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2012 Fiscal Year Final Research Report

Creation of Revolutionary Organic Light-emitting Materials Exhibiting Highly Efficient Solid-state Emission

Research Project

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Project/Area Number 22350081
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials/Devices
Research InstitutionKyoto Institute of Technology (2011-2012)
Kyoto University (2010)

Principal Investigator

SHIMIZU Masaki  京都工芸繊維大学, 工芸科学研究科, 教授 (10272709)

Co-Investigator(Kenkyū-buntansha) MORISUE Mitsuhiko  京都工芸繊維大学, 工芸科学研究科, 助教 (40403357)
Project Period (FY) 2010 – 2012
Keywords発光材料 / 蛍光 / 固体蛍光
Research Abstract

We have succeeded in the development of diaminobis(styryl)-benzenes, diaminoterephthalates, bis(EWD-substituted phenyl)bis(EDG-substituted phenyl)ethenes, spirobi(2,3-diarylindene)s, and silicon-bridged 2-arylindoles as novel fluorophores that exhibit highly efficient photoluminescence in the solid states. The relationship between substituents and emission colors are disclosed in each chromophore. Some of the designed compounds are confirmed to act as superior light-emitting materials in organic light-emitting devices.

  • Research Products

    (20 results)

All 2013 2012 2011 2010

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (10 results) Book (1 results)

  • [Journal Article] ケイ素ビアリールの新合成法と発光特性2013

    • Author(s)
      清水剛毅
    • Journal Title

      有機合成化学協会誌

      Volume: 71(4) Pages: 307-318

    • URL

      http://dx.doi.org/10.5059/yukigoseikyokaishi.71.307

    • Peer Reviewed
  • [Journal Article] 固体のままで美しく発光する有機材料2013

    • Author(s)
      清水剛毅
    • Journal Title

      化学

      Volume: 68(1) Pages: 24-29

    • URL

      http://www.kagakudojin.co.jp/kagaku/web-kagaku03/c6801/c6801-shimizu/HTML/index1.html

    • Peer Reviewed
  • [Journal Article] Efficient blue electroluminescence of silylenebridged 2-(2-naphthyl)indole2012

    • Author(s)
      Shimizu, M.;Mochida, K.; Asai, Y.; Yamatani, A.; Kaki, R.;Hiyama, T.; Nagai, N.; Yamagishi, H.; Furutani, H.
    • Journal Title

      J. Mater. Chem

      Volume: 22(10) Pages: 4337-4342

    • DOI

      DOI:10.1039/C2JM15173A

    • Peer Reviewed
  • [Journal Article] 1,4-Bis(diarylamino)-2,5-bis(4-cyanophenylethenyl) benzenes: Fluorophores Exhibiting Efficient Red and Near-Infrared Emissions in Solid State2012

    • Author(s)
      Shimizu, M.; Kaki, R.; Takeda, Y.; Hiyama, T.; Nagai, N.; Yamagishi, H.; Furutani, H.
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 51(17) Pages: 4095-4099

    • Peer Reviewed
  • [Journal Article] Silicon-Bridged Biaryls: Molecular Design, New Synthesis, and Luminescence Control2012

    • Author(s)
      Shimizu, M.; Hiyama, T.
    • Journal Title

      Synlett

      Volume: 23(07) Pages: 973-989

    • DOI

      DOI: 10.1055/s-0031-1290566

    • Peer Reviewed
  • [Journal Article] Photophysical properties of heteroaromatic ring-fused (di)benzosiloles.2011

    • Author(s)
      Shimizu, M.; Mochida, K.; Katoh, M.; Hiyama, T.
    • Journal Title

      Sci. China Chem

      Volume: 54(12) Pages: 1937-1947

    • DOI

      DOI: 10.1007/s11426-011-4396-6

    • Peer Reviewed
  • [Journal Article] Highly Efficient Blue Fluorescence from 3,2'- Silylene-Bridged 2-Phenylindoles in the Solid State2011

    • Author(s)
      Shimizu, M.; Mochida, K.; Hiyama, T.
    • Journal Title

      J.Phys. Chem. C

      Volume: 115(22) Pages: 11265-11274

    • DOI

      DOI: 10.1021/jp201168x

    • Peer Reviewed
  • [Journal Article] Synthesis and Photophysical Properties of Dimethoxybis(3,3,3-trifluoropropen-1-yl)benzenes:Compact Chromophores Exhibiting Violet Fluorescence in the Solid State.2011

