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2012 Fiscal Year Final Research Report

Development of next-generation external-field-responsive ionic liquids utilizing metal oxide nanosheets and metal complexes

Research Project

  • PDF
Project/Area Number 22685015
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionMeijo University

Principal Investigator

YOSHIDA Yukihiro  名城大学, 農学部, 助教 (10378870)

Project Period (FY) 2010 – 2012
Keywordsイオンソフトマテリアル / イオン液体 / 有機-無機ナノコンポジット / 金属酸化物 ナノシート / 外場応答 / プロトン伝導 / 粘弾性
Research Abstract

We demonstrated that negatively-charged metal oxide nanosheets can be utilized for development of novel functional ionic soft materials, by regarding them as “inorganic polymeric anions”. For example, viscoelastic ionic nanocomposite was obtained by virtue of the formation of ammonium-containing siloxane network on the titania nanosheet. The shape deformability allows us to process the thin film with a thickness of less than 100 nm, and the proton conductivity shows the multiple sensitivities to temperature, humidity, and photo-irradiation.

  • Research Products

    (18 results)

All 2012 2011 2010 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (5 results) Book (3 results)

  • [Journal Article] Preparation and Formation Mechanism of an-Butylammonium/MnO2 Layered Hybrid viaa Room Temperature One-Pot Synthesis2012

    • Author(s)
      K. Kai, Y. Yoshida, Y. Kobayashi, H.Kageyama, G. Saito
    • Journal Title

      Dalton Trans.

      Volume: 41 Pages: 825-830

    • DOI

      DOI:10.1039/c1dt11145k

    • Peer Reviewed
  • [Journal Article] One-Pot Synthesis of Co-Substituted Manganese Oxide Nanosheets and PhysicalProperties of Lamellar Aggregates2012

    • Author(s)
      K. Kai, M. Cuisinier, Y. Yoshida, 他
    • Journal Title

      Mater. Res. Bull.

      Volume: 47 Pages: 3855-3859

    • DOI

      DOI:10.1016/j.materresbull.2012.08.008

    • Peer Reviewed
  • [Journal Article] Ionic Liquids Based onDiethylmethyl(2-methoxyethyl)ammonium Cation and Bis(perfluoroalkanesulfonyl)amide Anions: Influence of Anion Structure on Liquid Properties2011

    • Author(s)
      Y. Yoshida, G. Saito
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 13 Pages: 20302-20310

    • DOI

      DOI:10.1039/c1cp21783f

    • Peer Reviewed
  • [Journal Article] Viscoelastic Nanocomposite Composed of Titania Nanosheets: Conductometric Sensitivity to Temperature, Humidity, andPhoto Irradiation2011

    • Author(s)
      Y. Yoshida, K. Kai, H. Kageyama, G. Saito
    • Journal Title

      Dalton Trans.

      Volume: 40 Pages: 7291-7294

    • DOI

      DOI:10.1039/c1dt10686d

    • Peer Reviewed
  • [Journal Article] Shape Deformable Nanocomposite Composed of Manganese Oxide Nanosheets2011

    • Author(s)
      Y. Yoshida, K. Kai, H. Kageyama, G. Saito
    • Journal Title

      J. Mater.Chem.

      Volume: 21 Pages: 5863-5866

    • DOI

      DOI:10.1039/c1jm10594a

    • Peer Reviewed
  • [Journal Article] Design of Functional Ionic Liquids Using Magneto- and Luminescent-Active Anions2010

    • Author(s)
      Y. Yoshida, G. Saito
    • Journal Title

      Phys. Chem.Chem. Phys.

      Volume: 12 Pages: 1675-1684

    • DOI

      DOI:10.1039/b920046k

    • Peer Reviewed
  • [Journal Article] Preparation, Structures, and Physical Properties of Tetrakis(alkylthio)tetraselena- fulvalene (TTCn-TSeF, n = 1-15)2010

    • Author(s)
      G. Saito, Y. Yoshida
    • Journal Title

      Bull. Chem.Soc. Jpn.

