• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2011 Fiscal Year Final Research Report

Development of electrode functions by controlling interface structure

Research Project

  • PDF
Project/Area Number 21350115
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionMie University

Principal Investigator

IMANISHI Nobuyuki  三重大学, 大学院・工学研究科, 准教授 (20223331)

Co-Investigator(Kenkyū-buntansha) HIRANO Atsushi  三重大学, 大学院・工学研究科, 助教 (60324547)
Project Period (FY) 2009 – 2011
Keywords固体電解質 / インターカレーション / 界面 / リチウム電池 / 全固体電池
Research Abstract

Electrode/solid electrolyte interfaces were studied for development of all solid-state batteries. The resistance was discussed about its correlation to ion diffusion formula in some active materials. The appropriate technique was investigated to estimate lithium ion diffusion coefficient, and potential-step was the method to give the most reasonable result. As a result, the interfacial resistance decreased in the order of electrode with one, two, three dimensional diffusion pathways. It is concluded that three dimensional diffusion is most effective to reduce the interfacial resistance.

  • Research Products

    (17 results)

All 2011 2010 2009

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (8 results)

  • [Journal Article] Electrochemical kinetics of nanosized Ag and Ag_2O thin films prepared by radio frequency magnetron sputtering2011

    • Author(s)
      J. Xie, N. Imanishi, A. Hirano, Y. Takeda, O. Yamamoto, X.-B. Zhao, G.-S. Cao
    • Journal Title

      J. Solid State Electrochemistry

      Volume: 15 Pages: 2031-2039

    • Peer Reviewed
  • [Journal Article] Determination of Li-ion diffusion coefficient in amorphous Zn and ZnO thin films prepared by radio frequency magnetron sputtering2011

    • Author(s)
      J. Xie, N. Imanishi, A. Hirano, Y. Takeda, O. Yamamoto, X. B. Zhao, G. S. Cao
    • Journal Title

      Thin Solid Films

      Volume: 519 Pages: 3373-3377

    • Peer Reviewed
  • [Journal Article] Electrochemical performance of all-solid-state Li batteries based LiMn_<0.5> Ni_<0.5> O_2 cathode and NASICON-type electrolyte2010

    • Author(s)
      J. Xie, N. Imanishi, Z. Zhang, A. Hirano, Y. Takeda, O. Yamamoto, X. B. Zhao, G. S. Cao
    • Journal Title

      J. Power Sources

      Volume: 195 Pages: 8341-8346

    • Peer Reviewed
  • [Journal Article] Li-ion diffusion behavior in Sn, SnO and SnO_2 thin films studied by galvanostatic intermittent titration technique2010

    • Author(s)
      J. Xie, N. Imanishi, A. Hirano, Y. Takeda, O. Yamamoto, X. B. Zhao, G. S. Cao
    • Journal Title

      Solid State Ionics

      Volume: 181 Pages: 1611-1615

    • Peer Reviewed
  • [Journal Article] An amorphous LiCo_<1/3> Mn_<1/3> Ni_<1/3> O_2 thin film deposited on NASICON-type electrolyte for all-solid-state Li-ion batteries2010

    • Author(s)
      J. Xie, N. Imanishi, T. Zhang, A. Hirano, Y. Takeda, O. Yamamoto
    • Journal Title

      J. Power Sources

      Volume: 195 Pages: 5780-5783

    • Peer Reviewed
  • [Journal Article] Amorphous LiCoO_2 thin films on Li_<1+x+y> Al_xTi_<2-x> Si_yP_<3-y> O_<12> prepared by radio frequency magnetron sputtering for all-solid-state Li-ion batteries2010

    • Author(s)
      J. Xie, N. Imanishi, T. Zhang, A. Hirano, Y. Takeda, O. Yamamoto, G. S. Cao, X. B. Zhao
    • Journal Title

      Electrochimica Acta

      Volume: 55 Pages: 5440-5445

    • Peer Reviewed
  • [Journal Article] Li-ion diffusion in amorphous Si films prepared by RF magnetron sputtering : A comparison of using liquid and polymer electrolytes2010

    • Author(s)
      J. Xie, N. Imanishi, T. Zhang, A. Hirano, Y. Takeda, O. Yamamoto
    • Journal Title

