• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2011 Fiscal Year Final Research Report

Development of Novel Fluorinated Polymeric Nanoparticles According to the Environmental Changes and Design of Their Composite Functionalized Life Materials

Research Project

  • PDF
Project/Area Number 21550179
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic industrial materials
Research InstitutionHirosaki University

Principal Investigator

SAWADA Hideo  弘前大学, 大学院・理工学研究科, 教授 (50259909)

Project Period (FY) 2009 – 2011
Keywords含フッ素オリゴマー / ナノコンポジット / シリカナノ粒子 / 表面処理 / 防汚・親水 / 超親水 / 超撥油性 / 抗菌活性
Research Abstract

A variety of fluorinated oligomers/silica nanocomposites, which are useful for new fluorinated polymeric nanoparticle surface modifiers, have been prepared in this study, and their dispersibility and thermal stability have been also studied in detail. Furthermore, based on these results, we have succeeded in the elucidation of the oleophobic-hydrophilic characteristics through the flip-flop motion according to the environmental change on the modified surface treated with these fluorinated polymeric nanoparticles.

  • Research Products

    (34 results)

All 2012 2011 2010 2009 Other

All Journal Article (27 results) (of which Peer Reviewed: 27 results) Presentation (5 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Preparation and Application of Novel Fluoroalkyl End-capped Oligomeric Nanocomposites2012

    • Author(s)
      H. Sawada
    • Journal Title

      Polym. Chem.(RSC)

      Volume: 3巻 Pages: 46-65

    • Peer Reviewed
  • [Journal Article] Coloring-Decoloring Behavior of Amphiphilic Fluoroalkyl End-Capped N-(1,1-dimethyl-3-oxobuty1)acrylamide-Acryloylmorpholine Cooligomer/Fluorescein Nanocomposites in Protic and Aprotic Solvents2012

    • Author(s)
      H. Sawada, S. Izumi, K. Sasazawa, and M. Yoshida
    • Journal Title

      J. Colloid Interface Sci

    • URL

      http://dx.doi.org/10.1016/j.jcis.2012.03.017.

    • Peer Reviewed
  • [Journal Article] Preparation and Applications of Novel Fluoroalkyl End-capped Oligomers/Polyimide/Silica Nanocomposites2012

    • Author(s)
      Y. Goto, N. Otsuka, and H. Sawada
    • Journal Title

      Polym. Adv. Technol

      Volume: 23巻 Pages: 290-298

    • Peer Reviewed
  • [Journal Article] Biphenylene Units Possessing Flammable and Non-flammable Characteristics in Fluoroalkyl End-capped Vinyltrimethoxysilane Origomeric Silica Gel Matrices after Calcination at 800℃2011

    • Author(s)
      Y. Goto, Y. Matsuki, M. Nishida, S. Oyama, K. Chikama, and H. Sawada
    • Journal Title

      Colloid Polym. Sci

      Volume: 290巻 Pages: 11-21

    • Peer Reviewed
  • [Journal Article] Preparation and Properties of Novel Cross-linked Fluoroalkyl End-capped Cooligomeric Nanoparticles Possessing Double Decker-type Aromatic Silsesquioxane Segments as Core Units2011

    • Author(s)
      Y. Goto, K. Yoshida, and H. Sawada
    • Journal Title

      Colloid Polym. Sci

      Volume: 289巻 Pages: 1493-1502

    • Peer Reviewed
  • [Journal Article] Creation of Coating Surfaces Possessing Superhydrophobic and Superoleophobic Characteristics with Fluoroalkyl End-capped Vinyltrimethoxysilane Oligomeric Nanocomposites Having Biphenylene Segments2011

    • Author(s)
      Y. Goto, H. Takashima, K. Takishita, and H. Sawada
    • Journal Title

      J. Colloid Interface Sci

      Volume: 362巻 Pages: 375-381

    • Peer Reviewed
  • [Journal Article] Low Molecular Weight Aromatic Compounds Possessing a Nonflammable Characteristic in Fluoroalkyl End-capped Acrylic Acid Oligomer/Silica Nanocomposite Matrices after Calcination at 800℃ under Atmospheric Conditions2011

