2011 Fiscal Year Final Research Report
Investigation of Kaleidoscopic Reactivities of Bis(triarylgermyl) bis(dimethylphenylphosphine) platinum(II)
| Project/Area Number |
21550066
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Gakushuin University |
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Principal Investigator |
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| Project Period (FY) |
2009 – 2011
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| Keywords | C-H活性化 / ゲルマニウムー白金錯体 / 万華鏡反応 / 14族元素-白金錯体 |
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| Research Abstract |
Toly-substituted germyl platinum complexes were prepared and their complexes were characterized by NMR method and X-ray analysis. These complexes underwent smooth cis-trans isomerization, C-H activation, aryl group migration and reductive elimination(Kaleidoscopic reactivates). To get information of kaleidoscopic reactivities of o-toly-substituted germylplatinum complexes(II), synthesis and reactivities of[o-tolMe2Ge] 2PtL2 and(o-tol) 2MeGe] 2PtL2(L=PhMe2P) as model complexes, were prepared and their reactivities were examined. Synthesis and reactivities of aryl-substituted silyl platinum complexes were also examined.
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Research Products
(5 results)
