2013 Fiscal Year Final Research Report
Hypermolecular Photochirogenesis
| Project/Area Number |
21245011
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
INOUE Yoshihisa 大阪大学, 工学(系)研究科(研究院), 教授 (30112543)
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| Co-Investigator(Kenkyū-buntansha) |
森 直 大阪大学, 大学院・工学研究科 (70311769)
楊 成 大阪大学, 大学院・工学研究科 (70456995)
福原 学 大阪大学, 大学院・工学研究科 (30505996)
西嶋 政樹 大阪大学, 産学連携本部 (70448017)
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| Project Period (FY) |
2009-04-01 – 2014-03-31
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| Keywords | 有機光化学 / 超分子化学 / 不斉合成 / 複合超分子 |
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| Research Abstract |
In this study, we first elucidated the chiral properties, guest affinities, and photochirogenic performances of inorganic, organic, and biological supramolecular systems, and then developed various novel chiral supramolecular combination systems and established the multidimensional control strategies, which were jointly applied to several photochirogenic reactions to ultimately achieve unprecedentedly high optical yields of up to 99%, which has been a sort of dream for researchers working in this area of science. We published 97 original papers and reviews as well as the first book on this new interdisciplinary area at the intersection of photochemistry, supramolecular chemistry, and asymmetric synthesis to enhance its visibility in science community.
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