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2011 Fiscal Year Final Research Report

Development of Highly Efficient Anion Sensor Using Color Variable Polymer

Research Project

  • PDF
Project/Area Number 21350058
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer chemistry
Research InstitutionHokkaido University

Principal Investigator

KAKUCHI Toyoji  北海道大学, 大学院・工学研究院, 教授 (80113538)

Co-Investigator(Kenkyū-buntansha) SATOH Toshifumi  北海道大学, 大学院・工学研究院, 准教授 (80291235)
Project Period (FY) 2009 – 2011
Keywordsアニオンセンサー / π共役系ポリマー / ポリアセチレン / 比色分析 / ホスト・ゲスト相互作用 / 超分子化学
Research Abstract

Development of novel anion sensor consisting of π-conjugated polymer was investigated in this research in order to provide an innovative methodology for simple and quick detection of anions. We achieved to fabricate various π-conjugated polymers that can show colorimetric and fluorescent changes upon the addition of anions. The sensitivity and selectivity in the anion detection was clarified to be tunable with the molecular design.

  • Research Products

    (19 results)

All 2012 2011 2010 2009 Other

All Journal Article (9 results) (of which Peer Reviewed: 8 results) Presentation (9 results) Remarks (1 results)

  • [Journal Article] Strict Size Specificity in Colorimetric Anion Detection Based on Poly(phenylacetylene) Receptor Bearing Second Generation Lysine Dendrons2011

    • Author(s)
      Sakai, R.; Sakai, N.; Satoh, T.; Li, W.; Zhang, A.; Kakuchi, T
    • Journal Title

      Macromolecules

      Volume: 44(11) Pages: 4249-4257

    • Peer Reviewed
  • [Journal Article] Syntheses of 3-arm and 4-arm star-branched polystyrene Ru(II) complexes by the click-to-chelate approach2011

    • Author(s)
      Zhang, C.; Shen, X.; Sakai, R.; Gottschaldt, M.; Schubert, U. S.; Hirohara, S.; Tanihara, M.; Yano, S.; Obata, M.; Xiao, N.; Satoh, T.; Kakuchi, T
    • Journal Title

      J. Polym. Sci. Part A : Polym. Chem

      Volume: 49(3) Pages: 746-753

    • Peer Reviewed
  • [Journal Article] Pendant structure governed anion sensing property for sulfonamide-functionalized poly(phenylacetylene)s bearing various α-amino acids2010

    • Author(s)
      Kakuchi, R.; Shimada, R.; Tago, Y.; Sakai, R.; Satoh, T.; Kakuchi, T
    • Journal Title

      J. Polym. Sci. Part A : Polym. Chem

      Volume: 48(8) Pages: 1683-1689

    • Peer Reviewed
  • [Journal Article] Host-guest complexation-triggered chiroptical change of poly(phenylacetylene)s bearing binaphthocrown ether moieties on the main chain2010

    • Author(s)
      Sakai, R.; Yonekawa, T.; Otsuka, I.; Kakuchi, R.; Satoh, T.; Kakuchi, T
    • Journal Title

      J. Polym. Sci. Part A : Polym. Chem

      Volume: 48(5) Pages: 1197-1206

    • Peer Reviewed
  • [Journal Article] Efficient Colorimetric Anion Detection Based on Positive Allosteric System of Urea-Functionalized Poly(phenylacetylene) Receptor2010

    • Author(s)
      Sakai, R.; Okade, S.; Barasa, E. B.; Kakuchi, R.; Ziabka, M.; Umeda, S.; Tsuda, K.; Satoh, T.; Kakuchi, T
    • Journal Title

      Macromolecules

      Volume: 43(18) Pages: 7406-7411

    • Peer Reviewed
  • [Journal Article] Optical and Chiroptical Output of Anion Recognition Event Using Clustered Sulfonamide Groups Organized on Poly(phenylacetylene) Backbone2009

    • Author(s)
      Kakuchi, R.; Kodama, T.; Shimada, R.; Tago, Y.; Sakai, R.; Satoh, T.; Kakuchi, T.
    • Journal Title

      Macromolecules

      Volume: 42(12) Pages: 3892-3897

    • Peer Reviewed
  • [Journal Article] Effect of the Pendant Structure on Anion Signaling Property of Poly(phenylacetylene)s Conjugated to α-Amino Acids through Urea Groups2009

    • Author(s)
      Kakuchi, R.; Tago, Y.; Sakai, R.; Satoh, T.; Kakuchi, T
    • Journal Title

