2012 Fiscal Year Final Research Report
Synthesis of Long-Branched Polycondensates
Project/Area Number |
22550106
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Polymer chemistry
|
Research Institution | Akita University |
Principal Investigator |
JIKEI Mitsutoshi 秋田大学, 大学院・工学資源学研究科, 教授 (70251618)
|
Co-Investigator(Kenkyū-buntansha) |
SUGIMOTO Masataka 山形大学, 大学院・理工学研究科, 准教授 (10361271)
KAWAGUCHI Seigou 山形大学, 大学院・理工学研究科, 教授 (00204694)
MATSUMOTO Kazuya 秋田大学, 大学院・工学資源学研究科, 助教 (70467025)
|
Project Period (FY) |
2010 – 2012
|
Keywords | 高分子合成 / 長鎖分岐 / 縮合系高分子 |
Research Abstract |
Long-branched polycondensates were prepared by self-polycondensastion of branched macromonomers. Inherent viscosity of the branched poly(ether sulfone)s increased with increasing the molecular weight of the macromonomers. The radius of gyrations of the branched poly(L-lactide)s in HFIP were much smaller than those of the linear PLLA with the corresponding weight-average molecular weight. It is experimentally revealed that the introduction of branching strongly affects the molecular architecture of the resulting polymers.
|
Research Products
(19 results)