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2012 Fiscal Year Final Research Report

Development of Core-Modified Phthalocyanines

Research Project

  • PDF
Project/Area Number 22550052
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionOsaka University

Principal Investigator

TAKAMITSU Fukuda  大阪大学, 大学院・理学研究科, 講師 (40344741)

Project Period (FY) 2010 – 2012
Keywordsフタロシアニン / 芳香族色素 / 芳香族錯体 / 熱変換
Research Abstract

Based on the newly developed lithium-assisted synthetic methods, core-modified phthalocyanine derivatives have been successfully obtained. The chemical and physical properties of these have been investigated in detail, leading to thermally-convertible phthalocyanine precursors and multi-layered phthalocyanine analogues showing exceptionally low-energy electronic excited states, which are potentially useful for developing novel organic electronic materials.

  • Research Products

    (19 results)

All 2013 2012 2011 2010 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (6 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Nickel and palladium complexes of seco-tribenzoporphyrazines derived from one-pot condensation of 1,3-diiminoisoindoline2013

    • Author(s)
      Ippei Sugita, Soji Shimizu, Takamitsu Fukuda, Nagao Kobayashi
    • Journal Title

      Tetrahedron Lett

      Volume: 54 Pages: 1599-1601

    • Peer Reviewed
  • [Journal Article] 可溶性フタロシアニン前駆体の簡便合成と熱変換特性2012

    • Author(s)
      福田貴光
    • Journal Title

      日本結晶学会誌

      Volume: 第54巻第6号 Pages: 345-351

    • Peer Reviewed
  • [Journal Article] Observation of Exceptionally Low-Lying π-π^*Excited States in Oxidized Forms of QuadrupleDecker Phthalocyanine Complexes2012

    • Author(s)
      Takamitsu Fukuda, Kentaro Hata, Naoto Ishikawa
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 14698-14701

    • Peer Reviewed
  • [Journal Article] Dinuclear single-molecule magnet with porphyrin-phthalocyanine mixed tripledecker ligand system giving SAP and SP coordination polyhedra2012

    • Author(s)
      Shohei Sakaue, Akira Fuyuhiro, Takamitsu Fukuda, Naoto Ishikawa
    • Journal Title

      Chem. Commun

      Volume: 48 Pages: 5337-5339

    • Peer Reviewed
  • [Journal Article] Synthesis and Spectroscopic Properties of Phthalocyanine-[60]Fullerene Conjugates Connected Directly by Means of a Four-Membered Ring2012

    • Author(s)
      Takamitsu Fukuda, Yuu Kikukawa, Shiori Takaishi, Nagao Kobayashi
    • Journal Title

      Chem. Asian. J

      Volume: 7 Pages: 751-758

    • Peer Reviewed
  • [Journal Article] Molecular assembly of fullereneconjugated phthalocyanine derivative on Au(111) at single molecular level2012

    • Author(s)
      Soichiro Yoshimoto, Satoshi Masuda, Takamitsu Fukuda, and Nagao Kobayashi
    • Journal Title

      J. Inorg.Biochem.

      Volume: 108 Pages: 178-181

    • Peer Reviewed
  • [Journal Article] Effect of Chain Length on Thermal Conversion of Alkoxy-Substituted Copper Phthalocyanine Precursors2011

    • Author(s)
      Takamitsu Fukuda, Yuu Kikukawa, Ryota Tsuruya, Akira Fuyuhiro, Naoto Ishikawa, Nagao Kobayashi
    • Journal Title

      Inorg. Chem

      Volume: 50 Pages: 11832-11837

    • Peer Reviewed
  • [Journal Article] Observation of long-range f-f interactions between two f-Electronic systems in quadruple-decker phthalocyanines2011

    • Author(s)
      Takamitsu Fukuda, Wakako Kuroda, Naoto Ishikawa
    • Journal Title

