2012 Fiscal Year Final Research Report
Synthesis of Sulfur-Containing Fused Heteroaromatic Compounds via Oxidative Coupling
| Project/Area Number |
22550101
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
SATOH Tetsuya 大阪大学, 大学院・工学研究科, 准教授 (40273586)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 縮合へテロ環 / π共役分子 / 酸化的カップリング / 炭素-水素結合活性化 |
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| Research Abstract |
The oxidative coupling reactions of various aromatic substrates with alkynes and alkenes under transition-metal catalysis such as rhodium, palladium, and ruthenium were investigated. As a result, I succeeded in finding a number of new coupling reactions involving C-H bond cleavage. Furthermore, it was successfully shown that a wide range of sulfu- or other heteroatom-containing fused heteroaromatic compounds can be efficiently prepared by using these new reactions.
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