2011 Fiscal Year Final Research Report
Development of a Novel Phenalenyl-Based Organic Conductors : A Relationship between Structure and Function
| Project/Area Number |
22750129
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Functional materials chemistry
|
|---|
| Research Institution | Osaka University |
|---|
Principal Investigator |
HIRAO Yasukazu 大阪大学, 大学院・理学研究科, 助教 (50506392)
|
|---|
| Project Period (FY) |
2010 – 2011
|
| Keywords | 電気・磁気的機能 / 分子性導体 / 超伝導 / π共役系 / 構造有機化学 / 有機ラジカル / スピンラダー |
|---|
| Research Abstract |
This project was focused on the relationship between molecular alignment and physical properties in molecular conductors. Especially, we tried to construct two unique molecular alignments : spiral and ladder, by the use of the new designed molecules. To increase intermolecular interactions and control of crystal orientations, phenalenyl that is a neutral PAH radical was introduced in this research. We succeeded in synthesizing both target molecules. Their electronic structures were revealed by physical measurements. Now, we try to obtain a crystal and extract a new function from its molecular alignment.
|
-
-
[Journal Article] Synthesis, Crystal Structure, and Physical Properties of Sterically Unprotected Hydrocarbon Radicals2011
Author(s)
Takashi Kubo, Yoshiki Katada, Akihiro Shimizu, Yasukazu Hirao, Kazunobu Sato, Takeji Takui, Mikio Uruichi, Kyuya Yakushi, Robert C. Haddon
-
Journal Title
J. Am. Chem. Soc
Volume: 133
Pages: 14240-14243
-
-
-
-
-
-
