2011 Fiscal Year Final Research Report
Development of Novel Transformations via Cleavage of Inactive Bonds using Group 7 Transition Metal Catalysts
Project/Area Number |
21750103
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Single-year Grants |
Research Field |
Synthetic chemistry
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Research Institution | Okayama University |
Principal Investigator |
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Project Period (FY) |
2009 – 2011
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Keywords | レニウム / マンガン / C-H結合活性化 / C-C結合切断 / 挿入 / 付加 / 位置選択的 / 触媒反応 |
Research Abstract |
We focused on group 7 transition metal compounds, such as rhenium and manganese complexes, and carried out investigations to develop novel and efficient transformations using such complexes as catalysts. As a result, we have succeeded in the development of transformations via the cleavage of C-H or C-C bond, which forms skeletons of organic molecules and is difficult to be cleaved. In addition, we also developed regioselective cycloaddition reactions.
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[Presentation] Indium-Catalyzed Retro-Claisen Rearrangement2010
Author(s)
Shun-ichi Yamamoto, Atsushi Kawata, Taihei Noborio, Takashi Matsuki, Kazumi Takata, Yoichiro Kuninobu, and Kazuhiko Takai
Organizer
The International Chemical Congress of Pacific Basin Societies(Pacifichem 2010)
Place of Presentation
Honolulu, Hawaii, USA
Year and Date
20101215-20
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