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2011 Fiscal Year Final Research Report

Fabrication of alkaline type membrane for fuel cells and Evaluation of fuel cell properties

Research Project

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Project/Area Number 21360327
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionTokyo City University

Principal Investigator

NAGAI Masayuki  東京都市大学, 総合研究所, 教授 (80112481)

Co-Investigator(Kenkyū-buntansha) MUNAKATA Fumio  東京都市大学, 工学部, 教授 (50386356)
Project Period (FY) 2009 – 2011
Keywords燃料電池 / 新エネルギー / 化学プロセス / 電極触媒 / 材料評価 / アルカリ形 / 無機有機コンポジット / 電解質膜
Research Abstract

The sample which showed the highest conductivity value was a film prepared using tri-methylamine and the value was 0.9mS/cm at 60℃ under 80% relative humidity. From the relationship between structure and properties, it was found that the homogeneity of the film was largely important for the ionic conductivity and it was possible to control the conductivity by choosing the starting materials. The single fuel cell performance was measured under the flow of hydrogen and oxygen. The highest power density of the cell was 016mW/cm^2 and the highest current density was 0.8mA/cm^2. The complex impedance measurement during the cell performance indicated that a resistance was observed in the frequency range between the high frequency part and 10Hz. It may be due to small ionic conduction and poor diffusion near the catalyst particles. In this study, development of novel solid electrolytes and electrodes for AMFC was conducted and its cell performance was demonstrated.

  • Research Products

    (20 results)

All 2012 2011 2010 2009 2008

All Journal Article (8 results) (of which Peer Reviewed: 7 results) Presentation (12 results)

  • [Journal Article] Agglomeration behavior of nickel particles on YSZ and TiO_2-doped YSZ electrolytes2012

    • Author(s)
      H.Kishimoto, A.Suzuki, T.Shimonosonoa, M.E.Brito, K.Yamaji, T.Horita, F.Munakata, H.Yokokawa
    • Journal Title

      Journal of Power Sources

      Volume: Vol. 199 Pages: 174-178

    • Peer Reviewed
  • [Journal Article] Intermediate Temperature Fuel Cell Using Gypsum Based Electrolyte And Electrodes2011

    • Author(s)
      Satoshi Suzuki, Yuji Katagiri and Masayuki Nagai
    • Journal Title

      IOP Conference Series: Materials Science and Engineering

      Volume: 8(12) Pages: 22008-1-22008-4

    • Peer Reviewed
  • [Journal Article] Modification of Nafion Using 3-mercaptopropyl Trimethoxysilane2010

    • Author(s)
      H. Lee, S.B. Park, M-Hoon, K. Cho, Y-I. Park, S. Suzuki, M. Nagai, and F.B. Prinz
    • Journal Title

      J. of Korean Pys. Soc.

      Volume: 56 Pages: 1215-1222

    • Peer Reviewed
  • [Journal Article] Electrophretic Deposition of LDC/LSGM/LDC Tri-layers on NiO-YSZ for anode-supported SOFC2010

    • Author(s)
      Harue T. SUZUKI, Tetsuo UCHIKOSHI, Kiyoshi KOBAYASHI, Tohru S. SUZUKI, Tatsuo SUGIYAMA, Kenji FURUYA, Motohide MATSUDA, Yoshio SAKKA and Fumio MUNAKATA
    • Journal Title

      J. Mater. Res. Soc. Jpn.

      Volume: 3 Pages: 51-55

    • Peer Reviewed
  • [Journal Article] Silicone based alkaline electrolyte membrane for fuel cell2009

    • Author(s)
      S.Suzuki and M.Nagai
    • Journal Title

      Mat. Sci. and Eng. B

      Volume: 161 Pages: 138-141

    • Peer Reviewed
  • [Journal Article] アルカリ燃料電池用新規電解質膜2009

    • Author(s)
      鈴木智史、永井正幸
    • Journal Title

      セラミックデータブック

      Volume: 36 Pages: 71-75

  • [Journal Article] Fabrication of GDC/LSGM/GDC Tri-layers on Polypyrrole-coated NiO-YSZ by Electrophretic Deposition for Anode-supported SOFC2009

