2012 Fiscal Year Final Research Report
Fabrication of meta-material by programmable plating of DNA
Project/Area Number |
22655059
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Research Category |
Grant-in-Aid for Challenging Exploratory Research
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Allocation Type | Single-year Grants |
Research Field |
Functional materials/Devices
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Research Institution | Hokkaido University |
Principal Investigator |
IJIRO Kuniharu 北海道大学, 電子科学研究所, 教授 (90221762)
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Project Period (FY) |
2010 – 2012
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Keywords | DNA / 自己組織化 / メッキ / メタマテリアル / 微細加工 |
Research Abstract |
Top-down processes, such as photolithography, have been approaching a limit with regard to the fabrication of fine structures. For the preparation of molecular-scale fine structures, it is important that conventional self-assembly methods should be adapted to a “programmable self-assembly” as a next-generation bottom-up system. We aim to fabricate nano-gap electrodes by sequence-selective metallization of template DNA. We have already reported the fabrication of sequence-selective platinum nano-wires using poly(guanine) and poly(adenine-thymine) diblock DNA, which is enzymatically polymerized as a template. That method, however, cannot be extended to the preparation of oligoblock DNA. In this study, we prepared triblock DNA sequences using guanine as a platinum-binding natural nucleotide and 7-deaza-guanine as a platinum-nonbinding unnatural nucleotide for the construction of platinum nano-wires with nano-gap structures.
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[Presentation] Room temperature coulomb blockade in a DNA-templated metal/ polymeralternated hybrid nanowire2012
Author(s)
K. Ijiro, G. Wang, H. Tanaka, L. Hong, Y.Matsuo, K. Niikura, M. Abe, K. Matsumoto, T. Ogawa
Organizer
2012 Optics + Photonics, SPIE
Place of Presentation
San Diego Convention Center, San Diego, California, USA
Year and Date
20120812-16
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[Book] ナノワイヤー2010
Author(s)
松尾保孝、居城邦治
Total Pages
166-167
Publisher
丸善株式会社、現代界面コロイド科学の事典