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2011 Fiscal Year Final Research Report

Electrochemical tailoring of semiconductor nanowire arrays and their application to photo-energy devices

Research Project

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Project/Area Number 21360363
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/treatments
Research InstitutionWaseda University

Principal Investigator

HOMMA Takayuki  早稲田大学, 理工学術院, 教授 (80238823)

Co-Investigator(Kenkyū-buntansha) 福中 康博  早稲田大学, ナノ理工学研究機構, 教授 (60111936)
Co-Investigator(Renkei-kenkyūsha) ミランダ カエタノ  京都大学, 工学研究科, 助教 (30456800)
Project Period (FY) 2009 – 2011
Keywords電気化学反応 / シリコン電析 / 光エネルギーデバイス / 反応解析 / ナノ構造創製
Research Abstract

Novel process for the electrodeposition of Si thin film from ionic liquid electrolyte has been developed and the initial stage of the deposition process was investigated using EQCM, TEM, and Raman Spectroscopy. It was found that amorphous Si was electrodeposited while a certain amount of ionic liquid was included in the films. Moreover, uniform array of Si nanodots was successfully electrodeposited using 150 nm diameter dot array patterns fabricated by UV nanoimprinting lithography.

  • Research Products

    (29 results)

All 2012 2011 2010 2009 Other

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (16 results) Remarks (1 results)

  • [Journal Article] Initial catalyzation analysis of electroless NiP nanoimprinting mold replicated from self-assembled monolayer modified nanopatterns2012

    • Author(s)
      C-P. Lin, M. Saito, T. Homma
    • Journal Title

      Electrochim. Acta

      Volume: 82 Pages: 75-81

    • Peer Reviewed
  • [Journal Article] Theoretical Analysis of Catalytic Activity of Metal Surfaces on Reaction of Hypophosphite Ion2012

    • Author(s)
      M. Kunimoto, H. Nakai, T. Homma
    • Journal Title

      Electrochemistry

      Volume: 80(3) Pages: 126-131

    • Peer Reviewed
  • [Journal Article] Density Functional Theory Analysis for Orbital Interaction between Hypophosphite Ions and Metal Surfaces2011

    • Author(s)
      M. Kunimoto, H. Nakai, T. Homma
    • Journal Title

      J. Electrochem. Soc., J. Electrochem. Soc

      Volume: 158(10) Pages: D626-D633

    • Peer Reviewed
  • [Journal Article] Density Functional Theory Analysis of Reaction Mechanism of Hypophosphite Ions on Metal Surfaces2011

    • Author(s)
      M. Kunimoto, T. Shimada, S. Odagiri, H. Nakai, T. Homma
    • Journal Title

      J. Electrochem. Soc

      Volume: 158(9) Pages: D585-D589

    • Peer Reviewed
  • [Journal Article] Numerical Calculation of Transient Current Density Distribution along Vertical Plane Electrode in CuSO4-H2SO4 Electrolyte Solution2010

    • Author(s)
      S. Kawai, Y. Fukunaka, S. Kida
    • Journal Title

      J. Electrochem. Soc

      Volume: 157(3) Pages: F40-F48

    • Peer Reviewed
  • [Journal Article] Carbothermic Reduction of Amorphous Silica Refined from Diatomaceous Earth2010

    • Author(s)
      M. Hakamada, Y. Fukunaka, T. Oishi, T. Nishiyama, H. Kusuda
    • Journal Title

      Metall. Mater. Trans. B

      Volume: 41(2) Pages: 350-358

    • Peer Reviewed
  • [Journal Article] Electrochemical etching process to tune the diameter of arrayed deep pores by controlling carrier collection at a semiconductor- electrolyte interface2010

    • Author(s)
      H. Sato, T. Yamaguchi, T. Isobe, S. Shoji, T. Homma
    • Journal Title

      Electrochem. Comm

      Volume: 12 Pages: 765-768

    • Peer Reviewed
  • [Journal Article] Fabrication of nanodot array using electrochemical deposition processes2010

