2012 Fiscal Year Final Research Report
Design and Synthesis of Suprarmolecular Metal Complexes Under the Chemical Reaction Fields of Polyoxometalates
| Project/Area Number |
22550065
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Inorganic chemistry
|
|---|
| Research Institution | Kanagawa University |
|---|
Principal Investigator |
NOMIYA Kenji 神奈川大学, 理学部, 教授 (80119354)
|
|---|
| Project Period (FY) |
2010 – 2012
|
| Keywords | 超分子金属錯体 / ポリオキソメタレート / 飽和型 / 欠損型 / 第4属金属イオン / 第11属金属イオン / ルイス酸触媒作用 / エポキシ化触媒作用 |
|---|
| Research Abstract |
Novel supramolecular metal complexes were synthesized using Group IV (Ti, Zr, Hf) and Group XI (Ag, Au) metal ions under the chemical reaction fields of the saturated and lacunary species ofpolyoxometalates (POMs) and their solid-state and solution structures were determined. Using some ofthe complexes, Lewis acid catalysis and epoxidation catalysis were also examined.
|
Research Products
(26 results)