      Materials Chemistry and Physics

      Volume: 120 Pages: 421-425

    • Peer Reviewed
  • [Journal Article] Li-ion diffusion kinetics in LiFePO_4 thin film prepared by radio frequency magnetron sputtering2009

    • Author(s)
      J. Xie, N. Imanishi, T. Zhang, A. Hirano, Y. Takeda, O. Yamamoto
    • Journal Title

      Electrochimica Acta

      Volume: 54 Pages: 4631-4637

    • Peer Reviewed
  • [Journal Article] Li-ion diffusion kinetics in LiCoPO_4 thin films deposited on NASICON-type glass ceramic electrolytes by magnetron sputtering2009

    • Author(s)
      J. Xie, N. Imanishi, T. Zhang, A. Hirano, Y. Takeda, O. Yamamoto
    • Journal Title

      J. Power Sources

      Volume: 192 Pages: 689-692

    • Peer Reviewed
  • [Presentation] スパッタリング電極層/無機固体電解質の熱処理と界面抵抗2011

    • Author(s)
      伊藤大介・今西誠之・平野敦・武田保雄
    • Organizer
      第52回電池討論会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      20111017-1020
  • [Presentation] The Effect of Heat-treatment on the Interfacial Properties of Perovskite-type Li-Ion Conductor and V_2O_5 Electrode2011

    • Author(s)
      M. Matsumoto, N. Imanishi, A. Hirano, Y. Takeda
    • Organizer
      18th International Conference on Solid State Ionics
    • Place of Presentation
      Warsaw Marriott Hotel(Warsaw, Poland)
    • Year and Date
      20110703-0708
  • [Presentation] LiCoO_2 Deposited on Li_<1.4> Al_<0.4> Ti_<1.6>(PO_4)_3 Ceramic Electrolyte for All Solid Lithium Battery2011

    • Author(s)
      D. Ito, N. Imanishi, A. Hirano, Y. Takeda
    • Organizer
      18th International Conference on Solid State Ionics
    • Place of Presentation
      Warsaw Marriott Hotel(Warsaw, Poland)
    • Year and Date
      20110703-0708
  • [Presentation] Interfacial properties of LiFePO_4-PEO(LiTFSI) composite cathode for dry polymer Li-ion batteries2010

    • Author(s)
      K. Hanai, M. Ueno, N. Imanishi, A. Hirano, O. Yamamoto, Y. Takeda
    • Organizer
      IMLB2010(International Meeting on Lithium Batteries)
    • Place of Presentation
      Fairmont the Queen Elizabeth(Montreal, Canada)
    • Year and Date
      20100627-0702
  • [Presentation] Interfacial properties of LiFePO_4-PEO(LiTFSI) composite cathode for dry polymer Li-ion batteries2010

    • Author(s)
      K. Hanai, M. Ueno, T. Kobayashi, N. Imanishi, A. Hirano, O. Yamamoto, Y. Takeda
    • Organizer
      7th Asian Conference on Electrochemistry(7th ACEC)第7回アジア電気化学会議
    • Place of Presentation
      KKRホテル熊本
    • Year and Date
      20100518-0522
  • [Presentation] LiFePO_4スパッタリング電極とPEO固体電解質における界面抵抗の研究2009

    • Author(s)
      草河孝一・花井一真・平野敦・今西誠之・武田保雄
    • Organizer
      第50回電池討論会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      20091130-1202
  • [Presentation] Interfacial properties between LiFePO_4 and poly(ethylene oxide)-Li(CF_3SO_2)_2N polymer electrolyte2009

    • Author(s)
      K. Hanai, K. Kusagawa, N. Imanishi, A. Hirano, Y. Takeda and O. Yamamoto
    • Organizer
      216th Meeting of The Electrochemical Society(ECS)
    • Place of Presentation
      Austria Center(Vienna, Austria)
    • Year and Date
      20091004-1009
  • [Presentation] Interfacial Properties between LiFePO_4 and Poly(ethylene oxide)-Li(CF_3SO_2)_2N Polymer Electrolyte2009

    • Author(s)
      K. Hanai, K. Kusagawa, M. Ueno, N. Imanishi, A. Hirano, Y. Takeda, O. Yamamoto
    • Organizer
      PBFC2009 4th International Conference on Polymer Batteries and Fuel Cells
    • Place of Presentation
      Yokohama Symposia
    • Year and Date
      20090802-06

URL: 

Published: 2013-07-31  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi