2022 Fiscal Year Final Research Report
Development of Functional Metal Complexes by Using Microfluidic systems
| Project/Area Number |
21K20544
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Multi-year Fund |
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| Review Section |
0501:Physical chemistry, functional solid state chemistry, organic chemistry, polymers, organic materials, biomolecular chemistry, and related fields
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| Research Institution | Kwansei Gakuin University |
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Principal Investigator |
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| Project Period (FY) |
2021-08-30 – 2023-03-31
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| Keywords | 錯体化学 / フロー合成 |
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| Outline of Final Research Achievements |
Metal complexes exhibit a wide variety of functional properties depending on their molecular arrangement. Therefore, control of molecular arrangement is critical requirement in coordination chemistry. In this study, we aimed to control the packing structure by utilizing microfluidic system. By precisely controlling the mixing process and the initial stage of the reaction, we succeeded in controlling the packing structure of one-dimensional coordination polymers and crystal size of metal-organic frameworks. Our results based on the use of microfluidic systems will provide a new strategy for tuning the packing structure.
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| Free Research Field |
錯体化学
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| Academic Significance and Societal Importance of the Research Achievements |
今日まで分子集積を制御するための試みが数多く行われてきたが、反応時間や濃度、温度等が制御されたフラスコ合成が主流である。本研究が着目したフロー精密合成システムは、医薬品の合成等、有機合成分野において多用される中、金属錯体の合成に利用した報告例は極めて限定的である。一方、本研究成果は、金属錯体の合成に有用であることを実証するものであり、集積構造および機能物性の自在な創出・制御に向けて有用な知見を与える。
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