    • Author(s)
      H. Sawada, M. Kikuchi, and M. Nishida
    • Journal Title

      J. Polym. Sci. Part A ; Polym. Chem

      Volume: 49巻 Pages: 1070-1078

    • Peer Reviewed
  • [Journal Article] Preparation of Perfluoro-1, 3-Propanedisulfonic Acid/Silica Nanocomposites-Encapsulated Low Molecular Weight Aromatic Compounds Possessing a Nonflammable Characteristic2011

    • Author(s)
      H. Sawada, X. Liu, Y. Goto, M. Kikuchi, T. Tashima, and M. Nishida
    • Journal Title

      J. Colloid Interface Sci

      Volume: 356巻 Pages: 8-15

    • Peer Reviewed
  • [Journal Article] Iodine Transfer Copolymerization of Vinylidene Fluoride, α-Trifluoromethacrylic Acid and Hexafluoropropene for Exceptional Thermostable Fluoropolymers/Silica Nanocomposites2011

    • Author(s)
      H. Sawada, T. Tashima, Y. Nishiyama, M. Kikuchi, G. Kostov, Y. Goto, and B. Ameduri
    • Journal Title

      Macromolecules

      Volume: 44巻 Pages: 1114-1124

    • Peer Reviewed
  • [Journal Article] Facile Preparation of Gold Nanoparticles through Autoreduction of Gold Ions in the Presence of Fluoroalkyl End-capped Cooligomeric Aggregates : LCST-triggered Sol-Gel Switching Behavior of Novel Thermoresponsive Fluoroalkyl End-capped Cooligomeric Nanocomposite-encapsulated Gold Nanoparticles2010

    • Author(s)
      H. Sawada and K. Takahashi
    • Journal Title

      J. Colloid Interface Sci

      Volume: 351巻 Pages: 166-170

    • Peer Reviewed
  • [Journal Article] Application of Ionic Liquid as Surface Modifier : Switching Behavior of Novel Fluoroalkyl End-capped Vinytrimethoxysilane Oligomer-Tri-n-butyl-[(3-trimethoxysilyl)propyl]phosphonium Chloride Silica Nanocomposites between Superhydrophilicity and Oleophobicity2010

    • Author(s)
      H. Sawada, Y. Okada, Y. Goto, T. Fukui, T. Shibukawa, S. Kodama, and M. Sugiya
    • Journal Title

      J. Jpn. Soc. Colour Mater

      Volume: 83巻 Pages: 368-373

    • Peer Reviewed
  • [Journal Article] UV-induced Switching Behavior of Novel Fluoroalkyl End-capped Vinyltrimethoxysilane Oligomer/Titanium Oxide Nanocomposite between Superhydrophobicity and Superhydrophilicity with Good Oleophobicity2010

    • Author(s)
      E. Sawada, H. Kakehi, Y. Chounan, M. Miura, Y. Sato, N. Isu, and H. Sawada
    • Journal Title

      Composites Part B

      Volume: 41巻 Pages: 498-502

    • Peer Reviewed
  • [Journal Article] Selective Preparation of Novel Fluoroalkyl End-capped Cooligomeric Nanocomposites-Encapsulated Magnetites and Magnetite-adsorbing Cooligomeric Nanoparticles2010

    • Author(s)
      H. Sawada, T. Kijima, and M. Mugisawa
    • Journal Title

      Polymer J

      Volume: 42巻 Pages: 494-500

    • Peer Reviewed
  • [Journal Article] Synthesis and Applications of Novel Fluoroalkyl End-capped Cooligomers Containing Diphenylacetylene Segments : a New Approach to the Surface Arrangement of Diphenylacetylene Segments on the Traditional Organic Polymer2010

    • Author(s)
      M. Mugisawa, A. Orita, J. Otera, and H. Sawada
    • Journal Title

