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2011 Fiscal Year Final Research Report

Development of thin films of layered double hydroxides with electron-, ion-and photo-functions

Research Project

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Project/Area Number 21350118
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionOsaka Prefecture University

Principal Investigator

TADANAGA Kiyoharu  大阪府立大学, 大学院・工学研究科, 准教授 (90244657)

Project Period (FY) 2009 – 2011
Keywordsゾル-ゲル法 / 温水処理 / 層状複水酸化物
Research Abstract

Thin films of layered double hydroxide(LDH) intercalated with various anions were prepared by immersing sol-gel derived precursor thin films. Organic dyes with sulfo groups were found to be easily intercalated in LDH nanocrystals in this process. Orientation of the nanocrystals on the surface can be controllable with the kind of organic molecules. Mg-Al and Ni-Al LDHs were found to show high hydroxide ion conductivity.

  • Research Products

    (36 results)

All 2012 2011 2010 2009

All Journal Article (8 results) (of which Peer Reviewed: 6 results) Presentation (27 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Effect of Mg/Al ratio on hydroxide ion conductivity for Mg-Al layered double hydroxide and application to direct ethanol fuel cells2012

    • Author(s)
      K. Tadanaga, Y. Furukawa, A. Hayashi and M. Tatsumisago
    • Journal Title

      J. Electrochem. Soc.

      Volume: 159 Pages: B368-370

    • Peer Reviewed
  • [Journal Article] Preparation of Co-Al and Ni-Al layered double hydroxide thin films by a sol-gel process with hot water treatment2012

    • Author(s)
      K. Tadanaga, A. Miyata, N. Yamaguchi, D. Ando, and M. Tatsumisago
    • Journal Title

      J. Sol-Gel Sci. Tech.

      Volume: 62 Pages: 111-116

    • Peer Reviewed
  • [Journal Article] Hydroxide ion conduction in Ni-Al layered double hydroxide2012

    • Author(s)
      D. Kubo, K. Tadanaga, A. Hayashi, and M. Tatsumisago
    • Journal Title

      J. Electroanal. Chem.

      Volume: 671 Pages: 102-106

    • Peer Reviewed
  • [Journal Article] Evaluation of ionic conductivity for Mg. Al layered double hydroxide intercalated with inorganic anions2011

    • Author(s)
      Y. Furukawa, K. Tadanaga, A. Hayashi, and M. Tatsumisago
    • Journal Title

      Solid State Ionics

      Volume: 192 Pages: 185-187

    • Peer Reviewed
  • [Journal Article] 水酸化物イオン伝導性無機固体材料の創製2011

    • Author(s)
      忠永清治、辰巳砂昌弘
    • Journal Title

      Electrochemistry

      Volume: 79 Pages: 630-633

  • [Journal Article] Direct Ethanol Fuel Cell Using Hydrotalcite Clay as a Hydroxide Ion Conductive Electrolyte2010

    • Author(s)
      K. Tadanaga, Y. Furukawa, A. Hayashi, and M. Tatsumisago
    • Journal Title

      Adv. Mater.

      Volume: 22 Pages: 4401-4404

    • Peer Reviewed
  • [Journal Article] Formation of Zn-Al Layered Double Hydroxide Thin Films Intercalated with Sulfonated Spiropyran2009

    • Author(s)
      K. Tadanaga, N. Yamaguchi, and M. Tatsumisago
    • Journal Title

      Res. Chem. Intermed.

      Volume: 35 Pages: 949-956

    • Peer Reviewed
  • [Journal Article] 温水処理を伴うゾル-ゲル法による機能性薄膜の合成2009

    • Author(s)
      忠永清治
    • Journal Title

      セラミックス

      Volume: 44 Pages: 613-615

  • [Presentation] 水酸化物イオン伝導性を有する層状複水酸化物とMnO_2からなる金属-空気二次電池用空気極の作製と評価2012

    • Author(s)
      窪大樹、忠永清治、林晃敏、辰巳砂昌弘
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      浜松
    • Year and Date
      20120329-31
  • [Presentation] 様々なアニオンを層間に含むZn-Cr系層状複水酸化物の作製と光触媒活性2012

    • Author(s)
      忠永清治、平田直也、辰巳砂昌弘
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学
    • Year and Date
      20120325-28
  • [Presentation] Ni-Al系層状複水酸化物のイオン伝導性評価とアルカリ形燃料電池への応用2011

