2011 Fiscal Year Final Research Report
Control and Functions of Two-Dimensional Molecular Crystals at Solid Liquid Interfaces Based on Precise Molecular Design
| Project/Area Number |
21245012
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
TOBE Yoshito 大阪大学, 基礎工学研究科, 教授 (60127264)
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| Co-Investigator(Kenkyū-buntansha) |
HIROSE Keiji 大阪大学, 大学院・基礎工学研究科, 准教授 (10252628)
TAHARA Kazukni 大阪大学, 大学院・基礎工学研究科, 助教 (40432463)
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| Project Period (FY) |
2009 – 2011
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| Keywords | 2次元結晶光学 / 自己組織化 / 走査プローブ顕微鏡 / パイ共役系 / 分子認識 / 有機合成化学 |
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| Research Abstract |
This research was undertaken aiming at the elucidation of guiding principles for constructing programmed two-dimensional molecular networks on solid surfaces and thus exploring the undeveloped field of two-dimensional crystal engineering. Through experimentations, the following unprecedented results were uncovered :(1) complex two-dimensional crystals(molecular mosaics) consisting of multiple components including the one composed by four components were achieved,(2) guiding principles for control of two-dimensional crystal structures were elucidated by constructing thermodynamic models for the control, and(3) functions of pores formed in two-dimensional crystals as molecular binding sites as well as chemical reaction sites were developed.
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[Journal Article] One Building Block, Two Different Nanoporous Self-Assembled Monolayers : A Combined STM and Monte Carlo Study2012
Author(s)
Adisoejoso, J.; Tahara, K.; Lei, S.; Szabelski, P.; Rzysko, W.; Inukai, K.; Blunt, M.; Tobe, Y
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Journal Title
De Feyter, S., ACS Nano
Volume: 6
Pages: 897-903
DOI
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