      Polym. Adv. Technol

      Volume: 21巻 Pages: 158-163

    • Peer Reviewed
  • [Journal Article] Surface Functionalization of Fluoroalkyl End-Capped Oligomer/Silica Nancomposites via Graft Polymerization : Application to the Dispersion of Fullerene and Single-walled Carbon Nanotube in Water with These Nanocomposites2010

    • Author(s)
      H. Sawada, Y. Goto, and T. Narumi
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: 83巻 Pages: 82-91

    • Peer Reviewed
  • [Journal Article] Preparation of Novel Fluoroalkyl End-capped Trimethoxyvinylsilane Oligomeric Nanoparticles-Encapsulated Binaphthol : Encapsulated Binaphthol Possessing a Thermally Stable Characteristic Even at 800℃2010

    • Author(s)
      H. Sawada, Y. Matsuki, Y. Goto, S. Kodama, M. Sugiya, and Y. Nishiyama
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: 83巻 Pages: 75-81

    • Peer Reviewed
  • [Journal Article] Fluoroalkyl End-capped Oligomers Possessing Nonflammable and Flammable Characteristics in Silica Gel Matrices after Calcination at 800℃2010

    • Author(s)
      H. Sawada, T. Tashima, H. Kakehi, Y. Nishiyama, M. Kikuchi, M. Miura, Y. Sato and N. Isu
    • Journal Title

      Polym. J

      Volume: 42巻 Pages: 167-171

    • Peer Reviewed
  • [Journal Article] Preparation of Size-controlled Cross-linked Fluoroalkyl End-capped Oligomer/Gold Nanocomposites2009

    • Author(s)
      H. Sawada, A. Sasaki, and K. Sasazawa
    • Journal Title

      Colloid Surf. A : Physicochem. Eng. Aspects

      Volume: 337巻 Pages: 57-60

    • Peer Reviewed
  • [Journal Article] Selective Encapsulation-Release and Photodegradation Characteristics of Organic Dyes by Cross-linked Fluoroalkyl End-capped Oligomeric Nanocomposites Possessing Aromatic Siloxane Segments as Core Units2009

    • Author(s)
      Y. Goto and H. Sawada
    • Journal Title

      Colloid Polym. Sci

      Volume: 287巻 Pages: 1317-1323

    • Peer Reviewed
  • [Journal Article] Preparation of Novel Cross-linked Fluoroalkyl End-capped Cooligomeric Nanoparticles-Encapsulated Cytochrome c in Water and Ionic Liquids2009

    • Author(s)
      Y. Okada and H. Sawada
    • Journal Title

      Colloid Polym. Sci

      Volume: 287巻 Pages: 1359-1363

    • Peer Reviewed
  • [Journal Article] Preparation and Applications of Novel Cross-linked Fluoroalkyl End-capped Oligomeric Nanocomposites Possessing Aromatic Siloxane Segments as Core Units2009

    • Author(s)
      Y. Goto, M. Mugisawa, and H. Sawada
    • Journal Title

      Polym. Adv. Technol

      Volume: 20巻 Pages: 1076-1081

    • Peer Reviewed
  • [Journal Article] Fluoroalkyl End-capped Oligomer Possessing a Nonflammable Characteristic in Silica Gel Matrices even at 800℃ under Atmospheric Conditions2009

    • Author(s)
      H. Sawada, H. Kakehi, T. Tashima, Y. Nishiyama, M. Miura, and N. Isu
    • Journal Title

      J. Appl. Polym. Sci

      Volume: 112巻 Pages: 3482-3487

    • Peer Reviewed
  • [Journal Article] Preparation and Properties of Novel Fluoroalkyl End-capped Oligomers/Hydrogarnet Nanocomposites2009

    • Author(s)
      H. Sawada, S. Sekiguchi, H. Kakehi, T. Mori, M. Miura, and N. Isu
    • Journal Title

      J. Composite Mater

      Volume: 43巻 Pages: 3291-3301

    • Peer Reviewed
  • [Journal Article] フルオロアルキル基含有オリゴマー/ポリビニルアルコール/炭酸カルシウムナノコンポジットの調製とその応用2009