      Chem. Commun

      Volume: 47 Pages: 1 1686-11688

    • Peer Reviewed
  • [Journal Article] Facile one-pot preparation of thermally and photochemically convertible soluble precursors of copper phthalocyanine and naphthalocyanine2011

    • Author(s)
      Yuu Kikukawa, Takamitsu Fukuda, Akira Fuyuhiro, Naoto Ishikawa, Nagao Kobayashi
    • Journal Title

      Chem. Commun

      Volume: 47 Pages: 8518-8520

    • Peer Reviewed
  • [Journal Article] Synthesis and spectroscopic properties of nickel complexes of benzo-, 1,2-naphtho-, or 2,3-naphthoannulated β-oxatetraazachlorins2011

    • Author(s)
      Semyon V. Dudkin, Elena A. Makarova, Takamitsu Fukuda, E. A. Lukyanets, Nagao Kobayashi
    • Journal Title

      Tetrahedron Lett.

      Volume: 52 Pages: 2994-2996

    • Peer Reviewed
  • [Journal Article] A Discrete Quadruple-Decker Phthalocyanine2010

    • Author(s)
      Takamitsu Fukuda, Tsuneaki Biyajima, Nagao Kobayashi
    • Journal Title

      J. Am. Chem. Soc

      Volume: 132 Pages: 6278-6279

    • Peer Reviewed
  • [Presentation] ハーフフタロシアニン骨格を有する新規錯体の合成と性質2013

    • Author(s)
      重吉奈都子,菊川悠,冬広明,福田貴光,石川直人
    • Organizer
      日本化学会第93回春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス
    • Year and Date
      2013-03-23
  • [Presentation] Preparation of Thermally Convertible Precursors of Copper Phthalocyanine2012

    • Author(s)
      Takamitsu Fukuda
    • Organizer
      IUPAC 8th International Symposium on Novel Materials and Synthesis (NMS-VIII) & 22th International Symposium on Fine Chemistry and Functional Polymers (FCFP-XXII)
    • Place of Presentation
      西安(中国)
    • Year and Date
      2012-10-16
  • [Presentation] 低温リチウム法を用いたフタロシアニン部分骨格を有する錯体の構造と物性2012

    • Author(s)
      菊川悠,福田貴光,冬広明,石川直人,小林長夫
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学
    • Year and Date
      2012-09-18
  • [Presentation] Facile Preparation of Thermally and Photochemically Convertible Soluble Precursors of Copper Phthalocyanine2011

    • Author(s)
      Takamitsu Fukuda
    • Organizer
      3rd Asian Conference on Coordination Chemistry (ACCC3)
    • Place of Presentation
      ニューデリー(インド)
    • Year and Date
      2011-10-17
  • [Presentation] Synthesis and Properties of Quadruple-Decker Phthalocyanines2010

    • Author(s)
      Takamitsu Fukuda
    • Organizer
      IUPAC 6th International Symposium on Novel Materials and Synthesis (NMS-VI) & 20th International Symposium on Fine Chemistry and Functional Polymers (FCFP-XX)
    • Place of Presentation
      武漢(中国)
    • Year and Date
      2010-10-12
  • [Presentation] 低温リチウム法を用いた溶解性無置換フタロシアニン前駆体の合成と物性2010

    • Author(s)
      菊川悠,鶴谷亮太,福田貴光,小林長夫,石川直人
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪国際交流センター
    • Year and Date
      2010-09-30
  • [Book] UV -Visible Absorption Spectroscopic Properties of Phthalocyanines and Related Macrocycles2010

    • Author(s)
      Takamitsu Fukuda, Nagao Kobayashi
    • Total Pages
      1-644
    • Publisher
      HANDBOOK OF PORPHYRIN SCIENCE(edited by K. M. Kadish, K. M. Smith, and R. Guilard)
  • [Remarks]

    • URL

      http://www.chem.sci.osaka-u.ac.jp/lab/ishikawa/

URL: 

Published: 2014-08-29  

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