    • Author(s)
      窪大樹、忠永清治、林晃敏、辰巳砂昌弘
    • Organizer
      第37回固体イオニクス討論会
    • Place of Presentation
      鳥取
    • Year and Date
      20111207-09
  • [Presentation] フルオレセインと界面活性剤が挿入されたZn-Al系層状複水酸化物薄膜の作製2011

    • Author(s)
      末澤諒也、忠永清治、辰巳砂昌弘
    • Organizer
      第52回ガラスおよびフォトニクス材料討論会
    • Place of Presentation
      姫路
    • Year and Date
      20111124-25
  • [Presentation] Ni-Al系層状複水酸化物を用いた全固体アルカリ形燃料電池2011

    • Author(s)
      窪大樹、忠永清治、林晃敏、辰巳砂昌弘
    • Organizer
      第52回電池討論会
    • Place of Presentation
      東京
    • Year and Date
      20111017-20
  • [Presentation] 温水処理による層状複水酸化物微結晶の析出における配向制御2011

    • Author(s)
      忠永清治
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学
    • Year and Date
      20110928-30
  • [Presentation] Hydroxide Ion Conductivity of Ni-Al Layered Double Hydroxides for Alkaline Fuel Cell2011

    • Author(s)
      D. Kubo, K. Tadanaga, A. Hayashi and M. Tatsumisago
    • Organizer
      The 62nd Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      新潟国際会議場
    • Year and Date
      20110911-16
  • [Presentation] ケミカルプロセスによる全固体電気化学デバイス用材料の合成2011

    • Author(s)
      忠永清治、林晃敏、辰巳砂昌弘
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      北海道大学
    • Year and Date
      20110907-09
  • [Presentation] Preparation and Fluorescent Properties of Zn-Al Layered Double Hydroxide Thin Films Intercalated with Sulforhodamine B2011

    • Author(s)
      R. Suezawa, K. Tadanaga, M. Tatsumisago
    • Organizer
      The 16^<th> International Sol-Gel Conference
    • Place of Presentation
      Hangzhou, China
    • Year and Date
      20110828-0902
  • [Presentation] スルホローダミンBが挿入されたZn-Al系層状複水酸化物薄膜の作製と蛍光特性2011

    • Author(s)
      末澤諒也、忠永清治、辰巳砂昌弘
    • Organizer
      日本ゾル-ゲル学会第9回討論会
    • Place of Presentation
      関西大学
    • Year and Date
      20110728-29
  • [Presentation] アルカリ形燃料電池への応用にむけたNi-Al系層状複水酸化物の作製と評価2011

    • Author(s)
      窪大樹、忠永清治、林晃敏、辰巳砂昌弘
    • Organizer
      第13回化学電池材料ミーティング
    • Place of Presentation
      日本化学会会館
    • Year and Date
      20110607-08
  • [Presentation] Ni-Al系層状複水酸化物の水酸化物イオン伝導性と固体アルカリ形燃料電池への応用2011

    • Author(s)
      忠永清治、窪大樹、林晃敏、辰巳砂昌弘
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      講演要旨集
    • Year and Date
      2011-03-29
  • [Presentation] Ni-Al系層状複水酸化物の水酸化物イオン伝導性の評価2011

    • Author(s)
      忠永清治、窪大樹、林晃敏、辰巳砂昌弘
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      講演要旨集
    • Year and Date
      2011-03-11
  • [Presentation] スルホローダミンBを含むZn-Al系層状複水酸化物薄膜の作製と発光特性2011

    • Author(s)
      末澤諒也、忠永清治、辰巳砂昌弘
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      講演要旨集
    • Year and Date
      2011-03-11
  • [Presentation] Preparation of materials for all-solid-state electrochemical devices by solution processes(Invited lecture)2011

    • Author(s)
      K. Tadanaga
    • Organizer
      The 1st Japan-Italy Workshop on Sol-Gel for Advanced Functional Materials
    • Place of Presentation
      大阪
    • Year and Date
      2011-02-09
  • [Presentation] Novel Inorganic Materials for Polymer Electrolyte and Alkaline Fuel Cells(招待講演)2010

    • Author(s)
      K. Tadanaga
    • Organizer
      2nd ASEAN-APCTP Workshop on Advanced Materials Science and Nanotechnology
    • Place of Presentation
      Penang, Malaysia
    • Year and Date
      20101221-23
  • [Presentation] Preparation of Zn-Al Layered Double Hydroxide Thin Films Intercalated with Anionic Dyes Having Sulfonic Groups through the Sol-Gel Process with Hot Water Treatment2010

