2012 Fiscal Year Final Research Report
High functionalization of nano-size coordination space based on itsinternal magnetic field for a specific reaction in the cavity
| Project/Area Number |
22710089
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Nanostructural science
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| Research Institution | Josai University (2012)
Osaka Electro-Communication University (2011)
Hiroshima University (2010) |
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Principal Investigator |
AKITA Motoko 城西大学, 理学部, 教授 (30370125)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 配位ナノ空間 / 磁性ホスト化合物 / 磁場効果 / 分子性磁性体 / 金属錯体 / 水熱合成 |
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| Research Abstract |
A series of metal-organic molecular-based magnets which included organic molecules as reactants were synthesized, and their crystal structure and magnetic properties were studied. Hydrothermal synthesis of D-, L-, and DL-amino acid with several transition metals gave a variety of molecular-based magnets which shows ferromagneism, antiferromagnetism and weak-ferromagnetism. New chiral magnets were successfully obtained from only achiral species by spontaneously resolution of enantiomers. Magnetic measurements revealed that those magnetic structures also might be chiral.
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