2011 Fiscal Year Final Research Report
Development of heavy transition metal complexes showing new photophysical properties arising from cooperative effects between the transition elements
| Project/Area Number |
21550062
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Nagasaki University |
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Principal Investigator |
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| Project Period (FY) |
2009 – 2011
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| Keywords | 重遷移金属元素 / 白金 / 11族元素 / 多核錯体 / 発光 / 光物性 |
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| Research Abstract |
In this study, we have succeeded in the syntheses of luminescent heteropolynuclear complexes containing three transition elements, which exhibit synergetic effect of the three transition elements. Various(diimine) Pt complexes containing 3-t-butylpyrazole reacted with group 11 metal ions to give Z-shaped luminescent heteropolynuclear complexes. We have also succeeded in elucidating the influence of chloride ligands coordinated to Pt atom on the emission energy of heteropolynuclear complexes.
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Research Products
(14 results)
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[Journal Article] Pyrazolato and 3, 5-dimethylpyrazolato bridged dinuclear platinum(II), palladium(II), and their mixed-metal complexes of 2, 2'-bipyrimidine. Syntheses, structures, and luminescent properties2010
Author(s)
K. Umakoshi, K. Kimura, Y. H. Kim, Y. Tsukimoto, Y. Arikawa, M. Onishi, S. Ishizaka, N.
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Journal Title
Kitamura, Bull. Chem. Soc. Jpn
Volume: 83
Pages: 1504-1510
Peer Reviewed
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