2013 Fiscal Year Final Research Report
Studies on the Regioselective Carbon-Carbon Formation Reactions via the Vinylidenemetal Comlexes as a Key Intermediate
| Project/Area Number |
22550100
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
FUKUMOTO Yoshiya 大阪大学, 工学(系)研究科(研究院), 准教授 (50273595)
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| Project Period (FY) |
2010-04-01 – 2013-03-31
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| Keywords | ビニリデン金属錯体 / 炭素－炭素結合生成 / レニウム / 末端アルキン / イミン / アリルアミン |
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| Research Abstract |
I have studied the new carbon-carbon bond reactions via the formation of the vinylidenemetal complex as a key intermediate. For example, I found the reaction of terminal alkynes with imines in the presence of rhenium complex as a catalyst leading to the formation of allylamines. Mechanistic studies for the present reaction were consistent with the proposed reaction mechanism involving the vinylidenerhenium intermediate.
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