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2011 Fiscal Year Final Research Report

Fundamental Study on the Establishment of Innovative System on Hydrogen Storage and Transportation using Lithium Hydride.

Research Project

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Project/Area Number 21246113
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Metal making engineering
Research InstitutionTohoku University

Principal Investigator

SATO Yuzuru  東北大学, 大学院・工学研究科, 教授 (80108464)

Co-Investigator(Kenkyū-buntansha) TAKEDA Osamu  東北大学, 大学院・工学研究科, 助教 (60447141)
TAKENAKA Toshihide  関西大学, 大学院・理工学研究科, 教授 (60197324)
YAMAGUCHI Katsunori  岩手大学, 工学部, 教授 (70220259)
UEDA Mikito  北海道大学, 大学院・工学研究科, 准教授 (00292053)
Project Period (FY) 2009 – 2011
Keywords水素貯蔵・輸送 / 水素化リチウム / 溶融塩電解 / 水素化反応
Research Abstract

Hydrogen energy is widely developed recently from the viewpoint of efficient energy utilization and the environmental conservation such as a fuel cell technology. However, efficient methods for the storage and transportation are not yet established due the lower density and extremely low boiling temperature of hydrogen. Therefore, authors made an offer new method for the storage and transportation using lithium hydride, LiH at room temperature. Metallic lithium is let to react with hydrogen to form lithium hydride and is transported to the place on demand. The hydrogen is generated by reacting of LiH with water vapor. Then, LiOH is generated as a by-product of the reaction and must be returned to produce metallic lithium for establishing the whole cycle of hydrogen utilization using LiH. In this study, lithium production from LiOH through the molten salt electrolysis was successfully developed, and the mechanism of the reaction of metallic lithium with hydro- gen was made clear.

  • Research Products

    (25 results)

All 2013 2012 2011 2010 2009

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (22 results) Book (1 results)

  • [Journal Article] Anodic Reactions on Some Materials in LiCl-KCl Melt2012

    • Author(s)
      T.Takenaka, M. Umehara, D.Araki and T.Morishige
    • Journal Title

      ECS Transaction

      Volume: Vol.50(11) Pages: 127-134

    • Peer Reviewed
  • [Journal Article] Electrowinning of Lithium from Molten Salt Containing LiOH for Hydrogen Storage and Transportation2010

    • Author(s)
      O.Takeda, M.Li, M.Hoshi and Y.Sato
    • Journal Title

      ECS Transaction

      Volume: Vol.33(7) Pages: 455-462

    • Peer Reviewed
  • [Presentation] 金属リチウムの水素吸蔵速度2013

    • Author(s)
      竹田修、鈴木悠、佐藤讓
    • Organizer
      日本鉄鋼協会第165回春期講演大会
    • Place of Presentation
      東京
    • Year and Date
      20130327-29
  • [Presentation] 溶融LiCl-KCl浴中における金属霧の発生についての調査2013

    • Author(s)
      高柳亮介,森重大樹,竹中俊英
    • Organizer
      日本金属学会2013年春期第152回演大会
    • Place of Presentation
      東京
    • Year and Date
      20130327-29
  • [Presentation] Electrowinning of Li from LiOH by BDD anode and tungsten cathode2012

    • Author(s)
      K.Yoshida, M.Ueda, T.Ohtsuka
    • Organizer
      4th Asian Conference on Molten Salt Chemistry and Technology
    • Place of Presentation
      Matsushima, Japan
    • Year and Date
      20120923-27
  • [Presentation] Formation Rate and Mechanism of LiH by Reacting Li with Hydrogen2012

    • Author(s)
      Y.Suzuki, O.Takeda and Y.Sato
    • Organizer
      4th Asian Conference on Molten Salt Chemistry and Technology
    • Place of Presentation
      Matsushima, Japan
    • Year and Date
      20120923-27
  • [Presentation] Anodic Reaction on Carbon Materials in LiCl-KCl Melt2012

    • Author(s)
      M.Umehara, T.Morishige and T.Takenaka
    • Organizer
      44th Symposium on Molten salt Chemistry, Japan
    • Place of Presentation
      Matsushima, Japan
    • Year and Date
      20120923-27
  • [Presentation] Anodic Behavior of Ti Electrode in Eu- tectic LiCl-KCl Melt2012

    • Author(s)
      D.Araki, T.Morishige and T.Takenaka
    • Organizer
      44th Symposium on Molten salt Chemistry, Japan
    • Place of Presentation
      Matsushima, Japan
    • Year and Date
      20120923-27
  • [Presentation] Evaluation for metal based anode in LiCl-KCl molten salt electrolysis2012

    • Author(s)
      T.Morishige, D.Araki, M.Umehara and T.Takenaka
    • Organizer
      7th Interational Sympo- sium in Science and Technology
    • Place of Presentation
      Penang, Malaysia
    • Year and Date
      20120820-24
  • [Presentation] Phase Equilibria of Li-H System and Rate of Formation of LiH2012

