2012 Fiscal Year Final Research Report
Development of innovative carbon-carbon bond forming reactions using triolborate salts
| Project/Area Number |
22550092
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Hokkaido University |
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Principal Investigator |
YAMAMOTO Yasunori 北海道大学, 大学院・工学研究院, 特任准教授 (30271646)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 選択的合成・反応 / 有機ホウ素化学 / 遷移金属触媒反応 / 有機トリオールボレート塩 |
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| Research Abstract |
We have developed ate-complexes, cyclic aryltriolborate salts that haveexceptionally high levels of stability in air and water and reasonable solubility in organic solvents. Wehave newly synthesized heteroaryltriolborate salts for palladium-catalyzed cross-coupling reactions,copper-catalyzed N-arylation reactions, and catalyzed asymmetric addition reactions.
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