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2011 Fiscal Year Final Research Report

Development and demonstration of rotary-type solar chemical reactor

Research Project

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Project/Area Number 21246147
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Energy engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

TAMAURA Yutaka  東京工業大学, 大学院・理工学研究科, 教授 (00108185)

Co-Investigator(Kenkyū-buntansha) KURODA Chiaki  東京工業大学, 大学院・理工学研究科, 教授 (80114867)
YOSHIZAWA Yoshio  東京工業大学, 原子炉工学研究所, 教授 (00016627)
HASEGAWA Noriko  東京工業大学, 炭素循環エネルギー研究センター, 助教 (30361801)
KANEKO Hiroshi  東京工業大学, ソリューション研究機構, 特任准教授 (90323774)
Project Period (FY) 2009 – 2011
Keywords新エネルギー / 化学工学 / 国際協力 / セラミックス / 格子欠陥
Research Abstract

New solar concentration systems of "post heating system" and "cross linear system" were developed, and highly reactive ceramics YSZ/Ni-ferrite solid solution was synthesized. TheαO_2 releasing reaction by rapid heating proceeds via two steps of 1) photon absorption and its relaxation process forming an excess Frenkel structure(light reaction), and 2) O_2 gas formation from lattice oxygen, which is driven by defect structure energy(dark reaction). The dual column solar reactor(3_<rd> model) was fabricated, with which the light and dark reactions can be occurred continuously. The field test of the rotary reactor developed was done at the solar field of CSIRO.

  • Research Products

    (12 results)

All 2012 2011 2010 2009 Other

All Journal Article (5 results) (of which Peer Reviewed: 4 results) Presentation (5 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results) (of which Overseas: 1 results)

  • [Journal Article] Conversion of concentrated solar thermal energyinto chemical energy2011

    • Author(s)
      Y. Tamaura
    • Journal Title

      AMBIO

      Volume: 41 Pages: 108-111

    • DOI

      DOI:10.1017/s13280-012-0264-7

    • Peer Reviewed
  • [Journal Article] Reduction reactivity of C_eO_2-ZrO_2oxide under high O_2 partial pressurein two-step water splitting process2011

    • Author(s)
      H. Kaneko, S. Taku, Y. Tamaura
    • Journal Title

      Solar Energy

      Volume: 85 Pages: 2321-2330

    • DOI

      DOI:10.1016/j.solener.2011.06.019

    • Peer Reviewed
  • [Journal Article] Reactivity of CeO2-based ceramics for solar hydrogen production via a two-step water-splitting cycle with concentrated solar energy2011

    • Author(s)
      Q. L. Meng, 他2名, H. Kaneko, Y. Tamaura
    • Journal Title

      Int. J. Hydrogen Energy

      Volume: 36 Pages: 13435-13441

    • DOI

      DOI:10.1016/j.ijhydene.2011.07.089

    • Peer Reviewed
  • [Journal Article] 集光型太陽熱利用技術によるサンベルト開発-低炭素社会に向けて果たす役割2010

    • Author(s)
      玉浦裕
    • Journal Title

      化学と工業

      Volume: 63 Pages: 21-23

    • URL

      http://www.chemistry.or.jp/journals/kakou/

  • [Journal Article] Development of reactive ceramics for conversion of concentrated solar heat into solar hydrogen with two-step water splitting reaction2010

    • Author(s)
      H. Kaneko, 他3名, N. Hasegawa, Y. Tamaura
    • Journal Title

      J. Solar EnergyEng.

      Volume: 132 Pages: 021202/1-021202/4

    • DOI

      DOI:10.1115/1.4001180

    • Peer Reviewed
  • [Presentation] 集光太陽エネルギーの化学エネルギー変換(107)ロータリー式太陽反応炉における反応性セラミックスの高温還元反応促進2012

    • Author(s)
      玉浦裕,重田智,金子宏
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜
    • Year and Date
      20120325-28
  • [Presentation] Graphite solar thermal storage system at 1300K using rotating-reactive-ceramics concept2011

    • Author(s)
      Y. Tamaura, Y. Ishikawa, H. Kaneko
    • Organizer
      ASME 2011 5th International Conference on Energy Sustainability(ES2011)
    • Place of Presentation
      Washington, DC
    • Year and Date
      20110807-10
  • [Presentation] CeO_2-ZrO_2系反応性セラミックスにおける酸素放出反応の昇温速度依存性の熱重量分析2010

    • Author(s)
      重田智,金子宏,玉浦裕
    • Organizer
      平成22年度日本太陽エネルギー学会・日本風力エネルギー協会合同研究発表会
    • Place of Presentation
      郡山
    • Year and Date
      20101104-05
  • [Presentation] 集光太陽熱を利用した水素生成反応炉のシステム解析2010

    • Author(s)
      眞下裕貴,松本秀行,黒田千秋
    • Organizer
      化学工学会宇都宮大会2010
    • Place of Presentation
      宇都宮
    • Year and Date
      20100921-24
  • [Presentation] Development of Reactive Ceramics with High O_2 Releasing Reactivity in Two-step Water Splitting Reaction2009

    • Author(s)
      Y. Tamaura, 他4名, H. Kaneko
    • Organizer
      SolarPACES2009
    • Place of Presentation
      Berlin, Germany
    • Year and Date
      20090915-18
  • [Remarks]

    • URL

      http://www.chemistry.titech.ac.jp/~tamaura/index.html

  • [Patent(Industrial Property Rights)] CROSS LINEAR TYPE SOLAR HEAT COLLECTING APPARATUS2011

    • Inventor(s)
      Yutaka Tamaura
    • Industrial Property Rights Holder
      Tokyo Institute of Technology
    • Industrial Property Number
      特許、PCT/JP2011/005504
    • Filing Date
      2011-09-29
    • Overseas

URL: 

Published: 2013-07-31  

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