    • Author(s)
      Shimizu, M.;Takeda, Y.; Higashi, M.; Hiyama, T.
    • Journal Title

      Chem.Asian J

      Volume: 6(9) Pages: 2536-2544

    • DOI

      DOI: 10.1002/asia.201100176

    • Peer Reviewed
  • [Journal Article] Twisting strategy applied to N,N-diorganoquinacridones leads to organic chromophores exhibiting efficient solid-state fluorescence.2011

    • Author(s)
      Shimizu, M.; Asai, Y.; Takeda, Y.; Yamatani, A.; Hiyama, T.
    • Journal Title

      Tetrahedron Lett

      Volume: 52(32) Pages: 4084-4089

    • DOI

      DOI: 10.1016/j.tetlet.2011.05.087

    • Peer Reviewed
  • [Presentation] D-π-A 型シラフルオレンの設計と白色 発光ポリマーへの対応2013

    • Author(s)
      清水剛毅
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(草津)
    • Year and Date
      20130322-25
  • [Presentation] reparation and Properties of Silylene-bridged 2-(2-naphthyl)indole2012

    • Author(s)
      Masaki Shimizu
    • Organizer
      4th Asian Silicon Symposium
    • Place of Presentation
      Tsukuba
    • Year and Date
      20121021-24
  • [Presentation] Palladium-catalyzed Synthesis and Luminescent Properties of Silicon-bridged Biaryls2011

    • Author(s)
      Masaki Shimizu
    • Organizer
      2011 Japan-Taiwan Joint Symposium on Organic Chemistry
    • Place of Presentation
      Kyoto
    • Year and Date
      20111119-21
  • [Presentation] Palladium-catalyzed Synthesis and Luminescent Properties of Silicon-bridged Biaryls2011

    • Author(s)
      Masaki Shimizu
    • Organizer
      Second International Collaborative and Cooperative Chemistry Symposium
    • Place of Presentation
      The University of Queensland, Brisbane (Australia)
    • Year and Date
      20111031-1101
  • [Presentation] Design and development of novel π-conjugated molecules exhibiting highly efficient solid state emission2011

    • Author(s)
      Masaki Shimizu
    • Organizer
      10th International Symposium on Functional π-Electron Systems
    • Place of Presentation
      Friendship Hotel, Beijing(China)
    • Year and Date
      20111013-17
  • [Presentation] Palladium-Catalyzed Synthesis and Photophysical Properties of Silicon-Bridged Biaryls2011

    • Author(s)
      Masaki Shimizu
    • Organizer
      The 14th Asian Chemical Congress (14ACC)
    • Place of Presentation
      Bangkok (Thailand)
    • Year and Date
      20110905-08
  • [Presentation] Silicon-bridged Biaryls: Molecular Design, New Synthesis, and Luminescence Control2011

    • Author(s)
      Masaki Shimizu
    • Organizer
      6th Green Elements Science Symposium (International Symposium)
    • Place of Presentation
      Okayama
    • Year and Date
      2011-12-03
  • [Presentation] Synthesis and Photophysical Properties of 2-Donor-7-acceptor-9-silafluorenes2010

    • Author(s)
      Masaki Shimizu
    • Organizer
      57th Symposium on Organometallic Chemistry
    • Place of Presentation
      Tokyo
    • Year and Date
      20100916-18
  • [Presentation] Development of Fluorinated π-conjugated Molecules Directed Toward Applications in Optoelectronic Devices2010

    • Author(s)
      Masaki Shimizu
    • Organizer
      Perugia Fluorine Days
    • Place of Presentation
      Perugia (Italy)
    • Year and Date
      20100711-15
  • [Presentation] Synthesis and Properties of Fluorinated π-Conjugated Functional Molecules2010

    • Author(s)
      Masaki Shimizu
    • Organizer
      The 8th Japan-China Symposium on Fluorochemical Industry
    • Place of Presentation
      Tokyo
    • Year and Date
      20100610-11
  • [Book] Diaminobenzene-Cored Fluorophores Exhibiting Highly Efficient Solid-State LuminescenceIn Aggregation- Induced Emission Chapter 4 (B. Z. Tang, A. Qin,Eds.)2013

    • Author(s)
      Masaki Shimizu
    • Publisher
      Wiley(in press)

URL: 

Published: 2014-08-29  

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