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2011 Fiscal Year Final Research Report

Photopolymerization induced phase separation for functional networks polymer thin film

Research Project

  • PDF
Project/Area Number 22760587
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Reaction engineering/Process system
Research InstitutionKyoto University

Principal Investigator

KENTARO Taki  京都大学, 大学院・工学研究科, 助教 (70402964)

Project Period (FY) 2010 – 2011
Keywords多孔構造体 / UV硬化
Research Abstract

In this study, a solution of UV curable monomer and 1, 4-dioxane was frozen unidirectionally and cured by UV irradiation to create a porous monolith structure using the crystals of the frozen solvent as the template materials for the UV curable monomers. The solution viscosity was found to be an important factor to control the pore diameters. As the viscosity affects the diffusivity of the solute, which was UV curable monomer, the combination of the materials and thermal diffusion determines the final porous structure at the interface of crystals.

  • Research Products

    (6 results)

All 2012 2011 2010 2009

All Journal Article (1 results) Presentation (5 results)

  • [Journal Article] Preparation of porous honeycomb monolith from UV-curable monomer/dioxane solution viaunidirectional freezing and Uvirradiation2012

    • Author(s)
      Okaji, Rika, Kentaro Taki, Shinsuke Nagamine, Masahiro Ohshima
    • Journal Title

      Journal of Applied Polymer Science

      Volume: 125(4) Pages: 2874-2881

  • [Presentation] 溶媒2成分高分子溶液の一方向凍結過程での相分離挙動と創製される多孔構造2012

    • Author(s)
      岡地理佳, 瀧健太郎, 長嶺信輔, 大嶋正裕
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      工学院大学
    • Year and Date
      20120315-0317
  • [Presentation] 液-液相分離現象と一方向凍結法を利用した多孔構造体の構造制御2011

    • Author(s)
      岡地理佳, 瀧健太郎, 長嶺信輔, 大嶋正裕
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋大学
    • Year and Date
      20110914-16
  • [Presentation] Preparationof Cross-linked Micrometer-scale PorousHoneycomb Monolith from UV Curable Monomer/Dioxane Solution via Unidirectional Freezing and UVIrradiation2010

    • Author(s)
      Okaji, Rika, Kentaro Taki, Shinsuke Nagamine, Masahiro Ohshima
    • Organizer
      9th Korea-Japan Symposiumon Materials & Interfaces
    • Place of Presentation
      Soul, Korea
    • Year and Date
      20101100
  • [Presentation] 重合度が制御された紫外線硬化性樹脂溶液の一方向凍結による多孔構造体の創製2010

    • Author(s)
      岡地理佳, 瀧健太郎, 長嶺信輔, 大嶋正裕
    • Organizer
      化学工学会第42回秋季大会
    • Place of Presentation
      同志社大学
    • Year and Date
      20100906-08
  • [Presentation] UV硬化性溶液の凍結と硬化による多孔膜の形成と構造制御2009

    • Author(s)
      岡地理佳, 金鎮雄, 瀧健太郎, 長嶺信輔, 大嶋正裕
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学
    • Year and Date
      20090916-18

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Published: 2013-07-31  

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