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2012 Fiscal Year Final Research Report

Development of a new size-control method for nano-crystalline zeolite and its rational design as a catalyst

Research Project

  • PDF
Project/Area Number 22560755
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionHokkaido University

Principal Investigator

TAGO Teruoki  北海道大学, 大学院・工学研究院, 准教授 (20304743)

Co-Investigator(Kenkyū-buntansha) MASUDA Takao  北海道大学, 大学院・工学研究院, 教授 (20165715)
NAKASAKA Yuta  北海道大学, 大学院・工学研究院, 助教 (30629548)
Project Period (FY) 2010 – 2012
Keywords反応速度
Research Abstract

Main objective of this research is a size-controlled synthesis for zeolite crystal and a development of design method for nano-zeolite catalyst. Various types of zeolites (MFI, TON, MOR, BEA, FAU and MTW) were synthesized and their crystal sizes could be successfully controlled. Especially, in MFI-,MOR-,MTW-,TON-type zeolites, the nano-crystalline zeolites with the size below 100 nm and macro-crystalline zeolite with the size above 1000 nm were obtained.Acrolein production from glycerol and 2,6-dimethyl naphthalene (2,6-DMN) production from 2-methyl naphthalene were conducted using zeolite catalysts. It is found that TON zeolite exhibits a high yield of acrolein above 80 % and that 2,6-DMN is selectively produced using MFI and MTW zeolites. Moreover, the crystal sizes of zeolite affect the product selectivity as well as the catalyst stability, the values of which are drastically improved by applying the nano-crystalline zeolite as a catalyst.

  • Research Products

    (7 results)

All 2012 2011 2010

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (2 results) Book (2 results)

  • [Journal Article] Synthesis of nano-sized zeolites and their applications to zeolite membranes2012

    • Author(s)
      T. Tago, Y. Nakasaka and T. Masuda
    • Journal Title

      J. Jpn Petrol. Instit

      Pages: 149-159

    • Peer Reviewed
  • [Journal Article] Size-controlled synthesis of nano-zeolites and their application to light olefin synthesis2012

    • Author(s)
      T. Tago, H. Konno, Y. Nakasaka, T. Masuda
    • Journal Title

      Catal. Surv. fromAsia

      Volume: 16 Pages: 148-163

    • DOI

      DOI:10.1007/s10563-012-9141-4

    • Peer Reviewed
  • [Journal Article] Selective Synthesis for light olefins from acetone over ZSM-5 zeolites with nano- and macro-crystal sizes2011

    • Author(s)
      T. Tago, H. Konno, M. Sakamoto, Y.Nakasaka and T. Masuda
    • Journal Title

      Appl. Catal. A,Gen

      Volume: 403 Pages: 183-191

    • DOI

      DOI:10.1016/j.apcata.2011.06.029

    • Peer Reviewed
  • [Presentation] Size/morphology controlled synthesis of zeolite crystals and their applications2012

    • Author(s)
      T. Tago
    • Organizer
      10th Japan-Korea Symposium on Materials and Interfaces
    • Place of Presentation
      Coop Inn Kyoto, Japan
    • Year and Date
      2012-11-07
  • [Presentation] Catalytic Cracking of n-Hexane Cracking over MFI-Type Zeolites with Different Crystal Sizes2012

    • Author(s)
      T. Tago
    • Organizer
      22th International Symposium on Chemical Reaction Engineering
    • Place of Presentation
      the Maastricht Exhibition & Congress Centers, The Netherlands
    • Year and Date
      2012-09-04
  • [Book] Zeolites: Synthesis, Chemistry and Applications, "Synthesis of nanocrystalline zeolites and their applications2012

    • Author(s)
      T. Tago, Y. Nakasaka and T. Masuda
    • Total Pages
      171-189
    • Publisher
      NovaScientific publisher
  • [Book] Zeolite Nanocrystals -Synthesis and Applications-2010

    • Author(s)
      T. Tago and T. Masuda, SCIYO, Nanocrystals
    • Total Pages
      191-206

URL: 

Published: 2014-08-29  

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