2012 Fiscal Year Final Research Report
Control of 1D chain structure constructed from half-lantern complexes with biimidazole ligand
| Project/Area Number |
22550058
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Gifu University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
UEMURA Kazuhiro 岐阜大学, 工学部, 助教 (60386638)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 多核錯体 |
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| Research Abstract |
Dirhodium complexes with biimidazole ligand were synthesized and their structures were determined. Because of their relatively high reduction potentials, one dimensional chain structures were not obtained. A novel dimer of dinuclear complexes with biimidazolate ligand showed two step oxidation.
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