    • Author(s)
      掛樋浩司、鹿内康史、三浦正嗣、井須紀文、佐藤有亮、沢田英夫
    • Journal Title

      材料技術

      Volume: 27巻 Pages: 151-162

    • Peer Reviewed
  • [Journal Article] Facile Preparation and Characterization of Novel Fluoroalkyl End-capped Oligomer/Zinc Oxide Nanocomposites2009

    • Author(s)
      K. Sasazawa, Y. Hirayama, and H. Sawada
    • Journal Title

      Polym. Int

      Volume: 58巻 Pages: 177-182

    • Peer Reviewed
  • [Journal Article] Preparation of Ionic Liquid/Silica Nanocomposites Possessing No Weight Loss Characteristic after Calcination at 800℃

    • Author(s)
      H. Sawada, T. Sasaki, M. Nishida, S. Kodama, M. Sugiya
    • Journal Title

      Colloid Polym. Sci

    • DOI

      DOI:10.1007/s00396-012-2608-z

    • Peer Reviewed
  • [Journal Article] Controlled Immobilization of Palladium Nanoparticles in Two Different Fluorinated Polymeric Aggregate Cores and Their Application in Catalysis

    • Author(s)
      T. Kijima, I. Javakhishvili, K. Jankova, S. Hvilsted, S. Kodama, M. Sugiya, and H. Sawada
    • Journal Title

      Colloid Polym Sci

    • DOI

      DOI:10.1007/s00396-011-2567-9

    • Peer Reviewed
  • [Presentation] Self-assembly of Ketones in Fluoroalkyl End-capped Betaine-type Oligomeric Gel Network Cores2011

    • Author(s)
      H. Sawada
    • Organizer
      242nd American Chemical Society National Meeting & Exposition
    • Place of Presentation
      Denver, Colorado, USA
    • Year and Date
      20110800
  • [Presentation] Low Molecular Weight Aromatic Compounds Possessing a Nonflammable Characteristic in Fluoroalkyl End-capped Oligomers/Silica Nanocomposite Matrices after Calcination at 800℃2011

    • Author(s)
      H. Sawada
    • Organizer
      14th IUPAC International Symposium on Macromolecular Complexes, MMC-14
    • Place of Presentation
      Helsinki, Finland
    • Year and Date
      20110800
  • [Presentation] Fluoroalkyl End-capped Oligomers Possessing Nonflammable and Flammable Characteristics in Silica Gel Matrices2010

    • Author(s)
      H. Sawada
    • Organizer
      Fluoropolymer (ACS Division of Polymer Chemistry) 2010
    • Place of Presentation
      Meze, France
    • Year and Date
      20100600
  • [Presentation] Preparation and Applications of Fluoroalkyl End-capped Oligomer/Silica Nanocomposites Possessing a Potent and Selective Anti-HIV-1 Activity2010

    • Author(s)
      H. Sawada
    • Organizer
      Particles 2010 : Medical/Biochemical Diagnostic, Pharmaceutical, and Drug Delivery Applications of Particle Technology, Lake Buena Vista, Regal Sun Resort
    • Place of Presentation
      Florida, USA
    • Year and Date
      20100500
  • [Presentation] Invited Keynote Speaker : Preparation of Noel Fluoroalkyl End-capped Oligomer/Silica Nanocomposites Possessing No Weight Loss Behavior Even at 800℃2009

    • Author(s)
      H. Sawada
    • Organizer
      11^<th> Pacific Polymer Conference 2009
    • Place of Presentation
      Cairns, Australia
    • Year and Date
      20091200
  • [Book] 非金属材料のコーティング技術辞典:フッ素系高分子ナノコンポジット類の合成・物性・応用2010

    • Author(s)
      沢田英夫
    • Total Pages
      235-246
    • Publisher
      (株)産業技術サービスセンター
  • [Remarks]

    • URL

      http://www.st.hirosaki-u.ac.jp/~fsaw/

URL: 

Published: 2013-07-31  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi