2012 Fiscal Year Final Research Report
Construction of unique photo-functional molecules based on thproperties of heteroatoms and azulene
| Project/Area Number |
22550039
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Yamaguchi University |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2012
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| Keywords | 典型元素 / アズレン / アザアズレン / 非ベンゼノイド / 光機能 |
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| Research Abstract |
Construction of photo-functional molecules based on the properties of heteroatoms and azulene was tried by introduction of a heteroatom (phosphorus or boron) into the position adjacent to a coordinative functional group in the 5-membered ring of azulene. Thus, we revealed how the intramolecular coordination of a pyridyl group with a phosphorus atom affected the -electron system of azulene. Furthermore, we found that the iminoazulenes prepared by the condensation of an amino acid with 2-boryl-1-formylazulene showed a variety of coloration in solid states depending on the structure of the amino acid.
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[Journal Article] Synthesis of 12,12a-dihydro-7,12a-diazacyclohepta[cd]benz[g]azulen-12-one(cyclohepta[mn]pyrrolo[2,1-c][1,4]-benzodiazepin-12-one) and evaluation of cytotoxic activity against HeLa S3 cells2011
Author(s)
E. Yoshioka, H. Fujii, T. Murafuji, R. Ikeda, T. Konakahara, T. Gunji, N. Abe
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Journal Title
Heterocycles
Volume: 83
Pages: 1409-1415
Peer Reviewed
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