2012 Fiscal Year Final Research Report
Synthesis and Application of Planar Chiral Heterocycles
| Project/Area Number |
22350019
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Kyushu University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
IGAWA Kazunobu 九州大学, 先導物質化学研究所, 助教 (80401529)
ITO Masato 九州大学, 先導物質化学研究所, 准教授 (20293037)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 有機化学 / 不斉合成 / 面不斉 / ヘテロ中員環分子 / 面不斉錯体 / 面不斉カルボニル化合物 |
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| Research Abstract |
To explore the chemistry of planar chiral heterocycles, we achieved the following: 1) stereoselective multimodal transformations of planar chiral nine-membered diallylic amides; 2) a unique functional group transformation of planar chiral nine-membered diallylic amides by using PtCl2 (2,4,6-trimethylpyridine) complexes; 3) enantioselective synthesis of planar chiral nine-membered diallylic amides; 4) synthesis and application of planar chiral (E)-5-cyclononen-1-one and its enolate; and 5) synthesis and application of planar chiral [7]orthocyclophanes
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