2014 Fiscal Year Final Research Report
Creation of stimulation responsive metal complexes: control of molecular uptake and release, and high sensitive molecular sensing
Project/Area Number |
23245014
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Research Category |
Grant-in-Aid for Scientific Research (A)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic chemistry
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Research Institution | Kyushu University |
Principal Investigator |
OHBA Masaaki 九州大学, 理学(系)研究科(研究院), 教授 (00284480)
|
Co-Investigator(Kenkyū-buntansha) |
HORI Akihiro 京都大学, 物質-細胞統合システム拠点, 研究員 (50595064)
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Project Period (FY) |
2011-04-01 – 2015-03-31
|
Keywords | 多孔性配位高分子 / 機能性金属錯体 / ゲスト応答性 |
Outline of Final Research Achievements |
In this research project, we promoted (a) the establishment of construction method of the interaction space having flexible structure and electronic state by reasonable controlling the organized structure of functional metal complexes and the placement of interaction parts, (b) the expression of specific guest-responsivity by cooperative coupling between framework and guest molecules, and (c) the elucidation of the mechanism of guest responsivity by in situ physical property measurements under the guest atmosphere. We mainly focused on the responsivity to chemical stimulation, and succeeded in (1) the control of spin state through host-guest interaction and the elucidation of its mechanism, (2) the improvement of responsivity by meso-crystallization, (3) the creation of guest-responsive luminescent porous frameworks, and (4) the creation of composites between coordination polymers and liposome by introducing lipophilicity into the building unit.
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Free Research Field |
錯体化学
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