2011 Fiscal Year Final Research Report
Study on the structure of metal complexes in the excited states by circularly polarized luminescence
| Project/Area Number |
21550067
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Seikei University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
TSUKUDA Toshiaki (70372943)
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| Project Period (FY) |
2009 – 2011
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| Keywords | 金属錯体化学 / 光化学 |
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| Research Abstract |
Sensitivity of the circularly polarized luminescence instrument has been enhanced. CPL spectra of some palladium(0), platinum(0), and copper(I) complexes were observed for the first time using the instrument. The structures of the complexes have been discussed based on the results of the CPL spectra as well as the CD spectra of the complexes, and the results of quantum chemical calculations. Very strong CPL signal has been obtained for a europium complex bearing tridentate ligands.
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