    • Author(s)
      K. Tadanaga, R. Suezawa, T. Tamura, M. Tatsumisago
    • Organizer
      3rd International Congress on Ceramics
    • Place of Presentation
      大阪
    • Year and Date
      20101114-18
  • [Presentation] Preparation of Layered Double Hydroxide Nano-Crystals Precipitated Coatings by the Sol-Gel Method with Hot Water Treatment2010

    • Author(s)
      K. Tadanaga, N. Yamaguchi, T. Tamura, R. Suezawa, M. Tatsumisago
    • Organizer
      XXII International Congress on Glass
    • Place of Presentation
      Bahia, Brazil
    • Year and Date
      20100920-25
  • [Presentation] Zn-Al系層状複水酸化物のイオン伝導性の評価2010

    • Author(s)
      忠永清治、古川佳宏、林晃敏、辰巳砂昌弘
    • Organizer
      2010年電気化学秋季大会
    • Place of Presentation
      神奈川工科大学
    • Year and Date
      20100902-03
  • [Presentation] Ionic Conduction in Mg-Al and Zn-Al Layered Double Hydroxide Intercalated with Inorganic Anions2010

    • Author(s)
      K. Tadanaga, Y. Furukawa, A. Hayashi and M. Tatsumisago
    • Organizer
      The 15th International Conference on Solid State Protonic Conductors
    • Place of Presentation
      California, USA
    • Year and Date
      20100815-19
  • [Presentation] 温水処理によるピラニンがインターカレーションされたZn-Al系層状複水酸化物薄膜の作製2010

    • Author(s)
      末澤諒也、忠永清治、辰巳砂昌弘
    • Organizer
      日本ゾル-ゲル学会第8回討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      20100729-30
  • [Presentation] Preparation of Zn-Al Layered Double Hydroxide Thin Films Intercalated with Pyranine via Sol-Gel Process with Hot Water Treatment2010

    • Author(s)
      R. Suezawa, K. Tadanaga, M. Tatsumisago
    • Organizer
      2nd Japan-Korea Joint Forum on Sol-Gel Science and Technology
    • Place of Presentation
      大阪
    • Year and Date
      20100626-28
  • [Presentation] Preparation of Nano-Structured Oxide Thin Films by the Sol-Gel Method with Hot Water Treatment(招待講演)2010

    • Author(s)
      K. Tadanaga
    • Organizer
      2nd Japan-Korea Joint Forum on Sol-Gel Science and Technology
    • Place of Presentation
      大阪
    • Year and Date
      20100626-28
  • [Presentation] 温水処理を伴うゾル-ゲル法によるピラニンを含むZn-Al系層状複水酸化物薄膜の作製2010

    • Author(s)
      忠永清治、末澤諒也、辰巳砂昌弘
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      20100325-28
  • [Presentation] Mg-Al系層状複水酸化物を電解質に用いたアルカリ形燃料電池2009

    • Author(s)
      古川佳宏、忠永清治、林晃敏、辰巳砂昌弘
    • Organizer
      第50回電池討論会
    • Place of Presentation
      京都
    • Year and Date
      20091128-30
  • [Presentation] Mg-Al系層状複水酸化物のイオン伝導性と水素-酸素燃料電池への応用2009

    • Author(s)
      古川佳宏、忠永清治、林晃敏、辰巳砂昌弘
    • Organizer
      2009年電気化学会秋季大会
    • Place of Presentation
      東京農工大
    • Year and Date
      20090911-12
  • [Presentation] Preparation of Layered Double Hydroxide Thin Films by Hot Water Treatment2009

    • Author(s)
      K. Tadanaga
    • Organizer
      The 4th KIFEE Symposium on Environment, Energy, Materials and Education
    • Place of Presentation
      Trondheim, Norway
    • Year and Date
      20090907-09
  • [Patent(Industrial Property Rights)] 金属-空気二次電池用空気極触媒層2012

    • Inventor(s)
      忠永清治、林晃敏、辰巳砂昌弘
    • Industrial Property Rights Holder
      大阪府立大学
    • Industrial Property Number
      特許、2012-69432
    • Filing Date
      2012-03-26

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Published: 2013-07-31  

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