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2012 Fiscal Year Final Research Report

First transition metal catalyst toward artificial photosynthesis

Research Project

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Project/Area Number 22550064
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionOsaka City University

Principal Investigator

KINOSHITA Isamu  大阪市立大学, 大学院・理学研究科 (80128735)

Co-Investigator(Renkei-kenkyūsha) HAMAZAWA Rika  大阪市立大学, 技術員 (80433316)
Project Period (FY) 2010 – 2012
Keywords光合成 / 錯体化学 / 銅錯体
Research Abstract

This research aimed to realize artificial photosynthesis (APS) for practical usage. As the first step for this movement, we intended to use the first transition metal complexes as the catalyst for APS. Usually, relatively rare metals such as Ru and Pt act

  • Research Products

    (12 results)

All 2012 2011 2010 Other

All Journal Article (5 results) Presentation (6 results) Remarks (1 results)

  • [Journal Article] Anion-controlled assembly of four manganese ions: structural, magnetic, and electrochemical properties of tetramanganese complexes stabilized by xanthene-bridged Schiff base ligands.2012

    • Author(s)
      Hirotsu M, Shimizu Y, Kuwamura N, Tanaka R, Kinoshita I, Takada R, Teki Y, Hashimoto H.
    • Journal Title

      Inorg Chem.

      Volume: 51 Pages: 766-8

    • DOI

      doi:10.1021/ic202287k

  • [Journal Article] The Absorption Spectrum of β-Carotene Cation Radical Promoted with Metal Complexes2011

    • Author(s)
      Shunya Ikenaka, Chiasa Uragami, Toshiyuki Kusumoto, Ritsuko Fujii, Takanori Nishioka, Hideki Hashimoto, and Isamu Kinoshita
    • Journal Title

      Carotenoid Science

      Volume: 16 Pages: 39-44

  • [Journal Article] Redox-Controlled, Reversible Rearrange-ment of a Tris(2-pyridylthio)methyl Ligand on Nickel to an Isomer with an "N,S-Confused" 2-Pyridylthiolate Arm.2011

    • Author(s)
      Kuwamura, N., Kitano, K., Hirotsu, M., Nishioka, T., Teki, Y., Santo, R., Ichimura, A., Hashimoto, H., Wright, L. James; Kinoshita, I.
    • Journal Title

      Chemistry-A European Journal.

      Volume: 17 Pages: 10708-10715

    • DOI

      DOI:10.1002/chem.201100875

  • [Journal Article] Preparation and structural features of Cu(I)Cu(II) coordination polymers obtained by using tripodal complexes as bridging ligands.2011

    • Author(s)
      Yoshida, Yuki; Miyamoto, Riichi; Nakato, Ayami; Santo, Ryoko; Kuwamura, Naoto; Gobo, Kenji; Nishioka, Takanori; Hirotsu, Masakazu; Ichimura, Akio; Hashimoto, Hideki; Kinoshita, Isamu.
    • Journal Title

      Bull. Chem. Soc. Japan

      Volume: 6 Pages: 600-611

    • DOI

      DOI:10.1246/bcsj.20100361

  • [Journal Article] Carbene-carbanion equilibrium for tris(2-pyridylthio)methanido Fe(II) complexes.2010

    • Author(s)
      Kuwamura, N., Ryo Kato, Kitano,K., Hirotsu, M., Nishioka, T., Hashimoto, H., Kinoshita, I.
    • Journal Title

      Dalton Trans.

      Volume: 39 Pages: 9988-9993

    • DOI

      DOI:10.1039/C0DT00615G

  • [Presentation] 好熱性シアノバクテリア由来 PSI と Co-C トリポッド錯体のハイブリッドによる水素発生2012

    • Author(s)
      竹本 祐唯・川上 恵典・神谷 信夫・木下 勇
    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      富山大学
    • Year and Date
      2012-09-22
  • [Presentation] トリポッド型配位子1-(ピリジン-2-イル)-2,2-ビス(ピリジン-2-イルチオ)エタニドをもつ第一遷移金属錯体の合成とその性質2012

    • Author(s)
      増田 裕・中藤 彩美・竹口 勝也・廣津 昌和・西岡 孝訓・木下 勇
    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      富山大学
    • Year and Date
      2012-09-22
  • [Presentation] Organometallic tripodal complexes related to artificial photosynthesis2011

    • Author(s)
      木下 勇
    • Organizer
      17th International SPACC Symposium
    • Place of Presentation
      Canada
    • Year and Date
      2011-08-05
  • [Presentation] Redox Non-Innocent Tripodal Carbanion of Tris(2-pyridylthio)-methyl Complexes Mimics the Photosynthetic Behavior2010

    • Author(s)
      木下勇
    • Organizer
      環太平洋国際会議
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2010-12-15
  • [Presentation] カロテノイドとチアカリックス[3]ピリジン錯体の相互作用によるカチオンラジカル様状態の発現2010

    • Author(s)
      池中俊哉、浦上千藍紗、楠本利行、藤井律子、廣津昌和、西岡孝訓、橋本秀樹、木下勇
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪国際交流センター
    • Year and Date
      2010-09-17
  • [Presentation] C-H 結合活性化と中心金属の酸化を伴うコバルト(III)錯体の合成2010

    • Author(s)
      竹口勝也、品田哲郎、大船泰史、桑村直人、廣津昌和、西岡孝訓、橋本秀樹、木下勇
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪国際交流センター
    • Year and Date
      2010-09-17
  • [Remarks]

    • URL

      http://www.materials.sci.osaka-cu.ac.jp/SEKKEI/index_e.htm

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Published: 2014-08-29  

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