    • Author(s)
      Harue T. SUZUKI, Tetsuo UCHIKOSHI, Kiyoshi KOBAYASHI, Tohru S. SUZUKI, Tatsuo SUGIYAMA, Kenji FURUYA, Motohide MATSUDA, Yoshio SAKKA and Fumio MUNAKATA
    • Journal Title

      J. Ceram. Soc. Jpn.

      Volume: 117 Pages: 1246-1248

    • Peer Reviewed
  • [Journal Article] Study of the nanoscopic deformation of an annealed nafion film by using atomic force microscopy and a patterned substrate2008

    • Author(s)
      Y.Maeda, Y-F.Gao, M.Nagai, Y.Nakayama, T.Ichinose, R.Kuroda, and K.Umemura
    • Journal Title

      Ultramicroscopy

      Volume: 08 Pages: 529-535

    • Peer Reviewed
  • [Presentation] リン酸処理石膏複合化電解質膜の作製と評価2012

    • Author(s)
      寺崎雄亮、鈴木智史、永井正幸
    • Organizer
      日本セラミックス協会第50回セラミックス基礎科学討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-01-13
  • [Presentation] 中温動作燃料電池用酸/イミダゾール系電解質膜の作製と評価2012

    • Author(s)
      高津聡、鈴木智史、永井正幸
    • Organizer
      日本セラミックス協会第i50回セラミックス基礎科学討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-01-13
  • [Presentation] シリコンオイルを用いた非フッ素樹脂系アルカリ膜の作製2012

    • Author(s)
      五十嵐友、鈴木智史、永井正幸
    • Organizer
      日本セラミックス協会セラミックス基礎科学討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-01-13
  • [Presentation] Anion Exchange Membrane Fuel Cell Using Silicone Based Electrolyte Membrane2011

    • Author(s)
      Satoshi Suzuki and Masayuki Nagai
    • Organizer
      62nd Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      新潟
    • Year and Date
      2011-09-11
  • [Presentation] シリコーン系アニオン交換膜形燃料電池用電解質膜2011

    • Author(s)
      鈴木智史、永井正幸
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      横浜
    • Year and Date
      2011-03-29
  • [Presentation] アニオン交換膜形燃料電池用電解質膜の開発と評価2010

    • Author(s)
      鈴木智史,永井正幸
    • Organizer
      電気化学会第77回大会
    • Place of Presentation
      富山
    • Year and Date
      2010-03-29
  • [Presentation] 中温動作型燃料電池電極用複合体の開発2010

    • Author(s)
      鈴木智史,猪野寿一,永井正幸
    • Organizer
      日本セラミックス協会2010年年会
    • Place of Presentation
      東京
    • Year and Date
      2010-03-23
  • [Presentation] セッコウ系プロトン伝導-イブリッド電解質膜2009

    • Author(s)
      鈴木智史,山腰千巳,寺崎雄亮,猪野寿一,永井正幸
    • Organizer
      日本セラミックス協会第22回秋季シンポジウム
    • Place of Presentation
      愛媛
    • Year and Date
      2009-09-16
  • [Presentation] 石膏系プロトン伝導-イブリッド電解質膜2009

    • Author(s)
      鈴木智史,山腰千巳,寺崎雄亮,猪野寿一,永井正幸
    • Organizer
      日本セラミックス協会2009年年会
    • Place of Presentation
      野田
    • Year and Date
      2009-03-16
  • [Presentation] シリコン系燃料電池用電解質膜の合成と特性評価2008

    • Author(s)
      鈴木智史,永井正幸
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      福岡
    • Year and Date
      2008-09-17
  • [Presentation] Development of Electrolyte and Electrode tor alkaline membrane fuel cell2008

    • Author(s)
      S.Suzuki and M.Naga
    • Organizer
      The 14th International Conference on Solid State Protonic Conductors
    • Place of Presentation
      Kyoto
    • Year and Date
      2008-09-08
  • [Presentation] Silicone based alkaline electrolyte membrane for fuel eell2008

    • Author(s)
      S. Suzuki and M. Nagai
    • Organizer
      Joint Conference of the 2nd International Conference on the Science and Technology for Advanced Ceramics and the 1st International Conference on Science and Technology of Solid Surface and Interface
    • Place of Presentation
      Chiba
    • Year and Date
      2008-06-01

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Published: 2013-07-31  

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