    • Author(s)
      T. Ouchi, Y. Arikawa, Y. Konishi, T. Homma
    • Journal Title

      Electrochim. Acta

      Volume: 55 Pages: 8081-8086

    • Peer Reviewed
  • [Journal Article] Transient mass transfer rate of Cu2+ ion caused by copper electrodeposition with alternating electrolytic current2010

    • Author(s)
      S. Kawai, M. Ogawa, K. Ishibashi, Y. Kondo, T. Matsuoka, T. Homma, Y. Fukunaka, S. Kida
    • Journal Title

      Electrochim. Acta

      Volume: 55(12) Pages: 3987-3994

    • Peer Reviewed
  • [Journal Article] Microstructure Formation within Films of Silicon using Electrochemical Anodization2010

    • Author(s)
      J. B. Ratchford, M. Saito, T. Homma
    • Journal Title

      Trans. Mat. Res. Soc

      Volume: 35(1) Pages: 69-72

    • Peer Reviewed
  • [Journal Article] High-Grade Silica Refined from Diatomaceous Earth for Solar-Grade Silicon Production2009

    • Author(s)
      M. Bessho, Y. Fukunaka, H. Kusuda, T. Nishiyama
    • Journal Title

      Energy Fuels

      Volume: 23(8) Pages: 4160-4165

    • Peer Reviewed
  • [Journal Article] Raman Microscopy and Scanning Surface Potential Microscopy Analysis of Nanoscale Defects on Si Wafer Surfaces2009

    • Author(s)
      T. Homma, M. Kato, N. Kubo, K. Sakata, M. Yanagisawa
    • Journal Title

      J. Electrochem. Soc

      Volume: 156(6) Pages: H475-H478

    • Peer Reviewed
  • [Presentation] Silicon Bonding State in Films Electrodeposited from SiCl_4 in Ionic Liquid2012

    • Author(s)
      J. Komadina, T. Akiyoshi, Y. Ishibashi, X. Wang, Y. Fukunaka, P. Pianetta, T. Homma
    • Organizer
      222^<nd> Meeting of the Electrochemical Society
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2012-10-10
  • [Presentation] Electrodeposition of Si nanopatterns from ionic liquid2012

    • Author(s)
      T. Homma
    • Organizer
      9th International Symposium on Electro- chemical Micro & Nanosystem Technology
    • Place of Presentation
      Linz, Austria, Keynote
    • Year and Date
      2012-08-16
  • [Presentation] Electrochemical Fabrication of Magnetic Nanodot Arrays2012

    • Author(s)
      T. Homma, A. Takami, M. Kunimoto
    • Organizer
      12^<th> International Fischer Symposium
    • Place of Presentation
      Lubeck, Germany, (Invited)
    • Year and Date
      2012-06-04
  • [Presentation] Progress in Nanowire Growth and Mechanistic Analysis of Silicon Electrodeposition in Ionic Liquid2012

    • Author(s)
      J. Komadina, T. Akiyoshi, Y. Ishibashi, Y. Fukunaka, P. Pianetta, T. Homma,
    • Organizer
      221^<st> Meeting of the Electrochemical Society
    • Place of Presentation
      Seattle, USA
    • Year and Date
      2012-05-07
  • [Presentation] Templated electro- deposition of Si nanowires from ionic liquid2011

    • Author(s)
      T. Homma, J. Komadina, Y. Nakano, T. Akiyoshi, Y. Ishibashi, Y. Nishimura, T. Nishida, Y. Fukunaka
    • Organizer
      220^<th> Meeting of the Electrochemical Society
    • Place of Presentation
      Boston, USA, (Invited)
    • Year and Date
      2011-10-10
  • [Presentation] Electrochemical Fabrication of Functional Micro/Nano Structures2011

    • Author(s)
      T. Homma, J. Komadina, M. Kunimoto, Y. Fukunaka
    • Organizer
      International Symposium on Renewable energy & Materials Tailoring
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2011-09-19
  • [Presentation] Electrochemical Fabrication of Functional Micro/Nanostructures: Process Development and Mechanistic Understandings2010

