2011 Fiscal Year Final Research Report
Synthesis ofα-Amino Acids Using Carbon Dioxide
| Project/Area Number |
22750081
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Hokkaido University |
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Principal Investigator |
MITA Tsuyoshi 北海道大学, 大学院・薬学研究院, 助教 (00548183)
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| Project Period (FY) |
2010 – 2011
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| Keywords | 二酸化炭素 / 固定化 / アミノ酸 / アミノスルホン / アミノスズ / フッ化セシウム / カルバニオン / フェニルグリシン |
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| Research Abstract |
Carbon dioxide is an abundant, inexpensive, and nontoxic C1 unit ; however, its inertness and gaseous character sometimes hamper its use for efficient C-C bond-forming reactions in organic synthesis. Despite its difficulty, we have successfully developed one-potα-amino acid synthesis from imines using carbon dioxide though C-C bond-formation.
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