    • Author(s)
      Y.Suzuki, N.Ouchi, O.Takeda and Y.Sato
    • Organizer
      18th Symposium on Thermophysical Prop- erties
    • Place of Presentation
      Boulder, USA
    • Year and Date
      20120624-29
  • [Presentation] LiOH-LiCl溶融塩中におけるBDD電極上の酸素発生反応2012

    • Author(s)
      吉田健一郎、上田幹人、大塚俊明
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      浜松
    • Year and Date
      20120329-31
  • [Presentation] LiOHを添加した塩化物溶融塩中のアノード反応2012

    • Author(s)
      東間崇洋、竹田修、星政義、佐藤讓
    • Organizer
      日本金属学会2012年春期第150回大会
    • Place of Presentation
      横浜
    • Year and Date
      20120328-30
  • [Presentation] 金属Liと水素の反応によるLiHの生成過程2012

    • Author(s)
      鈴木悠、大内規嵩、竹田修、佐藤讓
    • Organizer
      日本鉄鋼協会2012年春季第163回大会
    • Place of Presentation
      横浜
    • Year and Date
      20120328-30
  • [Presentation] LiOH-LiCl混合溶融塩中におけるBDD電極上でのアノード反応2012

    • Author(s)
      吉田健一郎、上田幹人、大塚俊明
    • Organizer
      平成23年度日本金属学会日本鉄鋼協会両北海道支部合同冬季講演大会
    • Place of Presentation
      札幌
    • Year and Date
      20120119-20
  • [Presentation] Production of Lithium from LiOH using Molten Salt Electrolysis for the Stor- age of Hydrogen through LiH2011

    • Author(s)
      Y.Sato, O.Takeda and M.Li
    • Organizer
      Fray Interna- tional Symposium
    • Place of Presentation
      Cancun, Mexico
    • Year and Date
      20111127-1201
  • [Presentation] 溶融LiCl-KCl-CsCl中でのLiOHの電解挙動2011

    • Author(s)
      東間崇洋、竹田修、星政義、佐藤讓
    • Organizer
      第43回溶融塩化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      20111121-22
  • [Presentation] Electrochemistry of Anodic Reaction in Molten Salt containing LiOH for Lith- ium-Hydrogen Cycle2011

    • Author(s)
      Y.Sato, O.Takeda, M.Li and M.Hoshi
    • Organizer
      9th International Symposium on Molten Salts Chemistry and Technology
    • Place of Presentation
      Trondheim, Norway
    • Year and Date
      20110605-09
  • [Presentation] 溶融塩化物中でのLiOHの電極反応2011

    • Author(s)
      東間崇洋、竹田修、栗明明、星政義、佐藤讓
    • Organizer
      日本金属学会2011年春期第148回大会
    • Place of Presentation
      東京
    • Year and Date
      20110325-27
  • [Presentation] 水素貯蔵に供する金属リチウムの水酸化リチウムからの電解製造2010

    • Author(s)
      竹田修、栗明明、星政義、佐藤讓
    • Organizer
      日本金属学会2010年秋期第147回大会
    • Place of Presentation
      札幌
    • Year and Date
      20100925-27
  • [Presentation] LiOH-LiCl混合溶融塩における炭素電極上でのアノード反応2010

    • Author(s)
      若井幸祐、上田幹人、大塚俊明
    • Organizer
      第42回溶融塩化学討論会
    • Place of Presentation
      函館
    • Year and Date
      20100909-10
  • [Presentation] 溶融LiCl-KCl中でのLiOHの電解2010

    • Author(s)
      栗明明、竹田修、星政義、佐藤讓
    • Organizer
      第42回溶融塩化学討論会
    • Place of Presentation
      函館
    • Year and Date
      20100909-10
  • [Presentation] 溶融LiCl-KCl共晶塩を用いたLiOHからのリチウムの電解析出2010

    • Author(s)
      竹田修、栗明明、星政義、佐藤讓
    • Organizer
      表面技術協会第122回講演大会
    • Place of Presentation
      仙台
    • Year and Date
      20100906-07
  • [Presentation] 溶融LiOH-LiClからのリチウムの電解製造2009

    • Author(s)
      竹田修、栗明明、星政義、佐藤讓
    • Organizer
      第41回溶融塩化学討論会
    • Place of Presentation
      京都
    • Year and Date
      20091119-20
  • [Presentation] Electrolytic Production of Lithium for Hydrogen Storage2009

    • Author(s)
      M.Li, O.Takeda, M.Hoshi and Y.Sato
    • Organizer
      60th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      北京、中華人民共和国
    • Year and Date
      20090816-21
  • [Book] "MOLTEN SALTS: FUNDAMENTALS AND APPLICA- TIONS OF FUSED MEDIA", Elsevier2013

    • Author(s)
      Y.Sato and O.Takeda
    • Publisher
      Electrowinning of lithium from molten salt containing LiOH for hydrogen storage and transportation.

URL: 

Published: 2014-08-29  

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