    • Author(s)
      T. Homma
    • Organizer
      218^<th> Meeting of the Electrochemical Society
    • Place of Presentation
      Las Vegas, USA, Award Lecture
    • Year and Date
      2010-10-13
  • [Presentation] Investigation of Electroless Deposition Process using DFT Calculation: Catalytic Effect of Metal Surface2010

    • Author(s)
      T. Homma, M. Kunimoto, R. Kinoshita, A. Otomo, H. Nakai
    • Organizer
      218^<th> Meeting of the Electrochemical Society
    • Place of Presentation
      Las Vegas, USA, (Invited)
    • Year and Date
      2010-10-12
  • [Presentation] Electroless-deposited NiP nanoarrays for nanoimprint replicated from a SiO22010

    • Author(s)
      C-P. Lin, M. Saito, J. B. Ratchford, T. Homma
    • Organizer
      The 7^<th> Asian Conference on Electrochemistry
    • Place of Presentation
      Kumamoto, Japan
    • Year and Date
      2010-05-21
  • [Presentation] Density Functional Theory Study on the Oxidation Reactivity of Hypophosphite Ion as a Reductant for Electroless Deposition Process2010

    • Author(s)
      M. Kunimoto, H. Nakai, T. Homma
    • Place of Presentation
      Vancouver, Canada
    • Year and Date
      2010-04-26
  • [Presentation] Electrochemical approaches for fabrication of micro/nano scale functional structures and devices2010

    • Author(s)
      T. Homma
    • Organizer
      1^<st> Ertl Symposium on Electrochemistry and Catalysis
    • Place of Presentation
      Gwangju, South Korea, (Invited)
    • Year and Date
      2010-04-16
  • [Presentation] The electrochemical formation mechanism of silicon in nanoaqueous solvents2009

    • Author(s)
      Y. Nishimura, T. Nishida, C. Miranda, Y. Fukunaka, T. Nohira, R. Hagiwara
    • Organizer
      216^<th> Meeting of the Electrochemical Society
    • Place of Presentation
      Vienna, Austria
    • Year and Date
      2009-10-07
  • [Presentation] Fabrication of Magnetic Nanodot Array using Electrochemical Deposition Processes2009

    • Author(s)
      T. Homma, T. Ouchi, Y. Arikawa, C-P. Lin, T. Kuno, J. Mizuno, S. Shoji
    • Organizer
      60^<th> Annual Meeting of International Society of Electrochemistry
    • Place of Presentation
      Beijing, China, Keynote
    • Year and Date
      2009-08-19
  • [Presentation] Electrochemical Approaches for Micro and Nano Scale Fabrication of Arrayed Functional Structures2009

    • Author(s)
      T. Homma, T. Ouchi, Y. Arikawa, K. Uzawa
    • Organizer
      17^<th> Inter- national Conference on Composites or Nano Engineering
    • Place of Presentation
      Honolulu, USA, (Invited)
    • Year and Date
      2009-07-28
  • [Presentation] Electrochemical Characterization of Strained Si Crystal Surfaces2009

    • Author(s)
      T. Homma, K. Sakata
    • Organizer
      215^<th> Meeting of the Electrochemical Society
    • Place of Presentation
      San Francisco, USA, (Invited)
    • Year and Date
      2009-05-28
  • [Presentation] Characterization and Modeling of Electroless Deposition Process using DFT Calculation2009

    • Author(s)
      T. Homma, M. Kunimoto, A. Mieno, H. Nakai
    • Organizer
      215^<th> Meeting of the Electrochemical Society
    • Place of Presentation
      San Francisco, USA, (Invited)
    • Year and Date
      2009-05-26
  • [Remarks]

    • URL

      http://www.sci.waseda.ac.jp/english/researchprofiles/advanced/subject07_1.html

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Published: 2015-03-12  

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