2011 Fiscal Year Final Research Report
How does the hydrogen bonding give changes to valence electrons?
| Project/Area Number |
22750019
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Physical chemistry
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| Research Institution | Kwansei Gakuin University |
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Principal Investigator |
MORISAWA Yusuke 関西学院大学, 理工学研究科, 博士研究員 (60510021)
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| Project Period (FY) |
2010 – 2011
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| Keywords | 電子状態 / 液体 / 液相分子ダイナミクス |
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| Research Abstract |
Effect of intermolecular interaction, such as hydrogen bonds and van der Waals forces to valence electrons were investigated by using an attenuated total reflection spectrometer in far-UV(ATR-FUV). After developing the ATR-FUV equipment for measurements in low temperature(～-70℃), ATR-FUV spectra of liquid acetone and, solid and liquid alkanes were observed. Comparing the results of electronic states in low-temperature liquids and high level quantum chemical calculations, we got a new insight about the effect of intermolecular interaction to valence electrons.
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