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2010 Fiscal Year Final Research Report

Highly efficient removal and degradation of toxic compounds with novel host molecule-metal ion complexes having enzyme-like activities

Research Project

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Project/Area Number 21710078
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Environmental technology/Environmental materials
Research InstitutionNagoya University

Principal Investigator

MATSUMIYA Hiroaki  Nagoya University, 工学研究科, 助教 (10362287)

Project Period (FY) 2009 – 2010
Keywordsチアカリックスアレーン / セリウム / 界面活性剤 / アドミセル / 有機リン系農薬 / カーバメイト系農薬 / エステル加水分解
Research Abstract

The present study was conducted with a view to developing highly efficient environmental purification systems by which the removal and subsequent detoxification of hazardous chemicals can be achieved with novel host molecule-metal ion complexes having enzyme-like activities. Taking organophosphate (e.g., fenitrothion, dichlorvos, and paraoxon) and carbamate (e.g., carbaryl and propoxur) pesticides as examples, their removal from water, followed by the hydrolytic degradation to reduce their neurotoxicity, was examined. The obtained results provide guidelines for the further design and development of environmental purification materials and systems for practical use.

  • Research Products

    (9 results)

All 2010 2009

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (7 results)

  • [Journal Article] Catalytic degradation of organophosphates and carbamates with cerium(IV)-thiacalix[4]arene complexes2010

    • Author(s)
      H.Matsumiya, H.Ishima, H.Nakamura, M.Hiraide
    • Journal Title

      Proceedings of International Conference on Environment CD-ROM

    • Peer Reviewed
  • [Journal Article] Phosphoester hydrolysis by cerium(IV)-thiacalix[4]arene complexes and its application to immunoassay2009

    • Author(s)
      H.Matsumiya, H.Nakamura, M.Hiraide
    • Journal Title

      Analytical and Bioanalytical Chemistry Vol.394, No.5

      Pages: 1471-1476

    • Peer Reviewed
  • [Presentation] Catalytic degradation of organophosphates and carbamates with cerium(IV)-thiacalix[4]arene complexes2010

    • Author(s)
      H.Matsumiya, H.Ishima, H.Nakamura, M.Hiraide
    • Organizer
      International Conference on Environment 2010
    • Place of Presentation
      Park Royal Hotel (Penang, Malaysia)
    • Year and Date
      20101213-20101215
  • [Presentation] アドミセルを用いる水中フェニトロチオンの捕集と触媒的加水分解2010

    • Author(s)
      石間早翔, 松宮弘明, 平出正孝
    • Organizer
      第29回溶媒抽出討論会
    • Place of Presentation
      広島大学東広島キャンパス(広島県東広島市)
    • Year and Date
      20101126-20101127
  • [Presentation] 界面活性剤によるチアカリックスアレーン金属錯体の触媒能向上とイムノアッセイの高感度化2010

    • Author(s)
      福島浩之, 永井真二, 松宮弘明, 平出正孝
    • Organizer
      第29回溶媒抽出討論会
    • Place of Presentation
      広島大学東広島キャンパス(広島県東広島市)
    • Year and Date
      20101126-20101127
  • [Presentation] Extraction of trace constituents with hydrophobic aggregates for water analysis2010

    • Author(s)
      M.Hiraide, T.Saitoh, H.Matsumiya
    • Organizer
      The 5th International Conference on Ion Exchange
    • Place of Presentation
      The University of Melbourne (Melbourne, Australia)
    • Year and Date
      20100718-20100721
  • [Presentation] Collection of trace metals with admicelles and the subsequent flotation for environmental water analysis2009

    • Author(s)
      H.Matsumiya, Y.Yatsuya, K.Kitakata, M.Hiraide
    • Organizer
      The 3rd Asian Conference on Colloids and Interface Science
    • Place of Presentation
      International Convention Center Jeju (Seogwipo, Korea)
    • Year and Date
      20091011-20091014
  • [Presentation] カチオン界面活性剤を増感剤とするチアカリックスアレーン錯体によるイムノアッセイ2009

    • Author(s)
      松宮弘明, 永井真二, 平出正孝
    • Organizer
      日本分析化学会第58年会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター(北海道札幌市)
    • Year and Date
      20090924-20090926
  • [Presentation] アドミセルおよびチアカリックスアレーン金属錯体を用いる農薬成分の捕集と分解2009

    • Author(s)
      石間早翔, 松宮弘明, 平出正孝
    • Organizer
      第70回分析化学討論会
    • Place of Presentation
      和歌山大学栄谷キャンパス(和歌山県和歌山市)
    • Year and Date
      20090516-20090517

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Published: 2012-02-13   Modified: 2016-04-21  

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