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2011 Fiscal Year Final Research Report

Development of Luminescent Chemosensors Displaying Switching of Analyte-sensitivity

Research Project

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Project/Area Number 21550134
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionOkayama University

Principal Investigator

OKAMOTO Hideki  岡山大学, 大学院・自然科学研究科, 准教授 (30204043)

Project Period (FY) 2009 – 2011
Keywordsセンサー / 蛍光 / 化学発光 / スイッチング
Research Abstract

Luminescent material displaying a specific response, such as changes in luminescence intensity and color, toward an analyte is useful to detect the analyte(referenced as chemosensor). Most conventional chemosensors respond to one analyte. Thus, when we detect two(or more) analytes, we need to use plural receptors responding to each analyte. In the present study, we have developed intelligent chemosensors which display switching of responses to analytes. By utilizing amide functionalities, which shows amide. amidate equilibrium, analyte sensitivity of luminescent sensors to various ionic species and ion pairs were able to be controlled.

  • Research Products

    (14 results)

All 2012 2011 2010 2009

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (9 results)

  • [Journal Article] Fluorescence response of 3-trifluoroacetylaminophthalimide to Li+. I. ion pair induced by 254 nm photolysis in acetonitrile2012

    • Author(s)
      Hideki Okamoto, Hiroyuki Konishi, and Kyosuke Satake
    • Journal Title

      Chem. Commun.

      Volume: 48 Pages: 23462-2348

    • Peer Reviewed
  • [Journal Article] Photochemical synthesis and electronic spectra of fulminene([6] phenacene)2012

    • Author(s)
      Hideki Okamoto, Minoru Yamaji, Shin Gohda, Kaori Sato, Hisako Sugino, and Kyosuke Satake
    • Journal Title

      Res. Chem. Intermed.

      Volume: (in press)

    • Peer Reviewed
  • [Journal Article] Studies on interactions of excited cadmium and mercury atoms with secondary and tertiary alkyl-and silylamines in gas phase2012

    • Author(s)
      Shunzo Yamamoto, Eriko Kainaga, Omar Ahmed, Hideki Okamoto, and Yoshimi Sueishi
    • Journal Title

      J. Photochem. Photobiol. A : Chem.

      Volume: 228 Pages: 38-43

    • Peer Reviewed
  • [Journal Article] Phthalide-derived novel fluoroionophores incorporating picolylamino receptors : Synthesis and response to metal cations2011

    • Author(s)
      Hideki Okamoto, Ayako Matsui, and Kyosuke Satake
    • Journal Title

      Analyst

      Volume: 136 Pages: 3164-3169

    • Peer Reviewed
  • [Journal Article] Facile synthesis of picene from 1, 2-di(1-naphthyl) ethane by 9-fluorenone-sensitized photolysis2011

    • Author(s)
      Hideki Okamoto, Minoru Yamaji, Shin Gohda, Kaori Sato, Hisako Sugino, and Kyosuke Satake
    • Journal Title

      Org. Lett.

      Volume: 13 Pages: 2758-2761

    • Peer Reviewed
  • [Presentation] 分子内電荷移動型蛍光色素を用いるマルチセンシングプローブの構築(依頼講演)2011

    • Author(s)
      岡本秀毅
    • Organizer
      第5回有機π電子系シンポジウム
    • Place of Presentation
      大阪
    • Year and Date
      20111125-26
  • [Presentation] ジピコリルアミノメチルレセプターを有するアントラセンジカルボヒドラジドの合成および金属イオン種に対する化学発光応答2011

    • Author(s)
      岡本秀毅, 山崎奈緒美, 松井絢子, 佐竹恭介
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎
    • Year and Date
      20110906-08
  • [Presentation] Preparation of Anthracenedicarboxylic-acid-derived Fluorescence and Chemiluminescence Probes Incorporating Dipicolylaminomethyl Receptors and Their Luminescence Responses to Metal Cations2011

    • Author(s)
      Hideki Okamoto, Ayako Matsui, Naomi Yamasaki, and Kyosuke Satake
    • Organizer
      XXV^<th> International Conference on Photochemistry
    • Place of Presentation
      Beijing, China
    • Year and Date
      20110807-12
  • [Presentation] ジピコリルアミノレセプターで修飾されたアントラセンジカルボン酸類縁体をルミノフォアとして用いるPETプローブの構築と発光特性2011

    • Author(s)
      岡本秀毅, 松井絢子, 山崎奈緒実, 佐竹恭介
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      横浜
    • Year and Date
      20110326-29
  • [Presentation] トリフルオロアセトアミド置換キノリンの蛍光挙動:アミド-アミデート平衡を利用した金属イオン応答スイッチング2010

    • Author(s)
      岡本秀毅, 佐藤温子, 佐竹恭介
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本
    • Year and Date
      20101106-07
  • [Presentation] トリフルオロアセトアミド置換キノリン誘導体の亜鉛イオン及び銅イオンに対する蛍光応答性スイッチング2010

    • Author(s)
      岡本秀毅, 佐藤温子, 佐竹恭介
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      東大阪
    • Year and Date
      20100326-29
  • [Presentation] トリフルオロアセタミド置換フタルイミドの蛍光挙動:ハロゲン化物イオン及びイオンペアへの光応答2009

    • Author(s)
      岡本秀毅, 小西廣幸, 佐竹恭介
    • Organizer
      2009年光化学討論会
    • Place of Presentation
      桐生
    • Year and Date
      20090916-18
  • [Presentation] Fluorescence behavior of 3-trifluoroacetylamino derivative of phthalimide : Photochemically induced response to Li^+/I^-ion pair2009

    • Author(s)
      Hideki Okamoto, Hiroyuki Konishi, Kyosuke Satake
    • Organizer
      XXIV^<th> International Conference on Photochemistry
    • Place of Presentation
      Toledo, Spain
    • Year and Date
      20090719-24
  • [Presentation] ひかる色素の話2009

    • Author(s)
      岡本秀毅
    • Organizer
      岡山県高等学校教育研究会理科部会総会講演会
    • Place of Presentation
      岡山
    • Year and Date
      2009-05-13

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Published: 2013-07-31  

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