2011 Fiscal Year Final Research Report
Small Molecule Activation by Iron Complexes with Aryloxide Ligands
| Project/Area Number |
22750049
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
ISHIDA Yutaka 東京工業大学, 大学院・理工学研究科, 助教 (00465931)
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| Project Period (FY) |
2010 – 2011
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| Keywords | 鉄錯体 / 小分子活性化 / アリールオキシド配位子 |
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| Research Abstract |
Terminal metal nitrides(M≡N) and imides(M=NR) have been invoked as intermediates in synthetic or biological transformations. We focused on the iron-nitrogen multiple bond chemistry. First, new ligands consisted of aryloxides were prepared as supporting ligands for the iron complexes. Iron complexes with bulky aryloxides can be applied for synthesis of highly reactive iron nitrides, which were structurally characterized by X-ray crystallographic analysis.
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