol.14 Pages: 248-253

    • DOI

      10.1021/bm301674e

    • Peer Reviewed
  • [Journal Article] Ultrastrong and high gas-barrier nanocellulose/clay layered composites2012

    • Author(s)
      Wu, C.-N.; Saito, T.; Fujisawa, S.; Fukuzumi, H.; Isogai, A.
    • Journal Title

      Biomacromolecules

      Volume: Vol.13 Pages: 1927-1932

    • DOI

      10.1021/bm300465d

    • Peer Reviewed
  • [Journal Article] Self-aligned integration of native cellulose nanofibrils towards producing diverse bulk materials2011

    • Author(s)
      Saito, T.; Uematsu, T.; Kimura, S.; Enomae, T.; Isogai, A.
    • Journal Title

      Soft Matter

      Volume: Vol.7 Pages: 8804-8809

    • DOI

      10.1039/c1sm06050c

    • Peer Reviewed
  • [Journal Article] TEMPO-oxidized cellulose nanofibers2011

    • Author(s)
      Isogai, A.; Saito, T.; Fukuzumi, H.
    • Journal Title

      Nanoscale

      Volume: Vol.3 Pages: 71-85

    • DOI

      10.1039/c0nr00583e

    • Peer Reviewed
  • [Journal Article] Glucose/glucuronic acid alternating copolysaccharide prepared from TEMPO-oxidized native celluloses by surface-peeling2010

    • Author(s)
      Hirota, M.; Furihata, K.; Saito, T.; Kawada, T.; Isogai, A.
    • Journal Title

      Angewandte Chemie International Edition

      Volume: Vol.49 Pages: 7670-7672

    • DOI

      10.1002/anie.201003848

    • Peer Reviewed
  • [Journal Article] Entire surface oxidation of various cellulose microfibrils by TEMPO-mediated oxidation2010

    • Author(s)
      Okita, Y.; Saito, T.; Isogai, A.
    • Journal Title

      Biomacromolecules

      Volume: Vol.11 Pages: 1696-1700

    • DOI

      10.1021/bm100214b

    • Peer Reviewed
  • [Journal Article] Elastic modulus of single cellulose microfibrils from tunicate measured by atomic force microscopy2009

    • Author(s)
      Iwamoto, S.; Kai, W.; Iwata, T.; Isogai, A.
    • Journal Title

      Biomacromolecules

      Volume: Vol.10 Pages: 2571-2576

    • DOI

      10.1021/bm900520n

    • Peer Reviewed
  • [Journal Article] Individualization of nano-sized plant cellulose fibrils by direct surface carboxylation using TEMPO catalyst under neutral conditions2009

    • Author(s)
      Saito, T.; Hirota, M.; Tamura, N.; Kimura, S.; Heux, L.; Isogai, A.
    • Journal Title

      Biomacromolecules

      Volume: Vol.10 Pages: 1992-1996

    • DOI

      10.1021/bm900414t

    • Peer Reviewed
  • [Presentation] Applications of TEMPOoxidized cellulose nanofibrils as gas-barrier films and bio-based composite materials2013

    • Author(s)
      Isogai, A.
    • Organizer
      EPNOE 2013
    • Place of Presentation
      Nice, France
    • Year and Date
      20131021-25
  • [Presentation] Characteristic properties of composite materials containing TEMPOoxidized cellulose nanofibrils2012

    • Author(s)
      Isogai, A.
    • Organizer
      International Cellulose Conference 2013
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      20121010-12
  • [Presentation] Nanofiber films from wood celluloses : Packaging barrier opportunities2011

    • Author(s)
      Isogai, A.
    • Organizer
      Tappi International Conference on Nanotechnology for Renewable Materials
    • Place of Presentation
      Arlington, USA
    • Year and Date
      20110606-08
  • [Presentation] Benefits and challenges of TEMPO-oxidized cellulose nanofibers2010

    • Author(s)
      Isogai, A.
    • Organizer
      Recent Advances in Fibrillar nanocellulose research
    • Place of Presentation
      Trondheim, Norway
    • Year and Date
      20101116-17
  • [Presentation] Chemistry-assisted individualization of wood cellulose microfibrils2009

    • Author(s)
      Isogai, A.
    • Organizer
      Nanomaterial Workshop
    • Place of Presentation
      Stockholm, Sweden
    • Year and Date
      20091202-03
  • [Book] World Scientific, Pretreatment of cellulose for further processing, in "Handbook of Green Materials; Processing Technologies, Properties and Applications"2013

    • Author(s)
      Isogai, A.
    • Total Pages
      1-20
    • Publisher
      World Scientific
  • [Book] Microfibrillar and nanofibrillar cellulose in "Advances in Pulp and Paper Research Cambridge 2013, Vol. 2"2013

    • Author(s)
      Isogai, A.
    • Total Pages
      737-763
    • Publisher
      Berglund, L. A. FRS
  • [Remarks]

    • URL

      http://psl.fp.a.u-tokyo.ac.jp/

  • [Patent(Industrial Property Rights)] 未公開2011

    • Inventor(s)
      磯貝 明, 齋藤継之, ウ・シュンナン
    • Industrial Property Rights Holder
      国立大学法人東京大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      特願2011-145419
    • Filing Date
      2011-06-30

URL: 

Published: 2015-06-25  

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