      Volume: 83 Pages: 335-344

    • DOI

      DOI:10.1246/bcsj.20090240

    • Peer Reviewed
  • [Journal Article] MolecularRotors of Coronene in the Charge-TransferSolids

    • Author(s)
      Y. Yoshida
    • Journal Title

      Chem. Eur. J.

      Volume: (印刷中)

    • DOI

      DOI:10.1002/chem.201300578

    • Peer Reviewed
  • [Journal Article] Charge-Transfer Solids Using Nucleobase: Supramolecular Architectures Composed of Cytosine and [Ni(dmit)2] Assembled by Multiple Hydrogen Bonds and Heteroatomic Contacts

    • Author(s)
      Y. Yoshida, 他6名
    • Journal Title

      Chem. Eur.J.

      Volume: (印刷中)

    • DOI

      DOI:10.1002/chem.201300865

    • Peer Reviewed
  • [Journal Article] Exploration of Charge-Transfer Solids Utilizing Nucleobases: Nanoarchitectures by Hydrogen-Bonds in the Ionic Assemblies of Guanine and TCNQ Derivatives

    • Author(s)
      T. Murata, G. Saito, K. Nakamura, M.Maesato, T. Hiramatsu, Y. Yoshida
    • Journal Title

      Cryst.Growth Des.

      Volume: (印刷中)

    • DOI

      DOI:10.1021/cg400059h

    • Peer Reviewed
  • [Presentation] 芳香族炭化水素コロネンを用いた電荷移動型分子ローターの開発2012

    • Author(s)
      吉田幸大
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学
    • Year and Date
      20120918-21
  • [Presentation] Viscoelastic Nanocomposites Composed of Transition-Metal Oxide Nanosheets2012

    • Author(s)
      Y. Yoshida, K. Kai, H. Kageyama, G. Saito
    • Organizer
      The International Conference on Science and Technology of Synthetic Metals (ICSM 2012)
    • Place of Presentation
      米国ジョージア州
    • Year and Date
      20120708-13
  • [Presentation] External-Field-Responsive Soft Materials: Ionic Liquid and Viscoelastic Nanocomposite2011

    • Author(s)
      Y. Yoshida, K. Kai, H. Kageyama, G. Saito
    • Organizer
      The 4th International Congress on IonicLiquids (COIL-4)
    • Place of Presentation
      米国バージニア州
    • Year and Date
      20110615-18
  • [Presentation] Valence-Tautomeric Ionic Liquid-Thermal-Induced Magnetic and OpticalChanges2010

    • Author(s)
      Y. Yoshida, H. Tanaka, G. Saito, L. Ouahab
    • Organizer
      Pacifichem2010
    • Place of Presentation
      米国ハワイ州
    • Year and Date
      20101215-20
  • [Presentation] Valence-Tautomeric Ionic Liquid Composed of Cobalt Bis(dioxolene) Complex Dianion2010

    • Author(s)
      Y. Yoshida, H. Tanaka, G. Saito, L. Ouahab, H. Yoshida, N. Sato
    • Organizer
      The International Conference on Science and Technology of Synthetic Metals (ICSM 2010)
    • Place of Presentation
      京都国際会館
    • Year and Date
      20100704-09
  • [Book] Yoshida,TopicsofCurrentChemistry:UnimolecularandMacromolecularElectronics2012

    • Author(s)
      G.Saito,Y.
    • Total Pages
      67-126
    • Publisher
      SpringerVerlag
  • [Book] Superconductors-Materials, Properties and Applications2012

    • Author(s)
      G. Saito, Y. Yoshida
    • Total Pages
      105-136
    • Publisher
      InTech
  • [Book] Ionic Liquids -Theory, Properties, New Approaches2011

    • Author(s)
      Y. Yoshida, G. Saito
    • Total Pages
      723-738
    • Publisher
      InTech

URL: 

Published: 2014-08-29  

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