2012 Fiscal Year Final Research Report
Creation of High-Functional Metal Complexes as Host Compounds andTheir Analytical Application
| Project/Area Number |
22550070
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Analytical chemistry
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| Research Institution | Chiba University |
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Principal Investigator |
KATSUTA Shoichi 千葉大学, 大学院・理学研究科, 准教授 (40277273)
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| Co-Investigator(Renkei-kenkyūsha) |
KUDO Yoshihiro 千葉大学, 大学院・理学研究科, 准教授 (00195463)
BESSHO Kotaro 大学共同利用機関法人高エネルギー加速器研究機構, 共通基盤研究施設, 准教授 (10300675)
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| Project Period (FY) |
2010 – 2012
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| Keywords | ホスト-ゲスト化学 / 分子イオン認識 / 金属錯体 / 溶媒抽出 / イオン液体 / 分離法 |
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| Research Abstract |
Metal complexes, such as macrocyclic trinuclear complexes of arene-ruthenium units bridged by 2,3-pyridinediolate and mononuclear complexes of1,1,1-tris(N-salicylideneaminomethyl)ethane derivatives, were synthesized as new host molecules for ions. Their ion-recognition ability and analytical applicability were investigated. The properties of hydrophobic ionic liquids as extraction solvents for ions and diluents for the metallohosts were also studied in detail.
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