      Macromolecules

      Volume: 42(13) Pages: 4430-4435

    • Peer Reviewed
  • [Journal Article] Strong Bronsted Acid as a Highly Efficient Promoter for Group Transfer Polymerization of Methyl Methacrylate2009

    • Author(s)
      Kakuchi, R.; Chiba, K.; Fuchise, K.; Sakai, R.; Satoh, T.; Kakuchi, T
    • Journal Title

      Macromolecules

      Volume: 42(22) Pages: 8747-8750

    • Peer Reviewed
  • [Journal Article] Fluorescence Turn-On Sensing of Anions Based on Disassembly Process of Urea-Functionalized Poly(phenylenebutadiynylene) Aggregates

    • Author(s)
      Sakai, R.; Nagai, A.; Tago, Y.; Sato, S.; Nishimura, Y.; Arai, T.; Satoh, T.; Kakuchi, T.
    • Journal Title

      Macromolecules

      Volume: (in press)

  • [Presentation] Synthesis of urea-functionalized poly(phenylenebutadiynylene) as a turn-on fluorescent probe for anion sensing2012

    • Author(s)
      R. Sakai, A. Nagai, Y. Tago, S. Sato, T. Satoh, T. Kakuchi
    • Organizer
      243rd ACS National Meeting & Exposition, San Diego
    • Place of Presentation
      CA, USA
    • Year and Date
      20120000
  • [Presentation] Corolimetric anion detection by urea-functionalized poly(phenylacetylene) s bearing L-amino acids as a pendants2012

    • Author(s)
      N. Sakai, R. Sakai, T. Satoh, T. Kakuchi
    • Organizer
      243rd ACS National Meeting & Exposition
    • Place of Presentation
      San Diego, CA, USA
    • Year and Date
      20120000
  • [Presentation] Chirality sensing towards amino acid using poly(phenylacetylene) conjugated with L-lysine through urea linkage2011

    • Author(s)
      Sakai, Naoya ; Sakai, Ryosuke ; Satoh, Toshifumi ; Zhang, Afang ; Kakuchi, Toyoji
    • Organizer
      241st ACS National Meeting & Exposition
    • Place of Presentation
      Anaheim, CA, USA
    • Year and Date
      20110000
  • [Presentation] アミド基を側鎖に導入したポリ(フェニルアセチレン)によるキラルカルボン酸塩の検出2011

    • Author(s)
      田口主、堺井亮介、佐藤敏文、覚知豊次
    • Organizer
      第45回(2010年度)高分子学会北海道支部研究発表会
    • Place of Presentation
      札幌
    • Year and Date
      20110000
  • [Presentation] ウレア基を有するポリ(p-フェニレン)を用いたアニオン応答性蛍光プローブの開発2011

    • Author(s)
      島田遼太郎、堺井亮介、佐藤敏文、覚知豊次
    • Organizer
      化学系学協会北海道支部2011年冬季研究発表会
    • Place of Presentation
      札幌
    • Year and Date
      20110000
  • [Presentation] ウレア基を側鎖に有するポリ(フェニルアセチレン)の光学活性カルボン酸塩によるらせん誘起2010

    • Author(s)
      岡出翔太・小玉達郎・多胡泰之・覚知亮平・堺井亮介・佐藤敏文・覚知豊次
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本
    • Year and Date
      20100000
  • [Presentation] リシン由来デンドロンを側鎖に有するポリ(フェニルアセチレン)の合成とアニオン認識能2010

    • Author(s)
      酒井直哉・伊原良介・堺井亮介・佐藤敏文・覚知豊次
    • Organizer
      第44回高分子学会北海道支部研究発表会
    • Place of Presentation
      札幌
    • Year and Date
      20100000
  • [Presentation] アミノ酸由来アミド基を側鎖に有するポリ(フェニルアセチレン)のアニオン認識能2010

    • Author(s)
      寺田絵里加・多胡泰之・堺井亮介・佐藤敏文・覚知豊次
    • Organizer
      第44回高分子学会北海道支部研究発表会
    • Place of Presentation
      札幌
    • Year and Date
      20100000
  • [Presentation] Boc-アミノ酸を有するポリ(フェニルアセチレン)の合成とアニオン比色検出能2010

    • Author(s)
      柴崎拓也・島田遼太郎・多胡泰之・堺井亮介・佐藤敏文・覚知豊次
    • Organizer
      第44回高分子学会北海道支部研究発表会
    • Place of Presentation
      札幌
    • Year and Date
      20100000
  • [Remarks]

    • URL

      http://poly-bm.eng.hokudai.ac.jp/index.html

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Published: 2013-07-31  

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